• 제목/요약/키워드: Recycling capacity

검색결과 297건 처리시간 0.027초

Li(Ni1-x-yCoxMny)O2계 이차전지 공정 스크랩으로부터 회수한 전이금속을 활용한 리튬이차전지 양극재 제조 (Preparation of Cathode Materials for Lithium Rechargeable Batteries using Transition Metals Recycled from Li(Ni1-x-yCoxMny)O2 Secondary Battery Scraps)

  • 이재원;김대원;장성태
    • 한국분말재료학회지
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    • 제21권2호
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    • pp.131-136
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    • 2014
  • Cathode materials and their precursors are prepared with transition metal solutions recycled from the the waste lithium-ion batteries containing NCM (nickel-cobalt-manganese) cathodes by a $H_2$ and C-reduction process. The recycled transition metal sulfate solutions are used in a co-precipitation process in a CSTR reactor to obtain the transition metal hydroxide. The NCM cathode materials (Ni:Mn:Co=5:3:2) are prepared from the transition metal hydroxide by calcining with lithium carbonate. X-ray diffraction and scanning electron microscopy analyses show that the cathode material has a layered structure and particle size of about 10 ${\mu}m$. The cathode materials also exhibited a capacity of about 160 mAh/g with a retention rate of 93~96% after 100 cycles.

Re-synthesis and Electrochemical Characteristics of LiFePO4 Cathode Materials Recycled from Scrap Electrodes

  • Kim, Hyung Sun;Shin, Eun Jung
    • Bulletin of the Korean Chemical Society
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    • 제34권3호
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    • pp.851-855
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    • 2013
  • This paper describes an environmentally friendly process for the recovery of $LiFePO_4$ cathode materials from scrap electrodes by a simple thermal treatment method. The active materials were easily separated from the aluminum substrate foil and polymeric binders were also decomposed at different temperatures ($400^{\circ}C$, $500^{\circ}C$, $600^{\circ}C$) for 30 min under nitrogen gas flow. The samples were characterized by X-ray diffraction (XRD), scanning electronic microscopy (SEM), Raman spectroscopy, Thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The electrochemical properties of the recycled $LiFePO_4$ cathode were evaluated by galvanostatic charge and discharge modes. The specific charge/discharge capacities of the recycled $LiFePO_4$ cathode were similar to those of the original $LiFePO_4$ cathode. The $LiFePO_4$ cathode material recovered at $500^{\circ}C$ exhibits a somewhat higher capacity than those of other recovered materials at high current rates. The recycled $LiFePO_4$ cathode also showed a good cycling performance.

ALC 패널을 활용한 건축물 외장 커튼월에 대한 Mock-up Test 성능 평가 연구 (Performance Evaluations of Mock-up Tests for ALC Panel Curtain Wall in Building Exterior)

  • 김영호;이용수
    • 한국디지털건축인테리어학회논문집
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    • 제13권4호
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    • pp.25-32
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    • 2013
  • The green building is one of biggest factors to go the goal of energy saving and environmental conservation, reduction of energy consumption, friendly energy technology, recycling of resource, and environmental pollution reduction technology. The purpose of these green buildings realized by the energy-saving technology such as the exterior materials or curtain wall system. The curtain wall system is a element that come to insulated portions of building envelope that results in heat loss. The purpose of this paper is to carried out mock-up tests for exterior wall used in autoclaved lightweight concrete panels in green building practices. Mock-up test execute a mixed process between standard test procedure and complex test procedure based on AAMA 501(American Society for Testing and Materials) and ASTM 283, ASTM 330(American Society for Testing and Materials). In results, tests meet the requirements that grant values in steps of procedures provided on ASTM and AAMA. ALC panel is suitable for a exterior wall product to be gratified thermal cycling performance and structural capacity, deflection(H/200) and lateral displacement(H/50), for curtain walls.

루틸단결정 성장을 위한 스컬용융시스템의 조건 (Conditions of Skull melting system for rutile single crystals growth)

  • 석정원;최종건
    • 한국결정성장학회지
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    • 제16권4호
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    • pp.141-148
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    • 2006
  • 스컬용융법은 생산원가가 낮고 crust의 재사용으로 수율이 좋아 양질의 산화물단결정성장 및 대량생산에 좋은 방법이다. 본 연구에서는 루틸단결정을 스컬용융법에 의해 성장시켰으며, 서로 다른 성장조건에서의 ingot특성을 비교하였다. 좋은 품질의 루틸 ingot 성장을 위한 조건은 직경 12, 높이 14cm 도가니 사용, 3000pF의 tank condenser 용량, 2.84 MHz의 주파수, 9시간의 용액유지시간, 2mm/h의 성장속도였다.

