• Title/Summary/Keyword: Recovery of metal

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Recovery of Indium from Secondary Resources by Hydrometallurgical Method (2차(次) 자원(資源)으로부터 습식방법(濕式方法)에 의한 인듐의 회수(回收))

  • Wang, Lingyun;Lee, Manseung
    • Resources Recycling
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    • v.22 no.2
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    • pp.3-10
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    • 2013
  • Indium is one of the rare metals, and it has been used mainly for preparation of indium tin oxide (ITO). This review investigated the process parameters and the merits and demerits of several methods to recover indium from the leaching solution of secondary resources, such as solvent extraction, ion exchange, and precipitation. D2EHPA has been used mostly as a cationic extractant for indium extraction in moderate acid solutions, while amine extractants are used in strong hydrochloric acid solution. Since the loading capacity of resins for indium is generally small, ion exchange has some advantage over solvent extraction only when the concentration of indium is low.

Investigation of Fluorescent Shape Memory Polyurethanes Grafted with Various Dyes

  • Chung, Yong-Chan;Choi, Jae-Won;Lee, Seung-Hwan;Chun, Byoung-Chul
    • Bulletin of the Korean Chemical Society
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    • v.32 no.spc8
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    • pp.2988-2996
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    • 2011
  • Shape memory polyurethane (SMPU), grafted with a fluorescent dye (Rhodamine, Mehylene violet, or Fluorescein) through an allophanate linking, was tested for the fluorescence and the shape recovery effect. The main chain of SMPU was composed of 4,4'-methylenebis(phenylisocyanate) (MDI), poly(tetramethyleneglycol) (PTMG), and 1,4-butanediol (BD), and a fluorescent dye was connected through a second MDI linked to the carbamate moiety of the main chain. Three series of SMPU, differing according to their dye content, were prepared to compare their shape recovery and fluorescence properties. In tensile mechanical property, maximum stress increased up to 350% compared to the linear SMPU, and strain remained above 2000%. Shape recovery went to as high as 97%, and remained almost same after repetitive shape recovery test cycles. Finally, the fluorescence emission of SMPU was demonstrated in the luminescence spectrum and fluorescent light emission pictures. In addition, the response of SMPU to external stimuli such as metal ions was investigated.

Treatment and Recovery of Valuable Materials from Aluminum Dross by Leaching (침출에 의한 알루미늄 드로스의 처리 및 유용성분의 회수)

  • Nguyen Thi, Thuy Nhi;Lee, Man Seung
    • Resources Recycling
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    • v.26 no.5
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    • pp.77-84
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    • 2017
  • White and black dross are resulted from the recycling of aluminum. There are no established processes to recover valuable materials from black dross. Hydrometallurgical processes seem to be suitable for the treatment of aluminum dross. The salts in the black dross are recovered by dissolving with water. The residues are treated by either alkaline or acid leaching. Although the leaching rate of alumina by NaOH is lower than that by acid, its intermediates are more suitable to the production of alumina-based materials. The future direction for the treatment and recovery of valuable materials from aluminum dross is discussed.

Superconducting magnetic separation of ground steel slag powder for recovery of resources

  • Kwon, H.W.;Kim, J.J.;Ha, D.W.;Choi, J.H.;Kim, Young-Hun
    • Progress in Superconductivity and Cryogenics
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    • v.19 no.1
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    • pp.22-25
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    • 2017
  • Steel slag has been considered as an industrial waste. A huge amount of slag is produced as a byproduct and the steel slag usually has been dumped in a landfill site. However the steel slag contains valuable resources such as iron, copper, manganese, and magnesium. Superconducting magnetic separation has been applied on recovery of the valuable resources from the steel slag and this process also has intended to reduce the waste to be dumped. Cryo-cooled Nb-Ti superconducting magnet with 100 mm bore and 600 mm of height was used as the magnetic separator. The separating efficiency was evaluated in the function of magnetic field. A steel slag was ground and analyzed for the composition. Iron containing minerals were successfully concentrated from less iron containing portion. The separation efficiency was highly dependent on the particle size giving higher separating efficiency with finer particle. The magnetic field also effects on the separation ratio. Current study showed that an appropriate grinding of slag and magnetic separation lead to the recovery of metal resources from steel slag waste rather than dumping all of the volume.

Ecological Recovery of Contaminated Dredged Materials in Masan Bay, Korea (마산만 오염 준설토사의 생태회복)

  • Lee, Chan-Won;Jeon, Hong-Pyo;Ha, Kyung-Ae
    • Journal of Environmental Science International
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    • v.17 no.1
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    • pp.29-36
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    • 2008
  • A large amount of $2.1{\times}10^6m^3$ of polluted sediment was dredged from the Masan Bay and deposited in Gapo confined area, Masan, Korea. The six representative sediments were obtained and analyzed for issue components. The data was discussed with the species of benthos and their distribution. It was judged that toxicological effects of sediment analyzed ranged from ERL to ERM with copper and zinc, and ERL with cadmium, chrome, lead and nickel by the Adverse Biological Effects. The dredging index (DI) of sediments stabilized for 10 years since dumping the confined site was calculated and compared with the DI values of dredged sediment itself. DI values decreased from 0.67 to $0.07{\sim}0.18$, which reflects DI value less than 0.2 is good for benthos in the sediment by the natural recovery of dredged materials. The ecological recovery was confirmed in this confined area as a habitat of benthic organisms.

