• Title/Summary/Keyword: Reduced properties

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Electrical Properties of PZT Ceramics Fabricated by Partial Oxalate Method at Low Sintering Temperature (부분수산법에 의한 PZT 세라믹스의 저온소성과 전기적 제특성)

  • Nam, Hyo-Duk;Choi, Se-Gon;Lee, Hee-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.11a
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    • pp.38-41
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    • 1992
  • Pb(Zr,Ti)$O_3$ powders were synthesized by the partial oxalate method and the modified partial oxalate method, where the difference between the two is the use of pre-reacted (Zr,Ti)$O_2$ in the former method. When compared with conventional mixed oxide method, calcination temperature can be reduced to less than $700^{\circ}C$ by both partial oxalate methods, and the resulting particle size was finer and more uniform. Using partial oxalate-derived PZT powders, sintering temperatures can also be reduced as low as $950^{\circ}C$ without sacrificing desired dielectric and piezoelectric properties, such as relative permittivity, electromechanical coupling factor, and piezoelectric coefficient. Two partial oxalate methods yield ceramics with almost the same physical and electrical properties, so that the step of producing ZTO powder does not seem to be necessary.

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Dyeing Characteristics of Herb Dyed Fabrics Treated with Mordants - Focused on Sage and Rosemary Extract - (매염제 처리에 의한 허브 염색직물의 염착 특성 - 세이지와 로즈마리 추출물 중심으로 -)

  • Goo, Sin Ae;Bae, Hyun Sook
    • Fashion & Textile Research Journal
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    • v.22 no.1
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    • pp.119-129
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    • 2020
  • Unlike synthetic dyes, natural dyes do not affect the human body or create atmosphere pollution that are also mothproof, antibiotic and sterilized. This study examined the changes in dye adsorption properties according to mordant types and mordanting method to qualify trends using sage and rosemary extracts. Dyeability of sage extract is often similar to rosemary extract regardless of dyeing conditions. Dyeing properties of herb colorants on cotton, silk and wool fiber and effect of dyeing conditions on dye uptake were also compared. Dyed fabric showed a yellowish color and the dyeing affinity was somewhat good with rosemary extract. The surface color of the dyed fabrics was darkened by mordant treatment. The K/S value of herb colorants of protein fiber was higher than cellulose fiber. The concentration of mordant having the highest dyeing affinity was different from the mordant type. Regardless of the type of fiber, the K/S value of premordanting was the highest in mordanting method, and the K/S value of simultaneous mordanting indicated no noticeable mordant effect. The fastness of washing of silk fabric was reduced the most by mordant treatment. The lightfastness was reduced in Al mordant treatment regardless of the type of fiber. The lightfastness of wool increased somewhat by mordant treatment.

Effect of Dissolved and Colloidal Contaminants of Newsprint Machine White Water on Water Surface Tension and Paper Physical Properties

  • Consultant, Seika-Tay
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.61-69
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    • 1999
  • Contaminants such as fatty acids, triglycerides, resin acids and foam collected from a high yield sulfite weak liquor storage tank lowered the water surface tension and reduced inter-fibre bonding but also tended to benefit sheet opacity. Some common wet end additives such as defoamers and dispersants gave similar results. Lignosulfonate and naphthalene sulfonate showed little if any negative effect on both surface tension and sheet strength properties. Among the natural wood extractives. fatty acids were identified to be most detrimental followed by triglycerides and then resin acids. In order to alleviate the detrimental impact of these contaminants, membrane separation, air floatation and ozone treatment were carried out on paper machine white water samples. The effect of these treatments on removal of fatty and resin acids was quantified by a GC-Mass analysis. Reverse osmosis with a 1000 molecular weight cut off membrane failed to totally reject fatty and resin acids, but markedly reduced losses of sheet properties due to contaminants. Ozone treatment resulted in a significant increase of the surface tension and air floatation was considered to be a practical and useful method for removing fatty and resin acids from the machine white water.

