• 대한기계학회논문집B
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• 제31권1호
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• pp.99-108
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• 2007

In this study, the NOx formation characteristics of one-dimensional $CH_4$/Air premixed flame using detailed-kinetic chemistry are examined numerically. The combustor length and the amount of heat loss are varied to investigate the effect of residence time and heat loss on the NOx formation in a post-flame region. In the flame region, NO is mainly produced by the Prompt NO mechanism including $N_2$O-intermediate NO mechanism over all equivalence ratios. However, thermal NO mechanism is more important than Prompt NO mechanism in the post-flame region. In the case of adiabatic condition, the increase of combustor length causes the remarkable increase of NO emission at the exit due to the increase of residence time. On the other hand, NO reaches the equilibrium state in the vicinity of flame region, considering radiation and conduction heat losses. Furthermore the NO, in the case of $\phi$=1.2, is gradually reduced in the downstream region as the heat loss is increased. From these results, it can be concluded that the controls of residence time and heat loss in a combustor should be recognized as an important NOx reduction technology.

• 한국한의학연구원논문집
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• 제9권1호
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• pp.137-144
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• 2003

The objective on this study was to investigate medicinal protection with KH-19, which was composed of 9 kinds of oriental herbs tonifying the blood, against side effect of chemotherapy in mice and its mechanism through microarray. Not only WBC (white blood cell), and PLT (platelet) as a hematopoiesis toxicity indicator but also spleen weight as an immune toxicity indicator was reduced significantly 7 day after. 5-flurouracil (FU) treatment. However, reduction of WBC, PLT, and spleen weight after 5-FU treatment was significantly recovered by KH-19. For mechanic study on KH-19 action, gene expression in mouse spleen treated 5-FU was compared with gene expression in mouse treated 5-FU and KH-19. The result indicates that 23 genes were increased. in expression level over 2 fold and 41 genes were decreased in expression level more than 2 fold at mouse spleen by KH-19 treatment. KH-19 mechanism may be complicated more than other drug which of mechanism were composed of single compound because KH-19 was composed of various compounds.

• Journal of Electrical Engineering and information Science
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• 제2권3호
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• pp.71-76
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• 1997

A lot of experiments and analyses have been done to determine the aging mechanism of mica-epoxy composite material used for large generator stator windings in order to estimate remaining life of the generator for last decades. After degrading artificially the mica-epoxy composite material, the surface analysis is performed to analyze breakdown mechanism of insulation in air and hydrogen atmosphere; i) In the case of air atmosphere, it is observed that an aging propagation from conductor to core by partial discharge effect and the formation of cracks between layers is widely carbonized surface. ii) In case of hydrogen atmosphere, the partial discharge effect is reduced by the hydrogen pressure (4kg/$\textrm{cm}^2$). Potassium ions forming a sheet of mica is replaced by hydrogen ions, which can lead to microcracks. It is confirmed that the sizes of crack by SEM analysis are 10∼20[$\mu\textrm{m}$] in length under air, and 1∼5[$\mu\textrm{m}$] in diameter, 10∼50[$\mu\textrm{m}$] in length under hydrogen atmosphere respectively. The breakdown mechanism of sttor winding insulation materials which are composed of mica-epoxy is analyzed by the component of materials with EDS, SEM techniques. We concluded that the postassium ions of mica components are replaced by H\ulcorner, H$_3$O\ulcorner at boundary area of mica-epoxy and/or mica-mica. It is proposed that through these phenomena, the conductive layers of potassium enable creation of voids and cracks due to thermal, mechanical, electrical and environmental stresses.

• 대한기계학회논문집B
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• 제28권11호
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• pp.1407-1416
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• 2004

A two-dimensional direct numerical simulation was performed to investigate the flame structure of CH$_4$/$N_2$-Air counterflow nonpremixed flame interacting with a single vortex. The detailed transport properties and a modified 16-step augmented reduced mechanism based on Miller and Bowman's detailed chemistry were adopted in this computation. The results showed that an initially flat stagnation plane, on which an axial velocity was zero, was deformed into a complex-shaped plane, and an initial stagnation point was moved far away from a vortex head when the counterflow field was perturbed by the vortex. It was noted that the movement of stagnation point could alter the species transport mechanism to the flame surface. It was also identified that the altered species transport mechanism affected the distributions of the mixture fraction and the scalar dissipation rate.

