• Title/Summary/Keyword: Reducing $CO_2$

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Analysis of Nano-particle and Emissions Characteristics for FTP75 Mode in LPLi Vehicle (FTP75 모드에 의한 LPG액상분사자동차의 배출가스 및 나노입자배출특성)

  • Lee, Ho-Kil;Kim, Yong-Tae
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.2
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    • pp.161-167
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    • 2009
  • The regulation of the $CO_2$ emit from vehicles have become much more stringent in recent years. This stringent regulation is more request vehicle manufacturers to develop the alternative fuel vehicles for reducing exhaust emissions. LPG fuel is more clean energy compares with gasoline and diesel fuel. Especially, $CO_2$ emission of LPG Vehicle is less than gasoline vehicle and almost equal to diesel vehicle. For this reason, recently korean government is extending LPG fuel for hybrid car and light duty vehicle. In domestic, Propane is mixing $15{\sim}30%$ to butane for improvement of cold start at winter season. Therefore, In this paper was investigated that the characteristics of emissions according to propane mixing rate with 0, 10, 20, 30% were compared and analyzed by the vehicle test using LPG vehicle according to the FTP75 mode. It was also investigated the characteristics of nano-particle emit with propane mixing rate.

Effect of O2, CO, and NO on the Surface Segregation in a Rh50Pd50 Bulk Crystal and a comparison to Rh50Pd50 Nanoparticles

  • Park, Mi-Ta;Grass, Michael E.;Aksoy, Funda;Zhang, Yawen;Liu, Zhi;Mun, Bong-Jin S.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.84-84
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    • 2010
  • We present an in-situ study of the interaction of a bimetallic Rh50Pd50 bulk crystal with O2, CO, and NO using ambient pressure x-ray photoelectron spectroscopy and compare it to results for 10 nm nanoparticles with the same overall composition. The surface of the bulk crystal has less Rh present under both oxidizing and reducing conditions than the nanoparticles under identical conditions. Segregation and oxidation/reduction proceeds quicker and at lower temperature for nanoparticles than for the bulk crystal. The near surface of the Rh50Pd50 bulk crystal after high temperature vacuum annealing is ca. 9% Rh measured by XPS. Heating in 0.1 Torr O2 to $350^{\circ}C$ increases the Rh surface composition to ca. 40%. The surface can then be reduced by heating in H2 at $150^{\circ}C$, leading to a reduced surface of 30% Rh. Titration of CO from this Rh-rich surface proceeds at a much lower pressure than on the Rh-deficient starting surface.

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A Study of GHG-AP Integrated Inventories and Alternative Energy Use Scenario of Energy Consumption in the University (대학 내 에너지 소비에 따른 온실가스-대기오염 통합 인벤토리 및 대체 에너지 사용 시나리오 분석)

  • Jung, Jae-Hyung;Kwon, O-Yul
    • Journal of Environmental Science International
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    • v.23 no.9
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    • pp.1643-1654
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    • 2014
  • The university is one of the main energy consumption facilities and thereby releases a large amount of greenhouse gas (GHG). Accordingly, efforts for reducing energy consumption and GHG have been established in many local as well as international universities. However, it has been limited to energy consumption and GHG, and has not included air pollution (AP). Therefore, we estimated GHG and AP integrated emissions from the energy consumed by Seoul National University of Science and Technology during the years between 2010 and 2012. In addition, the effect of alternative energy use scenario was analysed. We estimated GHG using IPCC guideline and Guidelines for Local Government Greenhouse Inventories, and AP using APEMEP/EEA Emission Inventory Guidebook 2013 and Air Pollutants Calculation Manual. The estimated annual average GHG emission was $11,420tonCO_{2eq}$, of which 27% was direct emissions from fuel combustion sectors, including stationary and mobile source, and the remaining 73% was indirect emissions from purchased electricity and purchased water supply. The estimated annual average AP emission was 7,757 kgAP, of which the total amount was from direct emissions only. The annual GHG emissions from city gas and purchased electricity usage per unit area ($m^2$) of the university buildings were estimated as $15.4kgCO_{2eq}/m^2$ and $42.4tonCO_{2eq}/m^2$ and those per person enrolled in the university were $210kgCO_{2eq}$/capita and $577kgCO_{2eq}$/capita. Alternative energy use scenarios revealed that the use of all alternative energy sources including solar energy, electric car and rain water reuse applicable to the university could reduce as much as 9.4% of the annual GHG and 34% of AP integrated emissions, saving approximately 400 million won per year, corresponding to 14% of the university energy budget.

