• 제목/요약/키워드: Reduction/dyeing

검색결과 143건 처리시간 0.021초

CDP 섬유의 염색성(III) -극세 CDP섬유의 염색성, Solvent wicking성 및 물성- (Dyeing Properties of CDP Fiber(III) - Dyeing and Solvent Wicking and Physical Properties of Micro CDP Fiber -)

  • 김영희;정동석;이문철
    • 한국염색가공학회지
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    • 제17권5호
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    • pp.1-12
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    • 2005
  • Polyester fibers can be modified into cationic dyeable polyester fibers(CDP) by the copolymerization of terephthalic acid and 5-sodium sulphoisophthalic acid with ethylene glycol. The advantage of CDP on most cationic dyes is the conspicuous brilliance due to a narrow steep absorption band and the wash fastness and etc. Weight reduction by alkali hydrolysis, dyeing and solvent wicking properties of fabrics with cationic dyes, and change of fine structure were investigated. To obtain optimum splitting process parameters for dyeing and physical properties of micro CDP fiber, splitting method under various conditions was carried out. By means of SEM, it was confirmed that the splitting process of the micro CDP fiber be achieved at the weight reduction. A comparatively greater quantity of dye is necessary to dye microfiber than conventional fiber. The fastness and solvent wicking of regular CDP fiber is higher than that of micro CDP fiber.

양모섬유의 염색시 디스아조계 산성염료의 변색현상 규명 (The Investigation on Color Change of Dis-azo Acid Dye in Wool Dyeing)

  • 김미경;김태경;윤석한;임용진
    • 한국염색가공학회지
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    • 제15권2호
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    • pp.86-92
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    • 2003
  • It is already known that the color of wool fabric dyed with disazo acid dyes could be changed in dyeing process and this is accelerated under alkaline condition. Focus was given to figuring out the mechanism of this color change, through the LC-MS analysis. In this study, no color change was seen in wool fabrics dyed with C. I. Acid Blue 113 under weak acidic, neutral and weak alkaline conditions for 1hour. However, the wool fabrics dyed under weak alkaline condition for a long time over 3 hours fumed reddish orange. When the wool fabrics dyed under weak acidic, neutral and weak alkaline conditions were treated with $0.5g/L\;Na_2C0_3$ solution, all of them turned reddish orange. On the other hand, the color of silk fabrics dyed with C. I. Acid Blue 113 were not changed after the same alkaline treatment. Wool contains cystine and cysteine, whereas silk does not. Due to the reversible reduction/oxidation process of cystine and cysteine in wool dyeing, the C. I. Acid Blue 113 of the dis-azo type is decomposed by reduction and consequently turned them into the reddish orange mono-azo types dye.

천연염료를 이용한 염색물의 항균, 소취성에 관한 연구(I) ―소 목― (A Study on the Antibacterial and Deodorization of Silk Fabrics Dyed with Natural Dye (II) ― Sappan Wood―)

  • Lee, Sang Rag;Lee, Young Hee;Kim, In Hoi;Nam, Sung Woo
    • 한국염색가공학회지
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    • 제7권4호
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    • pp.74-86
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    • 1995
  • Antibacterial and deodorization properties of silk fabrics dyed with Sappan wood are investigated by Halo, Shake flask, Bioassay and Detection column methods.The results are obtained as follows; 1. Although K/S values increase with Al mordant and concentrate concentrations, these are decreased in 10% Al mordant concentration in case of 4mlg dye concentration. 2. Reduction ratios of bacteria increase with K/S values in various tests. 3. When undyed silk fabrics are treated with Al mordant, reduction ratios of bacteria are not varied with Al mordant concentrations. 4. Deodorization property of Al pre-mordanted dyeing silk fabrics is better than one of unmordanted dyeing and raw silk fabrics. 5. Antibacterial properties of Cu and Cr mordanted dyeing fabrics are better than ones of the dyeing fabrics treated with the other mordants. 6. Natural dyes extracted from Sappan wood show the good antibacterial and deodorization properties, and colorant among various components contained in Sappan wood has a excellent antibacterial and deodorization properties.

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세가지 수계 추출 용매를 사용한 은행잎 추출액의 염색성 및 항균성 (Dyeability and Antibacterial Activity of Ginkgo Biloba Leaf Extract Using Three Kinds of Aqueous Extraction Solvents.)

  • 김정임;최영희;권오경
    • 한국염색가공학회지
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    • 제16권2호
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    • pp.8-14
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    • 2004
  • The purpose of this study was to investigate dyeing properties and antibacterial activities of cotton and silk fabrics treated with Ginkgo biloba leaf extracted with three kinds of aqueous solvents: distilled water, electrolytic reduction water and electrolytic oxidation water. The optimum dyeing condition of Ginkgo biloba leaf was 120 min at 8$0^{\circ}C$. Electrolytic reduction water had the highest dyeability to both cotton and silk compared with electrolytic oxidation water and distilled water. A color of extract by distilled water and electrolytic oxidation water showed yellowish Yellow Red, extract by electrolytic reduction water showed reddish Yellow Red. Irrespective of kinds of extraction solvents, appropriate acidity of medium was pH 9∼11 and pH 3 for cotton and silk fabrics, respectively. Colorfastness to laundering and Light fastness showed generally low but crocking fastness was excellent. Antibacterial activities of the treated fabrics above were 99.9%.

