• Journal of Korean Society for Atmospheric Environment
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• v.17 no.1
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• pp.51-56
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• 2001

This study was carried out to interpret mathematically hydraulic behaviour in packing tower which packed 50 mm plastic Hiflow-ring with a dimension of 300 mm wide and 1,400 mm high. In view of energy saving, the recent packing. 50 mm plastic Higlow-ring was superior to conventional packings because of low pressure drop in high loads. As relative error between numerically predicted and experimentally obtained values was less then 6% in the loading and flooding point, it found that therir results appeared to be adequate. Comparison of hose two values in both dry and wet packing conditions. relative errors amount to 3.96 and 5.6%, respectively. In order to evaluate the operating characteristics of packing, the type, size, and material for packings must be estimated in various system and loads. This study is able to calculated pressure drop, hold-up, gas and liquid loads using mathematical interpretation. For these calculation, the specific constants of each packings must be calculated first all. The method of mathematical interpretation in this study turned out to be superior to the existing methods because of reduced errors at loading and flooding point.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.1
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• pp.98-105
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• 2005

The effects of chlorination on the elimination of three estrogenic chemicals such as $17{\beta}$-estradiol (E2), nonylphenol (NP) and bis-phenol A (BPA) were investigated using yeast two-hybrid assay (YTA), estrogen receptor competition assay (ER-CA), and high-performance liquid chromatography/mass spectrometer (LC/MS). Results of YTA, ECA and the analysis of LC/MS indicated that the estrogenic activity of above mentioned three endocrine disruptors were significantly reduced as the result of chlorination. The decrease in estrogenic activity paralleled with decrease in estrogenic chemicals under the influence of free chlorine. One common characteristic of estrogenic chemicals is the presence of a phenolic ring. Considering that a phenolic ring is likely to undergo some sort of transformation in aqueous chlorination solution, the above mentioned results may be applied to the rest of the other estrogenic chemicals in natural waters.

• Steel and Composite Structures
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• v.22 no.1
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• pp.183-201
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• 2016

Perforated steel beams can be optimised by increased beam depth and the moment of inertia combined with a reduced web thickness, favouring the use of original I-section beams. The designers are often confronted with situations where optimisation cannot be carried out effectively, taking account of the buckling risk at web posts, moment-shear transfers and local plastic deformations on the transverse holes of the openings. The purpose of this study is to suggest solutions for reducing these failure risks of tested optimal designed beams under applying loads in a self-reacting frame. The design method for the beams is the hunting search optimisation technique, and the design constraints are implemented from BS 5950 provisions. Therefore, I have aimed to explore the strengthening effects of reinforced openings with ring stiffeners, welded vertical simple plates on the web posts and horizontal plates around the openings on the ultimate load carrying capacities of optimally designed perforated steel beams. Test results have shown that compared to lateral stiffeners, ring and vertical stiffeners significantly increase the loadcarrying capacity of perforated steel beams.

• Journal of Power System Engineering
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• v.7 no.3
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• pp.23-28
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• 2003

In heavy nuclear power plant, high energy through main steam line is provided to turbine that generate the electric power. Since plant had generated power, high noise has been occurred. Noise make equipments and work environment worse. For finding out the location and the cause of making noise, noise was measured along main steam line at open/close test of Main Steam Isolation Valve (MSIV hereafter). As the result, it was identified that the vortex shedding in the cavity of MSIV is main noise source. The profile change of MSIV seat ring was proposed as the method of noise reduction. After filletting MSIV seat ring, the noise level reduced $10{\sim}20dB$ compared before the change of profile.

• Archives of Pharmacal Research
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• v.28 no.8
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• pp.877-884
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• 2005

A number of wogonin derivatives have been synthesized as congeners of wogonin and evaluated for their inhibitory activities of $PGE_2$ production. Wogonin derivatives modified at the B ring of wogonin were obtained from 2,4-Dihydroxy-3,6-dimethoxyacetophenone (1) via several steps. Most wogonin derivatives exhibited much reduced inhibitory activities against COX-2 catalyzed $PGE_2$ production compared to that of wogonin. Alkylation of 5,7-phenol groups and substitution at the B ring of wogonin generally caused reduction of inhibitory activity.

• Journal of Microbiology
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• v.33 no.3
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• pp.234-238
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• 1995

The breakdown rate of NAD in Salmonella typhimurium was investigated both in aerobic and anaerobic conditions. After NAD is broken down to nicotinamide ring containing moiety, almost all the nicotinamide ring containing moiety recycles back to NAD pool. However almost none of the adenine containing moiety recycles back. We pulse-label the endogeneous NAD with [$\^$14/C]-adenine and [$\^$3/H]- niacin. The remaining [$\^$14/C]-radioactivity in NAD pool at each time was regarded as unbroken portion of NAD, WHERE AS THE OF [$\^$3/H] was served as a total amount of NAD to start with. Under aerobic condition, the half-life of NAD was around 2 hours. However, the breakdown rate was significantly reduced (around 3-5 fold) under anaerobic condition. The observation that under aerobic conditions, NAD turnover is considerably faster than under anaerobic conditions suggests that oxygen has important effect in NAD breakdown.

