• 대한기계학회논문집B
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• 제30권2호
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• pp.101-109
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• 2006

The narrow band-averaged transmissivity of $CO_2-H_2O$ mixtures is expressed by multiplying the transmissivities of $CO_2\;and\;H_2O$. Applying the multiplication property of narrow band transmissivities for gas mixtures of $CO_2-H_2O$ of the narrow band based WSGGM (weighted sum of gray gases model), the number of gray gases, required for accurate representation of the absorption characteristics by using the narrow band based WSGGM, is significantly increased. To reduce the computational loads by reducing the number of gray gases, we propose a gray gas regrouping process where the gray gases used for .the WSGGM are regrouped into a specified number of groups according to the magnitudes of absorption coefficients. To evaluate the proposed WSGGM for gas mixtures, the radiative transfer problems through 3-dimensional gas media are considered. The radiative source terms and the radiative heat fluxes obtained by using the proposed method are fairly well compared to previous results obtained by using the SNB model and other models. The regrouping technique results in an excellent computational efficiency with minor loss of accuracy.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 추계학술발표대회
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• pp.16.1-16.1
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• 2011

Gas sensor properties of $WO_3$ nanowire structures have been studied. The sensing layer was prepared by deposition of tungsten metal on porous single wall carbon nanotubes followed by thermal oxidation. The morphology and crystalline quality of $WO_3$ material was investigated by SEM, TEM, XRD and Raman analysis. A highly porous $WO_3$ nanowire structure with a mean diameter of 82 nm was obtained. Response to CO, $NH_3$ and $H_2$ gases diluted in air were investigated in the temperature range of $100{\sim}340^{\circ}C$ The sensor exhibited low response to CO gas and quite high response to $NH_3$ and $H_2$ gases. The highest sensitivity was observed at $250^{\circ}C$ for $NH_3$ and $300^{\circ}C$ for $H_2$. The effect of the diameters of $WO_3$ nanowires on the sensor performance was also studied. The $WO_3$ nanowires sensor with diameter of 40 nm showed quite high sensitivity, fast response and recovery times to $H_2$ diluted in dry air. The sensitivity as a function of detecting gas concentrations and gas sensing mechanism was discussed. The effect of dilution carrier gases, dry air and nitrogen, was examined.

• Journal of Korean Society for Atmospheric Environment
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• 제15권E호
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• pp.29-38
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• 1999

This study identified emission sources and emissions of air pollutants such as volatile organic compounds (VOCs), solvents, and acid gases produced from chemical plants. We collected air samples from various processes, reactors and facilities using VOC detectors and workers' experience. We identified chemical structures and emission concentrations of air pollutants. We analyzed total emissions of air pollutants emitted from the chemical plants. Also, we developed some emission reduction technologies based on chemical types and emission situations of the identified air pollutants. For reduction of air emissions of acid gases, we employed a method improving solubility of pollutants by reducing scrubber operation temperature, increasing surface area for effective contact of gas and liquid, and modifying or changing chemicals used in the acid scrubbers. In order to reduce air emissions of both amines and acid gases, which have had different emission sources each other but treated by one scrubber, we first could separate gas components. And then different control techniques based on components of pollutants were applied to the emission sources. That is, we first applied condensation and then acid scrubbing method using H2SO4 solution for amine treatment. However, we only used an acid scrubbing method using H2O and NaOH solution for acid gas treatment. In order to reduce air emissions of solvents such as dimethylformamide and toluene, we applied condensation and activated carbon adsorption. In order to reduce air emissions of mixture gases containing acid gases and slovents, which could not be separated in the processes, we employed a combination of various air pollution control devices. That is, the mixture gases were passed into the first condenser, the acid scrubber, the second condenser, and the activated carbon adsorption tower in sequence. In addition, for improvement of condensation efficiency of VOCs, we changed the type of the condensers attached in the reactors as a control device modification. Finally, we could successfully reduce air emissions of pollutants produced from various chenmical processes or facilities by use of proper control methods according to the types and specific emission situations of pollutants.

• 한국재료학회:학술대회논문집
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• 한국재료학회 1998년도 IUMRS-ICEM ABSTRACT BOOK
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• pp.88.3-88
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• 1998

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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• pp.460-463
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• 2002

$MoO_3$ thin films were deposited on electrode and heater screen-printed alumina substrates in $O_2$ atmosphere by RF reactive sputtering using Molybdenum metal target. The deposition was performed at $300^{\circ}C$ with 350W of a forward power in an $Ar-O_2$ atmosphere. The working pressure was maintained at $3{\times}10^{-2}mtorr$ and all deposited films were annealed at $500^{\circ}C$ for 5hours. To investigate gas sensing characteristics of the addition doped $MoO_3$ thin film, Co, Ni and Pt were used as adding dopants. The sensing properties were investigated in tenn of gas concentration under exposure of reducing gases such as $H_2$, $NH_3$ and CO at optimum working temperature. Co-doped $MoO_3$ thin film shows the maximum 46.8% of sensitivity in $NH_3$ and Ni-doped $MoO_3$ thin film exhibits 49.7% of sensitivity in $H_2$.