A Study on Effect of a Combined Plasma EGR System upon Soot CO and $CO_2$ Emissions in Turbo Intercooler Common-rail Diesel Engines (터보 인터쿨러 커먼레일 디젤기관의 매연, CO 및 $CO_2$ 배출물에 미치는 플라즈마 EGR 조합시스템의 영향에 관한 연구)

  • Bae, Myung-Whan;Ku, Young-Jin;Lee, Bong-Sub;Youn, Il-Joong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.4
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    • pp.1-11
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    • 2006
  • The aim in this study is to develop the combined EGR system with a non-thermal plasma reactor for reducing exhaust emissions and improving fuel economy in turbo intercooler ECU common-rail diesel engines. In this study, the characteristics of soot, CO and $CO_2$ emissions under four kinds of engine loads are experimentally investigated by using a four-cycle, four-cylinder, direct injection type, water-cooled turbo intercooler ECU common-rail diesel engine with a combined plasma exhaust gas recirculation(EGR) system operating at three kinds of engine speeds. The EGR and non-thermal plasma reactor system are used to reduce $NO_x$ emissions, and the non-thermal plasma reactor and turbo intercooler system are used to reduce soot and THC emissions. The plasma system is a flat-to-flat type reactor operated by a plasma power supply. The fuel is sprayed by pilot and main injections at the variable injection timing between BTDC $15^{\circ}$ and ATDC $1^{\circ}$ according to experimental conditions. It is found that soot emissions with increasing EGR rate are increased, but are decreased as the applied electrical voltage of the non-thermal plasma reactor is elevated at the same engine speed and load. Results also show that CO and $CO_2$ emissions are increased as EGR rate is elevated, and CO emissions are increased, but $CO_2$ emissions are decreased as the applied electrical voltage of the non-thermal plasma reactor is elevated at the same engine speed and load.

Potential of Lilium lancifolium in Alleviating Pain and Inflammation in a Rat Model of Monosodium Iodoacetate-Induced Osteoarthritis

  • Kim, Jisoo;Kim, Joo Yun;Jeong, Ji-Woong;Choi, Il dong;Park, Soo-Dong;Lee, Jung Lyoul;Sim, Jae-Hun
    • Korean Journal of Plant Resources
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    • v.33 no.6
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    • pp.638-644
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    • 2020
  • Lilium lancifolium (LL) is widely cultivated in East Asia and used to attenuate airway diseases. Our current study aimed to investigate the therapeutic effect of LL on pain level and inflammatory response in a rat model of monosodium iodoacetate (MIA)-induced osteoarthritis (OA). We first examined the effect of LL on inflammatory cytokines and inflammatory mediators in IL-1β-treated HTB-94 cells. The LL extract was found to significantly inhibit the levels of Interleukin-6 (IL-6), Interleukin-8 (IL-8), and prostaglandin-E2 (PGE-2) in Interleukin-1 β (IL-1β)-stimulated HTB-94 cells in a dose-dependent manner. Moreover, chronic oral administration of LL effectively restored the weight-bearing distribution in the rat model of MIA-induced OA. In addition, administration of LL inhibited inflammatory cytokines and inflammatory mediators, such as C-reactive protein (CRP), IL-6, leukotriene B4 (LTB-4), PGE-2, and matrix metalloproteinase-9 (MMP-9). Our findings collectively suggested LL as one of the potential therapeutic agents for OA, owing to its properties of reducing pain and inflammatory responses.