가래 외피 추출액을 이용한 견직물의 흑색 발현 연구 (A Study on the Black Color Expression of Silk Fabrics with Juglans mandshurica Cortex Extract)

  • 이제남;이은진
    • 패션비즈니스
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    • 제21권1호
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    • pp.166-176
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    • 2017
  • This study is fundamental research on how to be able to scientifically quantify and reproduce a natural dyeing procedure. By dyeing silk fabrics, the establishment of a reproducible dyeing method was sought. Juglans mandshurica has been known as one of the most widely used black vegetable dyes. Repetition conditions and combination dyeing were performed with Juglans mandshurica cortex, gallnut, clove, and Eclipta prostrata L. extracts to express a deep black color. Juglans mandshurica cortex, gallnut, clove, and Eclipta prostrata L. extracts were suitable for black coloration and showed a darker black color when combined with iron mordant. Specifically, Juglans mandshurica cortex and clove can be used for deep black coloring. Color fastness when washed or dry cleaned was found to be strong with a grade of 4-5 and fastness to light was rated at a 3-4. The grade of color change when exposed to rubbing and perspiration was good at a 4-5. In regards to functional property aspects, it showed excellent results with a 99% deodorization rate at 120 minutes of dyeing time, 97.1% UV protection rate, and 85.9% and 62.3% bacterial reduction against Staphylococcus aureus and Streptococcus pneumoniae, respectively. Therefore, it is considered that the extract from the Juglans mandshurica cortex is of great value as an eco-friendly, natural dyestuff.

키토산 가공이 모직물의 특성에 미치는 효과 (Effects of Chitosan Treatment on Properties of Wool Fabrics)

  • 모태화;이혜자;유혜자
    • 한국의류학회지
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    • 제24권1호
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    • pp.87-95
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    • 2000
  • The changes on shrinkage, dyeability, antimicrobial activities and other physical properties of wool fabrics by chitosan treatment were investigated. A acid dye, a basic dye and natural artemisia were used for dyeing of wool fabrics. For Antimicrobial test of wool fabrics, S.Aureus was used. As the results, The wool fabrics treated with chitosan showed a marked decrease in shrinkage. Dyeability increased slightly as concentration of chitosan treatment increased, Dyeability of acid dye was the highest than other dyes. On the other hand, the dyeability of basic dye on chitosan treated fabrics was lower than untreated fabrics. Reduction rates of colony of chitosan-treated wool fabrics showed from 64.8% to 85.24% as chitosan concentration increased. Reduction rates of colony of the chitosan-treated fabrics decreased by dyeing with acid and basic dye. But increased by retreating with chitosan. Fabrics dyeing with atremisia showed above 90% reduction rate against S.Aureus on all chitosan concentrations. The Tensile properties of chitosan-treated fabrics showed little decrease. The moisture regain and the air permeability was decreased on chitosan concentration on 0.1% but recovered as chitosan concentration increased. The warmth retention was increased a little by chitosan treatment. The drapeability became hard as chitosan concentration increased.

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에너지 절감형 염색기용 직접냉각수세장치에 대한 연구 (A Study on Direct Cooling and Washing Machine for Energy Saving-Type Dyeing Machine)

  • 한승철;김진호;김제훈;이성규
    • 한국산학기술학회논문지
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    • 제13권2호
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    • pp.485-491
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    • 2012
  • 최근 국내 섬유산업의 생산량이 증가함에 따라 섬유산업에서 에너지 소비는 계속 증가되고 있는 실정이다. 기존의 염색기는 고온 고압의 특성을 가지고 있기 때문에 염색 후 냉각을 하기 위하여 열교환기를 통한 간접냉각방식을 채택하고 있다. 이러한 간접냉각방식은 물의 소모량이 많으며 작업 시간 또한 오래 걸리는 문제점이 있고 냉각시 염액의 고착으로 인해 냉각 후 환원세정 및 수세를 수차례 하므로 에너지가 많이 소비된다. 따라서 본 논문에서는 고온 고압 액류 염색기의 열교환기에 의한 간접냉각방식을 염색기내에 냉수를 직접 공급하는 직접냉각방식으로 대체하기 위한 장치를 개발하여 기존의 염색기에 적용하여 냉각과 동시에 환원세정공정을 생략하고 수세공정을 단축시키면서 전공정을 마무리함으로써 전체 작업공정을 줄이고 에너지 소비를 절감하는 등의 생산성을 획기적으로 향상시킬 수 있는 직접냉각수세장치를 제안하며, 시제작품을 제작하고, 실제 염색기에 적용하여 기존의 간접 냉각 방식의 염색기와 성능, 자원 및 에너지 절감율을 비교하였다. 또한 시제작품을 적용한 염색기의 염색성 실험을 하였다.