• 한국전기전자재료학회논문지
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• 제16권8호
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• pp.705-710
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• 2003

MoO$_3$thin films were deposited on electrode of alumina substrates in $O_2$atmosphere by RF reactive sputtering using molybdenum metal target. The deposition was performed at 30$0^{\circ}C$ with 350 W of a forward power in an Ar-O$_2$atmosphere. The working pressure was maintained at 3$\times$10$^{-2}$ torr and all deposited films were annealed at 50$0^{\circ}C$ for 5 hours. The surface morphology of films was observed by using a SEM and crystalline phases were analyzed by using a XRD. To investigate gas sensing characteristics of the doped MoO$_3$thin film, Co, Ni and Pt were used as dopants. The sensing properties were investigated in term of gas concentration under exposure of reducing gases such as H$_2$, NH$_3$and CO at optimum working temperature. Co-doped MoO3 thin film shows the maximum 46.8 % of sensitivity in NH$_3$ and Ni-doped MoO$_3$thin film exhibits 49.7 % of sensitivity in H$_2$.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2009년도 춘계학술발표대회 논문집
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• pp.102-108
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• 2009

Fossil power plants firing lower grade coals or equipped with modified system for NOx controls are challenged with maintaining good combustion conditions while maximizing generation and minimizing emissions. In many cases significant derate, availability losses and increase in unburned carbon levels can be attributed to poor combustion conditions as a result of poorly controlled local fuel and air distribution within the boiler furnace. In order to develop a on-line combustion tuning system, field test was conducted at operating power boiler. During the field test the exhaust gases' $O_2$, NOx and CO was monitored by using a spatially distributed monitoring grid located in the boiler's high temperature vestibule and upper convective back-pass region. At these locations, the flue gas flow is still significantly stratified, and air in-leakage is minimal which enables tracing of poor combustion zones to specific burners and over-fire air ports. using these monitored information we can improving combustion at every point within the furnace, therefore the boiler can operate at reduced excess $O_2$ and gas temperature deviation, reduced furnace exit gas temperature levels while also reducing localized hot spots, corrosive gas conditions, slag or clinker formation and UBC. Benefits include improving efficiency, reducing NOx emissions, increasing output and maximizing availability. Discussion concerning the reduction of greenhouse gases is prevalent in the world. When taking a practical approach to addressing this problem, the best way and short-term solution to reduce greenhouse gases on coal-fired power plants is to improve efficiency. From this point of view the real time optimized combustion tuning approach is the most effective and implemented with minimal cost.

• 한국태양에너지학회 논문집
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• 제29권5호
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• pp.45-52
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• 2009

Fossil power plants firing lower grade coals or equipped with modified system for $NO_x$ controls are challenged with maintaining good combustion conditions while maximizing generation and minimizing emissions. In many cases significant derate, availability losses and increase in unburned carbon levels can be attributed to poor combustion conditions as a result of poorly controlled local fuel and air distribution within the boiler furnace. In order to develop a on-line combustion tuning system, field test was conducted at operating power boiler. During the field test the exhaust gases' $O_2,\;NO_x$ and CO was monitored by using a spatially distributed monitoring grid located in the boiler's high temperature vestibule and upper convective rear pass region. At these locations, the flue gas flow is still significantly stratified, and air in-leakage is minimal which enables tracing of poor combustion zones to specific burners and over-fire air ports. using these monitored information we can improving combustion at every point within the furnace, therefore the boiler can operate at reduced excess $O_2$ and gas temperature deviation, reduced furnace exit gas temperature levels while also reducing localized hot spots, corrosive gas conditions, slag or clinker formation and UBC. Benefits include improving efficiency, reducing $NO_x$ emissions, increasing output and maximizing availability. Discussion concerning the reduction of greenhouse gases is prevalent in the world. When taking a practical approach to addressing this problem, the best way and short-term solution to reduce greenhouse gases on coal-fired power plants is to improve efficiency. From this point of view the real time optimized combustion tuning approach is the most effective and implemented with minimal cost.

• 한국가스학회지
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• 제14권1호
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• pp.15-20
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• 2010

최근 들어 유럽 및 미국을 중심으로 각광받고 있는 가스화 열병합 설비는 석탄이나 바이오매스, 폐기물로부터 지역의 전기 및 냉난방 에너지를 공급하는 중소형 규모의 에너지 시스템으로서 시장적 측면이나 기술적 측면에서 그 활용 가능성이 매우 밝은 것으로 예견되고 있다. 가스화로부터 얻어지는 합성가스는 일반적으로 가스엔진, 스털링 엔진, 마이크로 가스터빈 및 중소형 가스터빈 등이 원동기 연료로 사용될 수 있다. 그러나 가스화를 통한 합성가스는 일반적으로 LPG, CNG와 같은 고발열량 가스연료에 비해 발열량이 낮고, 반응성 및 화염속도도 매우 큰 차이를 보인다. 본 연구는 저발열량의 합성가스연료를 이용한 고효율 전소엔진 개발의 전 단계로서 60kW급 디젤혼소엔진을 개발하였다. 저발열량의 합성가스를 모사하기 위해 CNG에 질소를 희석한 연료를 사용하였으며, 디젤 연료 분사를 제어하기 위한 인젝터 드라이버 및 ECU를 적용하였다.

• 한국환경교육학회지:환경교육
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• 제23권2호
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• pp.65-81
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• 2010

Universities which have taken an important role to develop the human resources, became one of emitters of greenhouse gases, they need to find a way to reduce global warming gases through reduction of energy consumption. This study is intented to propose a solution that can reduce the greenhouse gases at universities located in Korea. To conduct this study, we have chosen a university at Wonju in Kangwon province for a case study and investigated the emissions of carbon dioxide from campus facilities and residential area. The data has become a footstone to estimate the assumed amount of carbon emission for top 23 energy consumption universities in Korea. We calculate the amount for carbon emission, not only for facilities in campus, but also for residential buildings, amount for emission is increased severely by showing $9780.94tCO_2$, which is 2.1 times more than average amount for emission of greenhouse gases researched in existing statistics. Universities have difficulty in introducing new energy generation system, as having been done business companies or other commercial facilities but they are required to introduce some educational methods since it is a academic space. Incentive to universities reducing carbon emission in campus is a system to provide incentives with students, professors, administrative personnels and others in campus as a compensation for their efforts to save energy. It is needed to establish the infrastructures for measuring energy consumption in campus.