Effect of Carbon Materials on the Slag Foaming in EAF Process (전기로 슬래그 포밍에 미치는 가탄재 종류의 영향)

  • Kim, Young-Hwan;Yoo, Jung-Min;Um, Hyung-Sic
    • Resources Recycling
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    • v.28 no.2
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    • pp.40-45
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    • 2019
  • During steelmaking in EAF, recycled scraps is used as a main material, melted by arc, and electricity use as a main energy. Slag foaming is an important technology for reducing electrical energy. CO gas generated by the reaction between injection carbon and (FeO), [C] and injection {$O_2$}. CO gas generated by this reaction is collected in slag, resulted in slag foaming. In general, the carbon materials used in the EAF process is anthracite and coke. This study investigated the effects of the carbon materials used on slag foaming in the steelmaking process. As a result of this study, the slag foaming height is increased by cokes rather than anthracite, and with an increase in the amount of particles samller than $500{\mu}m$. Based on these results, the application to the operation resulted in increase of slag forming height, reduction of injection carbon, and reduction of electrical energy.

Synthesis of Fe3O4-δ Using FeC2O4·2H2O by Thermal Decomposition in N2 Atmosphere (N2분위기에서 FeC2O4·2H2O의 열분해에 의한 Fe3O4-δ합성)

  • Park, Won-Shik;Oh, Kyoung-Hwan;An, Suk-Jin;Suhr, Dong-Soo
    • Korean Journal of Materials Research
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    • v.22 no.5
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    • pp.253-258
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    • 2012
  • Activated magnetite ($Fe_3O_{4-{\delta}}$) was applied to reducing $CO_2$ gas emissions to avoid greenhouse effects. Wet and dry methods were developed as a $CO_2$ removal process. One of the typical dry methods is $CO_2$ decomposition using activated magnetite ($Fe_3O_{4-{\delta}}$). Generally, $Fe_3O_{4-{\delta}}$ is manufactured by reduction of $Fe_3O_4$ by $H_2$ gas. This process has an explosion risk. Therefore, a non-explosive process to make $Fe_3O_{4-{\delta}}$ was studied using $FeC_2O_4{\cdot}2H_2O$ and $N_2$. $FeSO_4{\cdot}7H_2O$ and $(NH_4)_2C_2O_4{\cdot}H_2O$ were used as starting materials. So, ${\alpha}-FeC_2O_4{\cdot}2H_2O$ was synthesized by precipitation method. During the calcination process, $FeC_2O_4{\cdot}2H_2O$ was decomposed to $Fe_3O_4$, CO, and $CO_2$. The specific surface area of the activated magnetite varied with the calcination temperature from 15.43 $m^2/g$ to 9.32 $m^2/g$. The densities of $FeC_2O_4{\cdot}2H_2O$ and $Fe_3O_4$ were 2.28 g/$cm^3$ and 5.2 g/$cm^3$, respectively. Also, the $Fe_3O_4$ was reduced to $Fe_3O_{4-{\delta}}$ by CO. From the TGA results in air of the specimen that was calcined at $450^{\circ}C$ for three hours in $N_2$ atmosphere, the ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was estimated. The ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was 0.3170 when the sample was heat treated at $400^{\circ}C$ for 3 hours and 0.6583 when the sample was heat treated at $450^{\circ}C$ for 3 hours. $Fe_3O_{4-{\delta}}$ was oxidized to $Fe_3O_4$ when $Fe_3O_{4-{\delta}}$ was reacted with $CO_2$ because $CO_2$ is decomposed to C and $O_2$.