• Bulletin of the Korean Chemical Society
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• v.20 no.11
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• pp.1263-1268
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• 1999

The fluorescence properties and photoisomerization behavior of 1-(9-anthryl)-2-(2-quinolinyl)ethene (2-AQE) have been investigated in various solvents. Instead of phenyl ring in 1-(9-anthryl)-2-phenylethene, the intro-duction of quinoline ring reduces not only the fluorescence yield but also the photoisomerization yield, due to competition of efficient radiationless deactivation and an increase in the torsional barrier for twisting in the singlet manifold. The S1 decay parameters were found to be solvent-dependent due to the charge-transfer character of lowest S1 state. Polar solvents reduce the activation barrier to twisting, thus slight enhancing the isomerization of t-2-AQE in the singlet manifold. As solvent polarity is increased, Φf of c-2-AQE is greatly reduced, but Φc →ｔ is practically independent of solvent polarity. Dual fluorescence in t-2-AQE was observed and two fluorescing species could be assigned t-2-AQE and c-2-AQE, where the ratio between two species was dependent on the solvent polarity. Interestingly, in the concentration above 1×10 -4 M, the shapes of the fluorescence excitation spectra of t- and c-2-AQE are significantly altered without spectral changes of their fluorescence and absorption, probably due to the formation of excimer.

• ETRI Journal
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• v.45 no.4
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• pp.581-593
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• 2023

This paper proposes four-ring slot resonator-based MIMO antennas of 75×150 mm² without and with CSRR structures in the sub-6-GHz range. These orthogonal-fed antennas have shown diverse characteristics with dual polarization. L-shaped parasitic structures have increased the isolation (i.e., >40 dB) in the single-element antenna over the band of 3.4 GHz-3.8 GHz. A set of three CSRR structures in the MIMO antenna reduced the coupling between antenna ports placed in an inline arrangement and enhanced the isolation from 12 dB to 20 dB and the diversity characteristics. The S-parameters of both MIMO antennas are measured and used to evaluate MIMO parameters like ECC, TARC, MEG, and channel capacity loss. The simulation results show the variations in the gain and directivity on exciting linear and dual polarizations. The diversity performance of the reported MIMO antennas is suitable for 5G applications.

• YAKHAK HOEJI
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• v.52 no.1
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• pp.20-26
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• 2008

2-Aminothiazole ring as a bioisoster of catechol in dopamine has provided with good oral availability and lipophilic property. Selenium was reported to have an improved antioxidant ability and to reduce the loss of dopamine. 2-Aminoindan, is a rigid form of dopamine, was evaluated as a dopamine agonist with low neurotoxocity. In order to develop a novel dopamine agonist, we tried to synthesize the selenazoloaminoindan derivative that is a hybrid structure of aminoindan and aminoselenazole instead of aminothiazole. 2-Indanone-2-oxime was reduced with $TiCl_4$ and $NaBH_4$ to form 2-aminoindan, which was reacted with propionyl chloride to give 2-N-n-propionylaminoindan (2). Compound 2 was reduced with $TiCl_4$ and $NaBH_4$ to afford 2-N-n-propylaminoindan (3) and it was nitrated and reduced to form 5-amino-2-N-n-propylaminoindan (5), which was reacted with KSeCN, $Br_2$, and glacial acetic acid to give 4,6-dibromo-5- amino-2-N-n-propylaminoindan (7) instead of selenazole ring formation. Otherwise, compound 2 was nitrated and hydrogenated to form 5-amino-2-N-n-propionylaminoindan (9), which was treated with KSeCN, $Br_2$, and glacial acetic acid to give 4,6-dibromo-5-amino-2-N-n-propionylaminoindan (10). Compound 9 was cyc1ized with KSeCN and glacial acetic acid in the absence of $Br_2$ to give 6-amino-2-N-(n-propionylamino)selenazolo[4,5-f]indan (11).

• Bulletin of the Korean Chemical Society
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• v.8 no.4
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• pp.285-291
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• 1987

The approximate rates, stoichiometries and products of the reaction of potassium triethylborohydride $(KEt_3BH)$ with selected organic compounds containing representative functional groups under the standard condition $(0^{\circ}C,$ THF) were examined in order to explore the reducing characteristics of this reagent as a selective reducing agent. Primary alcohols, phenols and thiols evolve hydrogen rapidly whereas secondary and tertiary alcohols evolve very slowly. n-Hexylamine is inert to this reagent. Aldehydes and ketones are reduced rapidly and quantitatively to the corresponding alcohols. Reduction of noncamphor gives 3% exo- and 97% endo-norboneol. Anthraquinone is cleanly reduced to 9,10-dihydro-9,10-dihydroxyanthracene stage. Carboxylic acids liberate hydrogen rapidly and quantitatively but further reduction does not occur. Anhydrides utilize 2 equiv of hydride to give an equimolar mixture of acid and alcohol. Acid chlorides, esters and lactones are rapidly and quantitatively reduced to the corresponding alcohols. Epoxides are reduced at moderate rates with Markovnikov ring opening to give the more substituted alcohols. Primary amides liberate 1 equiv of hydrogen rapidly. Further reduction of caproamide is slow whereas benzamide is not reduced. Tertiary amides are reduced slowly. Benzonitrile utilizes 2 equiv of hydride in 3 h to go to the amine stage whereas capronitrile takes only 1 equiv. The reaction of nitro compounds undergo rapidly whereas azobenzene and azoxybenzene are reduced slowly. Cyclohexanone oxime rapidly evolves hydrogen without reduction. Phenyl isocyanate utilizes 1 equiv of hydride to proceed to formanilide stage. Pyridine N-oxide and pyridine is reduced rapidly. Disulfides are rapidly reduced to the thiol stage whereas sulfoxide, sulfonic acid are practically inert to this reagent. Sulfones and cyclohexyl tosylate are slowly reduced. Octyl bromide is reduced rapidly but octyl chloride and cyclohexyl bromide are reduced slowly.