Effects of Hydrogen Reduction in Microstructure, Mechanical and Thermoelectric Properties of Gas Atomized n-type Bi2Te2.7 Se0.3 Material

  • Rimal, Pradip;Yoon, Sang-Min;Kim, Eun-Bin;Lee, Chul-Hee;Hong, Soon-Jik
    • Journal of Powder Materials
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    • v.23 no.2
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    • pp.126-131
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    • 2016
  • The recent rise in applications of thermoelectric materials has attracted interest in studies toward the fabrication of thermoelectric materials using mass production techniques. In this study, we successfully fabricate n-type $Bi_2Te_{2.7}Se_{0.3}$ material by a combination of mass production powder metallurgy techniques, gas atomization, and spark plasma sintering. In addition, to examine the effects of hydrogen reduction in the microstructure, the thermoelectric and mechanical properties are measured and analyzed. Here, almost 60% of the oxygen content of the powder are eliminated after hydrogen reduction for 4 h at $360^{\circ}C$. Micrographs of the powder show that the reduced powder had a comparatively clean surface and larger grain sizes than unreduced powder. The density of the consolidated bulk using as-atomized powder and reduced atomized powder exceeds 99%. The thermoelectric power factor of the sample prepared by reduction of powder is 20% better than that of the sample prepared using unreduced powder.

Effects of Irradiation and Fumigation on Physicochemical Properties of Red Pepper during Storage (감마선과 훈증처리가 건고추의 저장 중 이화학적 특성에 미치는 영향)

  • Kim, Byeong-Keun;Kwon, Joong-Ho
    • Journal of the Korean Society of Food Culture
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    • v.19 no.5
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    • pp.491-498
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    • 2004
  • In order to study the quarantine and sanitization methods for dried red pepper, comparative effects of commercial fumigation (methyl bromide/MeBr, $phosphine gas/PH_{3}$ and gamma irradiation (5, 10 kGy) were investigated in terms of its physicochemical properties. There were no noticeable chances in pH and soluble solids among the untreated control, irradiated and fumigated samples soon after treatments, but some decrease was found in stored samples (especially soluble solid in fumigated samples) for 8 months under room temperature. Total sugar content was influenced by storage time rather than both treatments. Immediately after treatments, reducing sugar content was significantly reduced in the samples including pericarp when exposed to fumigants (p<0.05), while an apparent decrease was observed in the stored samples including seeds with negligible differences among treatment groups. The electron donating ability (EDA) of the extracts was high in the order of pericarp, whole pepper, powdered pepper and seeds, which was reduced during storage for 8 months particularly in the samples containing seeds. The EDA of irradiated samples during storage was equal to that of the control sample, whereas that of fumigated samples was relatively low (p<0.05).

Hydrogen's influence on reduced activation ferritic/martensitic steels' elastic properties: density functional theory combined with experiment

  • Zhu, Sinan;Zhang, Chi;Yang, Zhigang;Wang, Chenchong
    • Nuclear Engineering and Technology
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    • v.49 no.8
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    • pp.1748-1751
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    • 2017
  • Reduced activation ferritic/martensitic (RAFM) steels are widely applied as structural materials in the nuclear industry. To investigate hydrogen's effect on RAFM steels' elastic properties and the mechanism of that effect, a procedure of first principles simulation combined with experiment was designed. Density functional theory models were established to simulate RAFM steels' elastic status before and after hydrogen's insertion. Also, experiment was designed to measure the Young's modulus of RAFM steel samples with and without hydrogen charging. Both simulation and experiment showed that the solubility of hydrogen in RAFM steels would decrease the Young's modulus. The effect of hydrogen on RAFM steels' Young's modulus was more significant in water-quenched steels than it was in tempering steels. This indicated that defects inside martensite, considered to be hydrogen traps, could decrease the cohesive energy of the matrix and lead to a decrease of the Young's modulus after hydrogen insertion.