Effects of hypochlorite exposure on morphology and trace organic contaminant rejection by NF/RO membranes

  • Simon, Alexander;Nghiem, Long D.
    • Membrane and Water Treatment
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    • 제5권4호
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    • pp.235-250
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    • 2014
  • The impacts of membrane degradation due to chlorine attack on the rejection of inorganic salts and trace organic contaminants by nanofiltration (NF) and reverse osmosis (RO) membranes were investigated in this study. The rejection of trace contaminants was examined at environmentally relevant concentrations. Changes in the membrane surface morphology were observed as a result of chlorine exposure. A small increase in rejection was consistently observed with all four membranes selected in this study after being exposed to a low concentration of hypochlorite (100 ppm). In contrast, a higher concentration of hypochlorite (i.e., 2000 ppm) could be detrimental to the membrane separation capacity. Membranes with severe chlorine impact showed a considerable decrease in rejection over filtration time, possibly due to rearrangement of the polyamide chains under the influence of chlorine degradation and filtration pressure. The reported results indicate that loose NF membranes are more sensitive to chlorine exposure than RO membranes. The impact of hypochlorite exposure (both positive and negative) on rejection is dependent on the strength of the hypochlorite solution and is more significant for the neutral carbamazepine compound than the negatively charged sulfamethoxazole.

커피찌꺼기를 이용한 흡착제 제조 및 수중 Trichloroethylene(TCE) 흡착제거에 관한 연구 (A Study on Preparation of Adsorbent from Coffee Grounds and Removal of Trichloroethylene in Water Treatment)

  • 이향숙;강주원;양원호;정문식
    • 한국환경보건학회지
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    • 제24권2호
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    • pp.20-31
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    • 1998
  • There is a need for waste recycling. This study was carried out to investigate removal efficiency of TCE in water treatment with adsorbent made from coffee grounds which obtained after extraction of coffee through hot water. The removal of TCE in synthetic Waste water using adsorbents was examined varying dose, concentration and temperature on a laboratory scale. The results were as followed 1. As much as 95% TCE remogal was possible with adsorbent made from coffee grounds at an adsorbent dose over 2.5 g/l under the test conditions. 2. The removal rate of TCE was propotional to weight of adsorbent made from coffee grounds (0.025, 0.1, 0.3, 0.5 g). 3. In the effect of temperature, as temperature of wastewater was high, the rate of removal was increased. 4. Iodine number (865 mg/g) of adsorbent made from coffee grounds was not higher than that (1123 mg/g) of adsorbent made from coconut. But, in considering adsorption capacity, Iodine number was inapplicable to adsorbent made from coffee grounds. 5. Generally, Freundlich's equation applies to adsorption in wastewater. In case of TCE, slope (1/n) was 0.83, 1.06 and intercept (k) was 456.18, 405.19 at 150, 300 ppb respectively (average r=0.904, 0.933).

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Assessing Nitrogen and Phosphorus in Excreta from Grower-finisher Pigs Fed Prevalent Rations in Vietnam

  • Vu, T.K.V.;Sommer, G.S.;Vu, C.C.;Jorgensen, H.
    • Asian-Australasian Journal of Animal Sciences
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    • 제23권2호
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    • pp.279-286
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    • 2010
  • Livestock production in Vietnam is, as in most Asian countries, increasing rapidly and changing into specialized highly intensified operations. The volume of animal excreta generated exceeds the capacity of the operation land base and cannot be utilized efficiently. As a consequence, there is a loss of plant nutrients from livestock farms that causes environmental pollution. This study carried out a feed and excretion experiment measuring fecal characteristic, daily fecal production, daily nitrogen and phosphorous excretion from grower-finisher pigs fed prevalent rations in Vietnam. Furthermore, equations for assessing the excretion were tested, which can be used in farm models for optimal recycling of manure while focusing on reducing pollution. The results indicated that fecal production and nutrient excretion were affected by the different rations tested. This study showed that five selected equations for predicting excretion from grower-finisher pigs in Danish conditions can also be used with precision in Vietnamese pig farming systems. The equations have been proven valid and can, therefore, be used as a much needed tool for assessing fecal production and nitrogen in excreta on pig farms. The study also showed that about 12% of nitrogen excreted was emitted during housing. Waste water contains more than half of the nitrogen excreted, mainly in ammonium form which has a high potential for gaseous emission.

