• 제목/요약/키워드: Reducing $CO_2$

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탄산화 환경에 노출된 RC 지하구조물의 내구수명과 플라이애쉬 배합 특성을 고려한 탄소 배출 및 흡착 평가 (CO2 Emission and Storage Evaluation of RC Underground Structure under Carbonation Considering Service Life and Mix Conditions with Fly Ash)

  • 김성준;문진만;이학수;권성준
    • 한국콘텐츠학회논문지
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    • 제14권12호
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    • pp.999-1009
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    • 2014
  • 본 연구에서는 실제 지하구조물에 사용되었던 제원과 배합에 대하여, 자재생산단계, 운송단계, 시공단계, 탄소저장량, 보수단위 탄소배출량을 고려하여 RC 지하구조물의 탄소배출 및 흡수량을 내구수명에 따라 평가하였다. 혼화재료를 포함한 4가지 배합이 고려되었고, 마이크로 모델을 이용하여 이산화탄소 확산계수를 도출하였다. 탄산화 내구한계상태를 고려하여 탄소 배출 및 흡수량을 평가하였는데, 단위 시멘트량이 높은 배합에서 초기탄소배출량이 높게 평가되었으며, 탄산화 진행속도가 증가함에 따라 이산화탄소 저장량은 증가하였다. 또한 대기 중의 이산화탄소 농도인 실측치(600ppm)이외에 다양한 이산화탄소 농도를 고려하여 RC 지하구조물의 탄소배출 및 흡수량을 평가하였다. 이산화탄소 농도의 증가로 탄산화 진행속도가 증가함에 따라 보수횟수가 증가하여 탄소배출량이 높게 평가되었다. 사용수명동안 전체 탄소 발생량을 감소하기 위해서는 OPC사용을 통해 탄소 흡착량을 늘리는 것보다 플라이애쉬와 같은 혼화재료를 치환하여 초기 탄소배출량을 줄이는 것이 결정적이다. OPC 생산시 과다한 $CO_2$가 발생하고 사용중의 탄소 흡착은 피복콘크리트에 국한하여 큰 효과를 나타내지 못하기 때문이다.

Asswssment of natural attenuation for Gasoline contaminated soil under various reducing conditions

  • 오인석;이시진;장순웅
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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    • pp.255-259
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    • 2004
  • 본 연구에서는 유류오염 토양현장샘플을 이용한 실험실 규모의 회분식 실험을 통해 다양한 환원조건하에서 BTEX와 MTBE의 자연정화 평가 및 현장 생복원 기술 적용 타당성을 검토하는데 있다. 첫째, 오염토양과 비오염 토양에서 충분한 전자수용체의 존재는 유류오염물질의 생분해능을 증가시킬 수 있었음 알았다. 둘째, 같은 토양이라도 전자수용체의 종류와 유류오염물질의 특성에 따른 생분해능의 다양성을 확인할 수 있었다. 셋째, BTEX에 비해 MTBE의 분해가 매우 느림을 확인하였다. 본 실험은 아직 초기 단계의 실험으로 현장 조건을 충분히 만족 시키지는 못한다. 추가적인 pH 변화에 따른 전자수용체의 이용 특성 및 토양-지하수 microcosm test, 혐기성 생분해 부산물인 $CO_2$, $N_2$ 또는 $N_2$O, TBA의 연구가 실시되어야 하겠다.

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$MoO_3$ 박막센서 제조 및 가스감지특성 (Fabrication and Gas Sensing Characteristics of $MoO_3$ Thin Film Sensor)

  • 황종택;장건익
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.826-829
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    • 2002
  • $MoO_3$ thin films were deposited on electrode and heater screen-printed alumina substrates in en atmosphere by RF reactive sputtering. The deposition was performed at $300^{\circ}C$ with 350W of a forward power in an $Ar-O_2$ atmosphere. The working pressure was maintained at $3{\times}10^{-2}$mtorr and all deposited films were annealed at $500^{\circ}C$ for 5hours. The surface morphology of films was observed by using a SEM and crystalline phases were analyzed by XRD. The sensing properties were investigated in term of gas concentration under exposure of reducing gases such as $H_2$, $NH_3$ and CO.