• International Journal of Automotive Technology
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• 제7권3호
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• pp.295-301
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• 2006

A new combustion method of high compression ratio SI engine was studied and proposed in order to achieve high thermal efficiency, comparable to that of CI engine. Compression ratio of SI engine is generally restricted by the knocking phenomena. A combustion chamber profile and a cranking mechanism were studied to avoid knocking with high compression ratio. Because reducing the end-gas temperature will suppress knocking, a combustion chamber was considered to have a wide surface at the end-gas region. However, wide surface will lead to large heat loss, which may cancel the gain of higher compression ratio operation. Thereby, a special cranking mechanism was adapted which allowed the piston to move rapidly near TDC. Numerical simulations were performed to optimize the cranking mechanism for achieving high thermal efficiency. An elliptic gear system and a leaf-shape gear system were employed in numerical simulations. Livengood-Wu integral, which is widely used to judge knocking occurrence, was calculated to verify the effect for the new concept. As a result, this concept can be operated at compression ratio of fourteen using a regular gasoline. A new single cylinder engine with compression ratio of twelve and TGV(Tumble Generation Valve) to enhance the turbulence and combustion speed was designed and built for proving its performance. The test results verified the predictions. Thermal efficiency was improve over 10% with compression ratio of twelve compared to an original engine with compression ratio of ten when strong turbulence was generated using TGV, leading to a fast combustion speed and reduced heat loss.

• 한국지진공학회논문집
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• 제23권1호
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• pp.43-54
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• 2019

Existing reinforced concrete frame buildings designed for only gravity loads have been seismically vulnerable due to their inadequate column detailing. The seismic vulnerabilities can be mitigated by the application of a column retrofit technique, which combines high-strength near surface mounted bars with a fiber reinforced polymer wrapping system. This study presents the full-scale shaker testing of a non-ductile frame structure retrofitted using the combined retrofit system. The full-scale dynamic testing was performed to measure realistic dynamic responses and to investigate the effectiveness of the retrofit system through the comparison of the measured responses between as-built and retrofitted test frames. Experimental results demonstrated that the retrofit system reduced the dynamic responses without any significant damage on the columns because it improved flexural, shear and lap-splice resisting capacities. In addition, the retrofit system contributed to changing a damage mechanism from a soft-story mechanism (column-sidesway mechanism) to a mixed-damage mechanism, which was commonly found in reinforced concrete buildings with strong-column weak-beam system.

• 로봇학회논문지
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• 제17권2호
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• pp.172-177
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• 2022

In general, detection robots using ultrasonic sensors are equipped with sensors to protrude outward or to contact objects. However, in the case of a screw-propelled robot that detects the inside of a reactor tendon duct, if the ultrasonic sensor protrudes to the outside, resistance due to grease is generated, and thus the propulsion efficiency is reduced. In order to increase the propulsion efficiency, the screw must be sharp, and the sharper the screw, the more difficult it is to apply a high-performance ultrasonic sensor, and the detection efficiency decreases. This paper proposes a screw shape-changing mechanism that can improve both propulsion efficiency and detection efficiency. This mechanism includes an overlapped helical ring (OHR) structure and a magnetic clutch system (MCS), and thus the shape of a screw may be changed to a compact size. As a result, the Screw-propelled robot with this mechanism can reduce the overall length by about 150 mm and change the shape of the screw faster and more accurately than a robot with a linear actuator.