An alternative treatment option for a bony defect from large odontoma using recycled demineralization at chairside

  • Lee, JuHyon;Lee, Eun-Young;Park, Eun-Jin;Kim, Eun-Suk
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • 제41권2호
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    • pp.109-115
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    • 2015
  • Odontoma is the most common odontogenic benign tumor, and the treatment of choice is generally surgical removal. After excision, bone grafts may be necessary depending on the need for further treatment, or the size and location of the odontoma. Although the osteogenic capacity of a demineralized tooth was verified as early as 1967 by Urist and many other investigators, the cumbersome procedure, including a long demineralization time, may be less than comfortable for clinicians. A modified ultrasonic technology, with periodic negative pressure and temperature control, facilitated rapid and aseptic preparation of demineralized teeth for bone grafts. This approach reduces the demineralization time dramatically (${\leq}80$ minutes), so that the graft material can be prepared chairside on the same day as the extraction. The purpose of this article is to describe two cases of large compound odonotomas used as graft material prepared chairside for enucleation-induced bony defects. These two clinical cases showed favorable wound healing without complications, and good bony support for future dental implants or orthodontic treatment. Finally, this report will suggest the possibility of recycling the benign pathologic hard tissue as an alternative treatment option for conventional bone grafts in clinics.

생물학적 유류오염토양 복원제의 현장 적용성 평가 (Field Test Assessment of Biological Recovering Agent for treating Oil Contaminated Soil)

  • 김수홍;송승구;서정호
    • KSBB Journal
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    • 제25권1호
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    • pp.73-78
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    • 2010
  • In this study, recovering agent was produced with organic sludge and modified peat moss (MPM) in pilot plant mixer to recover oil contaminated soil, and field test of it was estimated using landfarming method. Oil contaminated soil recovering agent was thought to contain more microorganisms than raw waste sludge and was no problem to come onto the market because there were not any items of specified wastes. According to the results of TPH variation with time, it was observed the initial degradation velocity of oil with produced recovering agent was rapid up to 50% after 4 days, remarkably. Because the microorganisms in the organic sludge discharged from chemical plant already acclimated with oil, therefore, it could be estimated initial degradation velocity of recovering agent might be rapid. It was concluded that the oil contaminated soil recovering agent produced in this study have high marketability because of its two aspects on recycling of wastes and initial rapid degradation capacity.

Composting High Moisture Materials : Bio-Drying Livestock Manure in a Sequentially Fed Reactor

  • Lee, J.H.;Park, H.L.
    • 한국농업기계학회:학술대회논문집
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    • 한국농업기계학회 1996년도 International Conference on Agricultural Machinery Engineering Proceedings
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    • pp.701-710
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    • 1996
  • Composting has gained rapid acceptance as a method of recyling relatively dry organic materials such as leaves and brush and , when alternative disposal costs are high, even moist materials such as grass clippings and dewatered sewage sludges. However, as moisture contents rise above 60% , the need for a dry bulking amendment increase the costs of composting , both by direct purchases of amendment and though increased reactor capacity and materials handling requirements. High moisture materials also present increased risks of anaerobic odor formation through reduced oxygen transport (Miller , 1991) . These costs and operational challengers often constrain the opportunities to compost high moisture materials such as agricultural manures. During the last several decades economies of scale in livestock production have been increasing livestock densities and creating manure management challenges throughout the world. This issue is particularly pressing in Korea, where livestock arms typically manage little or no cropland, and the nutrients and boichemical oxygen demand in manure pose a serious threat to water quality. Composting has recently become popular as a means of recycling manure into products for sale off the farm, but bulking amendments (usually sawdust) are expensive designed to minimize bulking agent requirements by using the energy liberated by decompostion. In this context the composting reactor is used as a biological dryer, allowing the repeated use of bulking amendment with several batches of manure.

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