• Title/Summary/Keyword: Reduction/dyeing

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Optimum Dosage of Fenton's Reagent for the Dyeing Wastewater by the Different Conditions of Biological Treatment as the Pre-treatment Process (염색폐수의 생물학적 전처리 조건변화에 의한 최적 펜톤시약 투입량 결정에 관한 연구)

  • Bea Joan-Sam;Lee Sang-Ho
    • Journal of Environmental Science International
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    • v.14 no.7
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    • pp.683-689
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    • 2005
  • The consecutive combination process of a biological process as the pre-treatment and a chemical process as the post-treatment is applied for the dyeing wastewater. The poor efficiency of biological treatment using pure oxygen makes the chemical treatment cost high. It is necessary to improve the efficiency of biological treatment in order to reduce the cost of chemical treatment. The purpose of this paper is to find the minimum dose of chemical reagent to fit the Discharged Water Quality Standards for the different biological treatment effluents. Results revealed that the minimum dosage of Fenton's reagent lead to save the cost of chemical treatment based on the guideline dose in the treatment plant. The possible maximum saving reagents was up to $70\%$ for the effluent of the pilot plant packed with the carrier imbedded microorganisms which were selected from the present treatment plant.

Comparative Analysis of Two Selective Bleaching Methods on Alpaca Fibers

  • Liu, Xin;Hurren, Christopher J.;Wang, Xungai
    • Fibers and Polymers
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    • v.4 no.3
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    • pp.124-128
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    • 2003
  • Dark brown Alpaca fiber was reduced in shade via selective bleaching with peroxide. Two selective oxidative bleaching methods were tested on alpaca top to assess their effectiveness for color removal and fiber quality properties. Color change, bundle strength, weight loss, fiber diameter, surface modification, dye-ability and dye wash fastness were assessed for both methods and compared with the original brown top. Bleach method 1 (BL-I) showed little surface modification, 5.8% weight loss and 2.4% strength loss. D1925 yellowness index was reduced to 74.3 from 83.1 and provided a good base for the dyeing of medium to deep shades. Bleach method 2 (BL-II) displayed considerable surface modification, 7.8% weight loss and 18% strength loss. BL-II also resulted in a mean diameter reduction of 1.9 micron during bleaching. Yellowness was reduced to 64.5 from 83.1 and provided a very good base for the dyeing of medium to deep shades. BL-I showed better exhaustion of the premetallised dye Lanaset Violet B than BL-II. Wash fastness for BL-II was 1 grey scale unit poorer than BL-I. BL-II showed far better color clarity at pale depths however the wash fastness of the finished product was not good enough to maintain the depth or clarity of the color. BL-I showed poorer clarity of color but exhibited better wash fastness results.

Eco-friendly Dyeing using Houttuynia cordata Extract: Dyeability and Functionality of Wool Fabrics (어성초 추출색소를 이용한 친환경 염색: 양모직물의 염색성과 기능성을 중심으로)

  • Son, Kyunghee
    • Textile Coloration and Finishing
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    • v.32 no.1
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    • pp.1-8
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    • 2020
  • The objective was to study the efficiency of Houttuynia cordata extract colorants as eco-friendly and functional dye for wool fabrics. Effects of dyeing conditions and mordanting on dye uptake, color change, and colorfastness were investigated. Also, antimicrobial activity and deodorization performance were evaluated. The Houttuynia cordata colorants showed good affinity to wool fabrics and produced YR Munsell color. The optimum condition of dyeing was 2.0% of colorants concentration(o.w.b.) at 100℃ for 60 minutes under pH 5.3. Regardless of the mordant type and mordanting method, mordants improved dye uptake and the increase in dye uptake by Fe mordant was higher than that of Al mordant. Al post-mordanting and Fe mordanting changed the color of dyed fabrics with Y Munsell color. The colorfastness of un-mordanted and Al post-mordanted fabrics were excellent above grade 4. Bacteria reduction rate(Staphylococcus aureus) of wool fabrics dyed with Houttuynia cordata colorants was excellent at 98.2%. Also, the deodorization was good at 81%. The results show Houttuynia cordata colorants can be used as a functional natural dye for wool fabrics.

Dyeing properties of PET-PU according to molecular structure of disperse dye (분산염료 분자구조에 따른 PET-PU blend의 염색성)

  • Park, Jong-Ho;Lee, Jong-Ryeol;Choe, Yeon-Ji;Lee, Ju-Eun;Kim, Seong-Dong
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2008.04a
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    • pp.80-82
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    • 2008
  • The distributions of 3 disperse dyes with different molecular structures among polyurethane (PU) and polyester (PET) in dyeing PET-PU blend and which dye structure contaminated less PU portion were studied. The amounts of dyes left substrates after reduction clearing and washing were measured to prove which dye structure had an effect on improving washing fastness. Disperse dye with high molecular weight showed similar distribution onto PU and polyester by dying both substrates with similar rate and less contamination to polyurethane while other dyes distributed to PU faster than to PET had.