Reduced Titania Films with Ordered Nanopores and Their Application to Visible Light Water Splitting

  • Shahid, Muhammad;Choi, Seo-Yeong;Liu, Jingling;Kwon, Young-Uk
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2271-2275
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    • 2013
  • We report on the photoelectrochemical properties of partially reduced mesoporous titania thin films. The fabrication is achieved by synthesizing mesoporous titania thin films through the self-assembly of a titania precursor and a block copolymer, followed by aging and calcination, and heat-treatment under a $H_2$ (1 torr) environment. Depending on the temperature used for the reaction with $H_2$, the degree of the reduction (generation of oxygen vacancies) of the titania is controlled. The oxygen vacancies induce visible light absorption, and decrease of resistance while the mesoporosity is practically unaltered. The photoelectrochemical activity data on these films, by measuring their photocurrent-potential behavior in 1 M NaOH electrolyte under AM 1.5G 100 mW $cm^{-2}$ illumination, show that the three effects of the oxygen vacancies contribute to the enhancement of the photoelectrochemical properties of the mesoporous titania thin films. The results show that these oxygen deficient $TiO_2$ mesoporous thin films hold great promise for a solar hydrogen generation. Suggestions for the materials design for improved photoelectrochemical properties are made.

Electrostatic Electrification Properties of Silicone Rubber due to Al Ratios (Al 비율에 실리콘 고무의 정전기 대전 특성)

  • Lee, Sung-Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.8
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    • pp.522-527
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    • 2014
  • In this study, using the silicone rubber sample of $4cm{\times}4cm{\times}0.1cm$ for low voltage cable, the electrostatic electrification properties of three samples that the conductive Al of 0%, 25%, and 50% is attached to the surface of sample was measured. The following conclusion was obtained through this experiment. 1) In case of the sample which has the Al area of 50%, the higher the humidity to 90% in the temperature of $10^{\circ}C$, the electrostatic electrification voltage was reduced about 0.25 kV to 0.02 kV, and it confirmed that the electrostatic electrification voltage was in constant about 0.02 kV in the temperature over $20^{\circ}C$. 2) Increasing the Al area of samples of 0%, 25%, and 50% in temperature of $10^{\circ}C$, it confirmed that the electrostatic electrification voltage was reduced by about 2.67 kV, 2.02 k, 0.21 kV. 3) This study shows that the conductor, followed by temperature and humidity affects the electrostatic electrification voltage.

Application to the design of reduced-order robust MPC and MIMO identification

  • Lee, Kwang-Soon;Kim, Sang-Hoon
    • 제어로봇시스템학회:학술대회논문집
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    • 1997.10a
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    • pp.313-316
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    • 1997
  • Two different issues, design of reduced-order robust model predictive control and input signal design for identification of a MIMO system, are addressed and design techniques based on singular value decomposition(SVD) of the pulse response circulant matrix(PRCM) are proposed. For this, we investigate the properties of the PRCM, which is a periodic approximation of a linear discrete-time system, and show its SVD represents the directional as well as the frequency decomposition of the system. Usefulness of the PRCM and effectiveness of the proposed design techniques are demonstrated through numerical examples.

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A Multi-period Behavioral Model for Portfolio Selection Problem

  • Pederzoli, G.;Srinivasan, R.
    • Journal of the Korean Operations Research and Management Science Society
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    • v.6 no.2
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    • pp.35-49
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    • 1981
  • This paper is concerned with developing a Multi-period Behavioral Model for the portfolio selection problem. The unique feature of the model is that it treats a number of factors and decision variables considered germane in decision making on an interrelated basis. The formulated problem has the structure of a Chance Constrained programming Model. Then empoloying arguments of Central Limit Theorem and normality assumption the stochastic model is reduced to that of a Non-Linear Programming Model. Finally, a number of interesting properties for the reduced model are established.

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