질소성분 함유 인조섬유에 대한 천연염료 오배자의 무매염 염색성 및 항균성 (Dyeing and antimicrobial properties of N-containing man-made fibers non-mordanted in dyeing with gallnut)

  • 김예홍;상정선;박명자
    • 복식문화연구
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    • 제25권5호
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    • pp.648-655
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    • 2017
  • This study measured dyeing properties under different dyeing conditions and levels of antimicrobial activity when man-made fibers are dyed with gallnut, including rayon, tencel, tencel blended fabric, soybean fiber, and nylon non-mordanted. The dye up-take (K/S), color ($L^*a^*b^*$), and color differences (${\Delta}E$) were measured with a colorimeter, and the number of bacteria present in the dyed fabrics were determined using Staphylococcus aureus and Klebsiella pneumonia as strains. The results are as follows: First, the optimal dyeing conditions for man-made fibers dyed with gallnut are 60 minutes of dyeing time and a $80^{\circ}C$ dyeing temperature. Second, gallnut dye is most effective on soybean fiber and then, in descending order of effectiveness, on nylon, rayon, tencel, and tencel blended fabric. This means that dyeing properties of nitrogen containing fibers are excellent when using gallnut. Third, all man-made fibers are dyed brown with gallnut. This implies dyeing possibility of man-made fibers about gallnut dye, so development and supply of natural dyed goods of man-made fibers can be increased. Fourth, in all man-made fibers dyed with gallnut extract, both Staphylococcus aureus and Klebsiella pneumonia show 99.9% reduction ratios of fungistasis, which indicate antimicrobial activity. Therefore, safe, functional, man-made materials can be developed to relieve symptoms from and treat patients with skin ailments.

생물자원 폐기물을 활용한 친환경 가죽염색(III): 매리골드와 편백나무 잎 추출물의 복합염색에 의한 기능성 부여 (Eco-friendly Leather Dyeing Using Biomass Wastes(III): Imparting Functionality by Combination Dyeing with Marigold (Tagetes erecta L.) and Hinoki Cypress(Chamaecyparis obtusa) Leave Extracts)

  • 이건희;신윤숙
    • 한국염색가공학회지
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    • 제31권1호
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    • pp.1-13
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    • 2019
  • In this study, eco-friendly functional leather was developed by recycling wastes such as eel skin, marigold(Tagetas erecta l.), hinoki cypress(Chamaecyparis obtusa). The hot water extracts of marigold and hinoki cypress leaves were freeze-dried at $-80^{\circ}C$ to prepare colorant powder. The dyeing of eel leather with marigold was carried out to investigate the effects of dyeing conditions, mordanting on dye uptake, color, morphological change, and color fastness. Considering shrinkage of eel leather caused by dyeing, the optimum dyeing conditions were $60^{\circ}C$ of dyeing temperature and 60 min of dyeing time at 1:100 of bath ratio, and color of the dyed eel leather was Y to YR Munsell series. In order to prevent the degradation of leather from microbe, we conducted combination dyeing with marigold and hinoki cypress leave colorants. In this case, the combination dyed eel leathers showed excellent antimicrobial activity with above 99% bacterial reduction rate against S. aurieus and K. pneumoniae. It was confirmed that all of the dyed eel leathers were sufficient to meet the Korean Standard for color fastness of leather products. It can be applied practically for the development of eco-friendly functional leather by utilizing some useful active components extracted from plant resources and by recycling food wastes.

차가버섯 추출염액을 이용한 닥섬유 혼방직물의 염색성과 항균효과 (Dyeing Properties and the Antibacterial Activity of Mulberry Fiber/Cotton Blended Fabrics with Inonotus obliquus)

  • 김성희
    • 한국의류학회지
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    • 제34권3호
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    • pp.472-479
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    • 2010
  • The dyeing properties of mulberry fiber/cotton blended fabric with Inonotus obliquus are studied through the investigation of the effects of dyeing conditions, such as the concentration of Inonotus obliquus extract colorants, dyeing temperature, time, and pH values on dye uptakes (K/S). In addition, the effects of mordant on the dye uptakes and antibacterial activities are investigated. The results are summarized as follows. The dye uptakes of dyed fabric increased gradually with an increase concentration of Inonotus obliquus extract colorants, the K/S value was the highest when the dyeing temperature was $60^{\circ}C$ for a duration of 60 minutes. As the pH value of the dyeing solution changed to more acidic, the dyeability of the, fabric was improved. The K/S value recorded the highest at pH 3. The antibacterial activities of dyed and unmordanted mulberry fiber/cotton blended fabric showed a high Staphylococcus aureus reduction rate.