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New Synthetic Approach to Squarylium Near Infrared Dyes

  • Park, Soo-Youl;Oh, Sea-Wha
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2003.04a
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    • pp.29-31
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    • 2003
  • The 1,3-bis(4-aminoaryl)squaraines showed colour change behaviour, they were found to undergo reduction with sodium borohydride in solution to give colourless leuco compounds, which oxidised readily in air back to the coloured squaraine dye. We have shown that oxidation of the parent leuco-squaraines gives the neutral squaraine system. Initial observations indicated that the derivatives gave new long-wavelength absorbing chromophores, and It is interesting to note that the onidation of the leuco squaraines did initially produce a species absorbing at longer wavelengths than the parent squaraine dye. This colour-change redox behaviour has potential in the area of peroxidase-based bioassays and artificial camouflage.

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The development of dyeing process by ultrasonics wave for clean technology (초음파를 이용한 피혁의 친환경 염색공정 기술 개발)

  • Kim, W.J.;Kim, H.H.;Kim, S.C.;Park, K.S.
    • Clean Technology
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    • v.10 no.1
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    • pp.19-25
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    • 2004
  • The leather was fixed with various colors through the dyeing process in leather manufacturing. During the dyeing process, the amount of 30~50% dyestuff which were not bonded with leather drained with waste water. These dyestuff raise lots of environmental problems, so technology for improving the fixing effect, levelling effect and penentration effect with the use of small amount of dyestuff has been required. Also, insufficient color fastness level 2~3 grade for common natural leather needs to be improved at the same time. Accordingly, the use of ultrasound(us) in dyeing process has decreased the amount of dyestuff and obtained the smooth permeability effect. So, we could find that the reduction of amount of dyestuff in wastewater led to decrease in environmental trouble caused by leather waste water with severe contamination degree and improved fastness up to 0.5 grades.

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Mechanical Characteristics of GF/recycled PET Thermoplastic Composites with Chopped Fiber According to Cross Section (단면형상에 따른 GF/rPET 열가소성 복합재료의 물리적 특성 연구)

  • Kim, Ji-hye;Lee, Eun-soo;Kim, Myung-soon;Sim, Jee-hyun
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.239-246
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    • 2017
  • Recently fiber-reinforced thermoplastic composites have attracted great interest from industry and study because they offer unique properties such as high strength, modulus, impact resistance, corrosion resistance, and damping reduction which are difficult to obtain in single-component materials. The demand for plastics is steadily increasing not only in household goods, packaging materials, but also in high-performance engineering plastic and recycling. As a result, the technology of recycling plastic is also attracting attention. In particular, many paper have studied recycling systems based on recycled thermoplastics. In this paper, properties of Glass Fiber Reinforced Thermoplastic(GFRTP) materials were evaluated using recycled PET for injection molding bicycle frame. The effect on thermal and mechanical properties of recycled PET reinforced glass chop fiber according to fiber cross section and fiber content ratio were studied. And it was compared void volume and torque energy by glass fiber cross section, which is round section and flat section. Mechanical characteristics of resulting in GF/rPET has been increased by increasing fiber contents, than above a certain level did not longer increased. And mechanical properties of flat glass fiber reinforced rPET with low void volume were most excellent.

Evaluation of Hygienic Properties and Effects of Printing on Curcuma- and Coffee-Dyed Cotton Fabrics (강황, 커피염색 면직물의 위생학적 성능과 Printing의 영향 평가)