Possibility of aerobic stabilization technology for reducing greenhouse gas emissions from landfills in Korea (국내 폐기물매립지 온실가스 감축을 위한 호기성 안정화 공법의 적용 가능성)

  • Ban, Jong-Ki;Park, Jin-Kyu;Kim, Kyung;Yoon, Seok-Pyo;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.4
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    • pp.40-51
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    • 2015
  • This study is to estimate the viability of aerobic stabilization technology for reducing greenhouse gas (GHG) emissions from landfills in Korea. In this study, methane emissions were estimated by applying Landfill gas estimation model (LandGEM) to Y landfill in Korea. By comparison of an anaerobic condition (baseline) and an aerobic condition, the amount of $CO_2eq$ savings was calculated. The $CO_2eq$ savings take place inside the landfilled waste during aeration due to the conversion of previously anaerobic biodegradation to aerobic processes, releasing mainly $CO_2$. It was demonstrated that 86.6% of the total GHG emissions occurring under anaerobic conditions could be reduced by aerobic stabilization technology. This means the aerobic stabilization technology could reduce environmental contamination through early stabilization and GHG emissions considerably at the same time. Therefore, the aerobic stabilization technology is one of the optimal technologies that could be employed to domestic landfill sites to achieve sustainable landfill.

Effects of Ceria and CO Reductant on $N_2O$ Decomposition over the Layered Mixed Oxide Catalysts (층상 혼합금속산화물 촉매에 의한 $N_2O$ 분해에서 Ceria 첨가 및 CO 환원제의 영향)

  • Yang, Ki-Seon;Chang, Kil-Sang
    • Clean Technology
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    • v.16 no.4
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    • pp.284-291
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    • 2010
  • Nitrous oxide ($N_2O$) is a greenhouse material which is hard to remove. Even with a catalytic process it requires a reaction temperature, at least, higher than 670 K. This study has been performed to see the effects of Ce addition to the mixed oxide catalyst which shows the highest activity in decomposing $N_2O$ completely at temperature as low as 473 K when CO is used as a reducing agent. Mixed metal oxide(MMO) catalyst was made through co-precipitation process with small amount of Ce added to the base components of Co, Al and Rh or Pd. Consequently, the surface area of the catalyst decreased with the contents of Ce, and the catalytic activity of direct decomposition of $N_2O$ also decreased. However, in the presence of CO, the activity was found high enough to compensate the portion of activity decrease by Ce addition, so that it can be ascertained that the catalytic activity and stability can be maintained in the CO involved $N_2O$ reduction system when Ce is added for the physical stability of the catalyst.

Bioactive Materials and Antioxidant Properties of Fermented Rice-bran Extract (쌀겨발효추출물의 이화학적 특성 및 항산화 작용)

  • Ahn, Hee-Young;Choe, Da-Jeong;Kim, Bo-Kyung;Lee, Jae-Hong;Cho, Young-Su
    • Journal of Life Science
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    • v.25 no.9
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    • pp.1014-1020
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    • 2015
  • This study suggests that fermented rice bran extract contains natural antioxidants. The contents of bioactive materials (e.g., polyphenolic compounds and flavonoids), antioxidative properties (DPPH (α,α'- diphenyl-β-picrylhydrazyl) free radical scavenging activity, Fe reducing, Cu reducing power, peroxidation of linoleic acid and rat hepatocyte microsome) were tested by in vitro experimental models using fermented rice bran (FRB) extract. The concentrations of phenolic compound and flavonoid were 19.92 mg/g and 11.56 mg/g, respectively. In oxidation in vitro models using DPPH free radical scavenging activity, (free radical scavenging activity 69.8%) Fe reducing power and Cu reducing power (effect of dose-dependent manner), Fe2+/ascorbate induced linolenic acid peroxidation by ferric thiocyanate and thiobarbituric acid (TBA) methods (inhibition activity 81%), and autooxidation of rat hepatic microsomes membrane (lipid peroxidation inhibition activity 38%), antioxidative activities were stronger in FRB extract than FRS (Fermented Rice and Soybean, positive control) extract and, these effects were dose-dependent manner. From these results, FRB extract was shown to have the most potent antioxidative properties and contain the highest amounts of antioxidative compounds such as phenolic compounds and flavonoids. Overall, these results may provide the basic data to understand the antioxidative properties of fermented rice bran for development of functional foods.