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Impact of Co-transfection with Livin and Survivin shRNA Expression Vectors on Biological Behavior of HepG2 Cells

  • Xu, Wei;Chang, Hong;Qin, Cheng-Kun;Zhai, Yun-Peng
    • Asian Pacific Journal of Cancer Prevention
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    • 제14권9호
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    • pp.5467-5472
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    • 2013
  • Objective: To construct short hairpin RNA (shRNA) eukaryotic expression vectors targeting Livin and Survivin genes, and to explore the impact of co-transfection of Livin and Survivin shRNA expression vectors on the biological behavior of HepG2 cells. Methods: shRNA eukaryotic expression vectors pSD11-Livin and pSD11-Survivin were designed and constructed then transfected into HepG2 cells separately or in combination. mRNA and protein expression in transfected cells was assessed by quantitative fluorescence PCR and Western blotting, respectively. Cell proliferation was measured by MTT assay and cell apoptosis by TUNEL assay. Results: The Livin and Survivin shRNA eukaryotic expression vectors were successfully constructed and transfected into HepG2 cells. The relative mRNA expression levels of Livin and Survivin in HepG2 cells co-transfected with pSD11-Livin and pSD11-Survivin were $0.12{\pm}0.02$ and $0.33{\pm}0.13$, respectively, which was significantly lower than levels in cells transfected with either pSD11-Livin or pSD11-Survivin (P<0.05). The relative protein expression levels of Livin and Survivin in the co-transfected cells were also significantly decreased compared to single-transfection (P<0.05). The inhibition rate of cell growth in the co-transfection group was higher than that in the single-transfection groups at 48 h, 60 h, or 72 h after transfection (P<0.01). The apoptotic rate increased to the greatest extent in the co-transfection group relative to any other group (P<0.05). Conclusions: Co-transfection with pSD11-Livin and pSD11-Survivin was more efficient than transfection with either vector alone in reducing the mRNA and protein expression of Livin and Survivin genes in HepG2 cells. Co-transfection also inhibited the proliferation of transfected cells more than the other groups, and induced cellular apoptosis more effectively.

텅스텐-알루미나 접합거동에 미치는 산소분압의 영향 (Effect of Oxygen Partial Pressure on Tungsten-Alumina Bonding Behavior)

  • 박정현;이상진
    • 한국세라믹학회지
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    • 제27권6호
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    • pp.755-762
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    • 1990
  • The tungsten paste was printed on the surface of 92% alumina sheet which was made by type casting process. The printed tungsten was bonded on the Al2O3 by co-firing in reducing atmosphere. During the co-firing, the binder burn-out was easier in wet H2 atmosphere than in dry H2, which affected sintered density. In practically, the use of wet H2 above 100$0^{\circ}C$ was beneficial for density of alumina and bond strength. This phenomena occured more distinctly when atmosphere varied from dry H2 to wet H2 than varied dew point in wet H2. In wet H2, the improvement in bonding strength can be attributed to good glass migration into the metal layer due to inhibition of the tungsten particle growth, with increase of alumina density, at the temperatrue higher than 100$0^{\circ}C$.

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NFC의 자기 차폐용 Ni-Zn-Co 페라이트 자성체의 고주파 자기특성 (High-frequency Magnetic Properties of Ni-Zn-Co Ferrites Used for Mangetic Shielding in NFC)

  • 류요한;김성수
    • 한국분말재료학회지
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    • 제21권6호
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    • pp.429-433
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    • 2014
  • This study investigated the magnetic properties and frequency dispersion of complex permeability of Ni-Zn-Co ferrites used for magnetic shielding in near field communication (NFC) system. The sintered specimens of $(Ni_{0.7}Zn_{0.3})_{1-x}Co_xFe_2O_4$ composition were prepared by the conventional ceramic processing. The coercive force and saturation magnetization were measured by vibrating sample magnetometer. The complex permeability was measured by RF impedance analyzer in the range of 1 MHz~1.8 GHz. The coercive force increased and saturation magnetization decreased with increasing the Co substitution. The real and imaginary parts of complex permeability decreased and the resonance frequency increased with Co substitution, which was attributed to the increase in crystal anisotropy field and reduction in saturation magnetization. The effect of Co substitution could be found in reducing the magnetic loss to nearly zero at the operating frequency of NFC (13.56 MHz).