  • Park, Soon Ja
    • The Korean Journal of Community Living Science
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    • v.28 no.1
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    • pp.143-154
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    • 2017
  • This study was conducted to develop fabrics using non-toxic and eco-friendly natural dyes made from curcuma and coffee extract. The natural dyes were applied to non-printed cotton fabrics using the dip dyeing method, and the pattern was hand-printed onto the dyed fabrics to make dyed printed-fabrics. The four types of developed fabric samples were compared to analyze the effects of the dyeing materials and printing on the hygienic properties of curcuma- and coffee-dyed fabrics. The findings were as follows. First, air permeability of both curcuma- and coffee-dyed fabrics was greatly affected by the presence of patterns, although the type of dye did not seem to have an effect. Printing greatly reduced air permeability of the fabric, and coffee-dyed fabric showed greater reduction of dyeing method than curcuma-dyed fabric. Moisture regain also tended to decrease with printing, but the change was much smaller compared to air permeability. Second, increased UV blockage was observed in curcuma- and coffee-dyed fabrics with patterns compared to non-printed fabrics, showing that printing enhanced UV blocking. Third, deodorization rate tended to increase sharply for both curcuma- and coffee-dyed fabrics until 30 minutes and gradually increased thereafter to yield 30% for curcuma and 50% for coffee at 120 minutes, demonstrating higher deodorization of coffee dye. Coffee-dyed fabric showed an antibacterial rate about twice as high as that of curcuma-dyed fabric, and the observed data suggest that curcuma-dyed fabric had an insignificant level of antibiosis. Fourth, printing significantly enhanced wash, sunlight, and compound colorfastness of the two types of dyed fabrics. The effect of printing was most dramatic on sunlight and compound colorfastness, which are aspects in which natural dyed fabrics perform poorly in general. Eventually, the development and application of biologically- and environmentally-friendly fabrics with natural dyes correspond with increased interest towards the wellness and healthy attitudes of modern society.

Dyeing Properties of Acetate/Functional Polyester Composite Yarn in Different Yarn Twisting Processes (연사방법에 따른 아세테이트/기능성 폴리에스터 복합사의 염색성에 관한 연구)

  • Kim, So-Jin;Jeon, Dong-Won;Park, Young-Hwan
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.2 s.150
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    • pp.255-265
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    • 2006
  • The purpose of this study was to examine the dyeing properties of four kinds of composite yams that were twisted in different processes. The composite yarns consist of acetate and functional polyester in ratio of 70 : 30. The composite yams were dyed at 100$^{circ}C$ and 125$^{circ}C$ using three types of dyes, disperse dyes for acetate fiber, PET fiber and PET-acetate blended fiber, in the three primary colors. The exhaustion($\%$) and K/S value were observed for each case. Also the effects of four different twisting processes to dyeing properties and physical properties were examined. Regardless of twisting methods, the composite yarns that were dyed at 125$^{circ}C$ had higher exhaustion($\%$) than those were dyed at 100$^{circ}C$ with all three types of dyes; However, tendency of the K/S value after reduction cleaning process was measured at 100$^{circ}C$ and the value measured 125$^{circ}C$ had a great difference with disperse dyes for acetate and dyes for PET. The difference of the K/S values of composite yarns, when dyed at 100$^{circ}C$ and 125$^{circ}C$ with disperse dyes for PET-acetate blended fiber, was almost negligible. According to twisting methods K/S values were in the following order: AP1 > AP3 > AP4> AP2. This means that AP1, treated at 220$^{circ}C$, had the highest K/S value and K/S value becomes higher as the yam is higher twisted and becomes lower as lower twisted. On the other hand, the dry shrinkage and wet shrinkage showed low shrinkage rate when the twist was high and steam setting temperature was high.

Eco-friendly, natural dyeing of linen, ramie, and hemp fabrics using Polygonum tinctoria (친환경을 위한 마직물(아마, 저마, 대마)의 쪽 천연염색에 관한 연구)

  • Mikyoung Kim
    • The Research Journal of the Costume Culture
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    • v.31 no.2
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    • pp.161-172
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    • 2023
  • In this study, natural dyeing using Polygonum tinctoria was performed with linen, ramie, and hemp, which are biodegradable cellulose fibers, considering environmental aspects. In particular, the impacts of alkali NaOH and reducing agent Na2S2O4 were examined, and the possibilities of minimizing the use and reusing the dye were explored. The surface dye concentrations were found to be in the following order: hemp>linen>ramie. With the increase in all additives, the L* value decreased, and the ⊿E and K/S values increased gradually. When Na2S2O4 was 1g/L, the surface color of the dye appeared uniformly from the NaOH concentration of 0.4g/L (pH 10.84). When NaOH was 0.4g/L, the K/S values of linen and ramie increased rapidly after 0.4g/L of Na2S2O4, and hemp maintained a stable color from 0.6g/L of Na2S2O4. With the increase in the dye concentration from 1 to 6g/L, all the fibers were dyed uniformly. The K/S value increased or higher doubled upon repeated dyeing six times for 5 min than when dyed only once for 30 min. Therefore, the linen, ramie, and hemp fibers dyed repeatedly exhibited good washing, rubbing, and colorfastness to perspiration, which was rated between 4 and 4-5, and that to light was rated as 5. Moreover, no discoloration due to sunlight was observed. Finally, linen exhibited a bacterial reduction of 99.9%, thereby indicating its excellent antibacterial property.