• 전기화학회지
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• 제15권2호
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• pp.83-89
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• 2012

전기화학적 석출에 의해 Ag-Au 합금층을 전극표면에 형성한 후 진한 질산으로 Ag만을 녹여내는 기법으로 나노다공성 금(nanoporous gold, NPG) 구조를 만들어 전기화학적 산소환원에 대한 촉매현상을 관찰하였다. 석출과정의 전구체의 농도비를 달리하였을 때 나타나는 NPG 표면구조의 변화를 주사전자현미경으로 관찰하고 전기화학적 표면적을 측정하였다. 전기화학적 산소환원 촉매 효율은 NPG 표면의 구조에 따라 달라졌는데, Ag/Au 비율이 2.0에 해당하는 NPG 구조에서 가장 우수한 촉매 현상이 관찰 되었다. 표면구조의 변화에 따른 촉매 활성 변화에서 다공성 구조의 역할이 매우 큰 기여를 하는 반면 표면적의 변화는 큰 영향을 미치지 않았다. 최적 조건의 NPG 구조상의 전기화학적 산소환원 과정의 메커니즘을 회전원판전극 실험을 통해 관찰하였는데, 산성 조건에서 NPG 전극에서 전기화학적 산소환원은 과산화수소를 거쳐 물이 생성되는 2-단계 4-전자 환원 메커니즘으로 진행되었고 염기성 조건에서는 산소가 4개의 전자 전달을 통해 물로 직접적으로 환원 되었다.

• Advances in environmental research
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• 제1권1호
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• pp.37-55
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• 2012

Here we show that perchlorate reduction during pitting corrosion of zero-valent titanium (ZVT) is likely caused by dissolved titanium species, especially Ti(II). Several possible mechanisms were suggested based on the literature and were evaluated based on experimental observations. Direct reduction of perchlorate on the bare metal of the ZVT electrode was thermodynamically infeasible due to the high anodic potential that was applied. Other potential mechanisms were considered such as reduction by small ZVT metal particles released from the electrode and direct reduction on the oxide layer of the electrode where potential was sufficiently reduced by a high ohmic potential drop. However, these mechanisms were not supported by experimental results. The most likely mechanism for perchlorate reduction was that during pitting corrosion, in which ZVT is partially oxidized to form dissolved ions such as Ti(II), which diffuse from the electrode surface and react with perchlorate in solution. This mechanism is supported by measurements of the dissolution valence and the molar ratio of ZVT consumed to perchlorate reduced (${\Delta}Ti(0)/{\Delta}ClO_4{^-}$). The results shown in this study demonstrate that ZVT undergoing pitting corrosion has the capability to chemically reduce perchlorate by producing dissolved Ti(II) and therefore, it has the potential to be applied in treatment systems. On the other hand, the results of this research imply that the application of ZVT undergoing pitting corrosion in treatment systems may not be feasible now due to several factors, including material and electricity costs and possible chloride oxidation.

• Toxicological Research
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• 제12권2호
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• pp.195-201
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• 1996

Endotoxic shock causes death in humans and animals via extreme hypoperfusion of peripheral organs. A massive production of nitric oxide (NO) both from the endothelical cells and smooth muscle cells has been proposed as a possible mechanism in this process. Since NO attenuated the contractility to vasoconstricting agents such as norepinephrine (NE) by directly acting on the smooth muscle cells, this mechanism was considered mainly as a postsynaptic mechanism. In this research it was investigated whether NO, thus released, also participates in the presynaptic events for the regulation of vascular tone in endotoxic shock. The role of NO was studied by adding NO donors or NO synthase inhibitor $N^\omega $methyl-L-arginine (NMA) in stimulated sympathetic nerves of the mesenteric vascular bed and the Langendorff heart of rats. Sodium nitroprusside (SNP), an NO donor, reduced the pressor responses of isolated mesenteric artery either to electrical stimulation or exogenously administered phenylephrine (PE). In this mesentery, although neither agent influenced NE release, in the presence of the adrenergic $\alpha_2$-receptor antagonist yohimbine, elecrical stimulation-evoked NE release was augumented by SNP. In the heart SNP facilitated the NE release induced by electrical stimulation, while NMA had no effect. From these results it is proposed that there exists a local reflex phenomenon in the junction between the sympathetic nerve terminals and the smooth muscle of resistance blood vessels; by which sympathetic responses are reduced by NO at the postjunctional level while NO facilitates NE release contributing to augumentation of sympathetic tone. All these facts suggest that NO produced during endotoxic shock has dual effects: whereas NO blunts the vasoconstrictive activity of NE at the postsynaptic level, NO presynaptically facilitates the release of NE from sympathetic nerve terminals.