시멘트산업의 CO2 배출계수 개발 및 대체연료 사용에 의한 온실가스 저감량 산정 연구 (Development of CO2 Emission Factors for Alternative Fuels with Assessment of Emission Reduction in Cement Industry)

  • 윤석경;명수정;장태혁;김진수;이시형;김기현;전의찬
    • 한국대기환경학회지
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    • 제24권2호
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    • pp.189-195
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    • 2008
  • We developed emission factors for alternative fuels used in cement industries in Korea and also estimated reduction in emissions of greenhouse gas (GHG) by the use of alternative fuels. Emission factors for GHG of waste tire, waste plastic, waste oil and RDF were estimated to be about 89, 78, 77 and 95 ton $CO_2$/TJ respectively. When compared with previous studies, most of the results showed similar trends. The calorific value estimation and elemental analysis for energy source were implemented in order to estimate the exact emission factors and the reduction of GHG emissions using alternative fuel. In the case of 'A' company, $CO_2$ emission from alternative fuels was about 4% lower than that of bituminous coal only. Also in case of company 'B', $CO_2$ emission from alternative fuels was about 1.4% lower than that of only bituminous coal. In Germany and Japan, alternative fuel is not regarded to be fuel consumption in cement industry. When applying this rule, the emission reductions were about 4.3% for company 'A' and 6.3% for company 'B'. The results of this study may be considered as a useful information for developing strategies in reducing GHG emissions.

Preparation of LiCoO$_2$from Used Lithium Ion Battery by Hydrometallurgical Processes

  • Lee, Churl-Kyoung;Rhee, Kang-In;Yang, Dong-Hyo;Yu, Hyo-Shin
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.240-244
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    • 2001
  • Recycling process involving mechanical, thermal, hydrometallurgical, and sol-gel step has been applied to recover cobalt and lithium from spent lithium ion batteries and to synthesize LiCoO$_2$from leach liquor as cathodic active materials. Electrode materials containing lithium and cobalt could be concentrated with 2-step thermal and mechanical treatment. Leaching behaviors of the lithium and cobalt in nitric acid media was investigated in terms of reaction variables. Hydrogen peroxide in 1 M HNO$_3$solution turned out to be an effective reducing agent by enhancing the leaching efficiency. O f many possible processes to produce LiCoO$_2$, the amorphous citrate precursor process (ACP) has been applied to synthesize powders with a large specific surface area and an exact stoichiometry. After leaching used LiCoO$_2$with nitric acid, the molar ratio of Li/Co in the leach liquor was adjusted at 1.1 by adding a fresh LiNO$_3$solution. Then, 1 M citric acid solution at a 100% stoichiometry was also added to prepare a gelatinous precursor. When the precursor was calcined at 95$0^{\circ}C$ for 24 hr, purely crystalline LiCoO$_2$was successfully obtained. The particle size and specific surface area of the resulting crystalline powders were 20 пm and 30 $\textrm{cm}^2$/g, respectively The LiCoO$_2$powder was proved to have good characteristics as cathode active materials in charge/discharge capacity and cyclic performance.

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고체 추진제의 기계물성 최적화 연구 (A Study on the Mechanical Properties Optimization of Solid Propellant)

  • 최용규;류태하;김낙현;김정은
    • 한국추진공학회지
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    • 제19권6호
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    • pp.91-97
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    • 2015
  • HTPB/AP/Al 계열의 혼합형 열경화 추진제를 적용한 로켓 연구개발에 있어서의 추진제 기계물성 규격을 정하는 일련의 과정을 고찰하고, 공정지수를 통하여 추진제 제조에서의 공정관리를 분석하였다. 이를 근간으로 기계물성간의 종속성을 분석하고 최적화 물성을 제시함으로서 불량률을 제거하는 공정 안전도 향상뿐만 아니라 추진제 그레인의 구조적 안전도 상승에도 기여할 것이다.

온실가스배출 감소와 연료절감을 위한 최적 운용절차 방안에 관한 연구 (A Study of Optimized Operation for CO2 Emission and Aircraft Fuel Reduced Operation Procedures)

  • 황정현;이태광;황사식
    • 한국항공운항학회지
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    • 제21권4호
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    • pp.62-70
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    • 2013
  • As the aviation industry looks to the future, fuel saving and $CO_2$ emission reduction play a dominant role in meeting the business challenges presented by global financial uncertainty. The IATA and International Government effort to save fuels, and then save 4 billion gallons of fuel burned, while reducing $CO_2$ emissions by 34 million tons. The various reduction methods adapted airlines and airports. We focused on optimized flight operation procedures for saving fuel and reduction emission cases. IATA and Canada government research reports focused on four methods that Engine Core Washing, Portable Water Management, Single Engine Taxi, APU limit operation. Apply to domestic airlines fuel data, Engine Core washing was saving more than Twenty-four thousand tons $CO_2$ emissions.