Removal/Recovery of Heavy Metals Using Biopolymer (생물고분자를 이용한 중금속 제거/회수에 관한 연구)

  • 안대희;정윤철
    • KSBB Journal
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    • v.8 no.4
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    • pp.336-340
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    • 1993
  • Zoogloea ramigera 115, well known type of bacteria to produce slime in sewage plants, was selected for biopolymer production. The extracted biopolymer showed high uptake capacity of metals such as cadmium and zinc. Especially the fermentor broth itself showed high adsorption of metal and could be used a biosorbent without an additional separation process. Biopolymer was immobilized into beads of calcium alginate and used in a packed bed reactor for the purpose of valued metals recovery. The biopolymer showed high removal efficiencies of 80% or greater for Cu, Cd, Mn and Zn, and high stability in sorption-desorption-resorption experiments. The immobilized biopolymer systems were found to be comparable to other metal removal systems such as ion exchange resins and to be of potential industrial application value.

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Recovery of phosphorus from waste activated sludge by microwave heating and MAP crystallization (잉여 슬러지의 마이크로웨이브 가온과 MAP 결정화를 이용한 인산염 회수)

  • Ahn, Johwan
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.4
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    • pp.291-297
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    • 2019
  • Phosphorus is a vital resource for sustaining agriculture and nutrition, but a limited non-renewable resource. Thus, the recovery of phosphorus from waste activated sludge(WAS) was attempted by microwave heating and magnesium ammonium phosphorus(MAP) crystallization. Polyphosphate-accumulating organisms(PAOs) in WAS release phosphate from the cell when they are exposed to high temperature environments. Microwave heating caused phosphorus and ammonia to release from WAS. The amount was increased with increasing temperature, showing that 88.5% of polyphosphate present in the cells were released in the form of phosphate at $80^{\circ}C$. A similar result was also observed in the release of ammonia. On the other hand, both phosphorus and ammonia were crystallized with magnesium, and then was harvested as MAP. Phosphorus recovery rate reached almost 97.8%, but the ammonia was about 13.4%. These results cleary indicate that phosphorus could be recovered from WAS using a physiological trait of PAOs. Heavy metal analyses also show that the MAP crystal is useful and safe as a phosphorus fertilizer.

The New Smart Power Modules for up to 1kW Motor Drive Application

  • Kwon, Tae-Sung;Yong, Sung-Il
    • Journal of Power Electronics
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    • v.9 no.3
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    • pp.464-471
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    • 2009
  • This paper introduces a new Motion-$SPM^{TM}$ (Smart Power Modules) module in Single In-line Package (SIP), which is a fully optimized intelligent integrated IGBT inverter module for up to 1kW low power motor drive applications. This module offers a sophisticated, integrated solution and tremendous design flexibility. It also takes advantage of pliability for the arrangement of heat-sink due to two types of lead forms. It comes to be realized by employing non-punch-through (NPT) IGBT with a fast recovery diode and highly integrated building block, which features built-in HVICs and a gate driver that offers more simplicity and compactness leading to reduced costs and high reliability of the entire system. This module also provides technical advantages such as the optimized cost effective thermal performances through IMS (Insulated Metal Substrate), the high latch immunity. This paper provides an overall description of the Motion-$SPM^{TM}$ in SIP as well as actual application issues such as electrical characteristics, thermal performance, circuit configurations and power ratings.

Membrane Based Recovery of Valuable Lithium Metals from Lithium Ion Battery Waste (리튬이온전지 폐기물로부터 가치 있는 리튬금속을 멤브레인 기반으로 회수)

  • Togzhan Tangbay;Rajkumar Patel
    • Membrane Journal
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    • v.34 no.3
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    • pp.163-171
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    • 2024
  • Growing demand on clean energy to control environmental pollution is growing rapidly. Rechargeable battery such as lithium ion battery is excellent source of clean energy but there is rapid depletion of lithium metal due to high demand and supply mismatch. Recovery of the precious metal from the battery waste is one of the possible solution along with the environmental pollution control. Membrane based separation method is highly successful commercial process available to recover lithium from the waste. This work will cover various methods reported recently and will be compiled in the form of a review.

Rubidium Market Trends, Recovery Technologies, and the Relevant Future Countermeasures (루비듐 시장 및 회수 동향에 따른 향후 관련 대응방안)

  • Sang-hun Lee
    • Resources Recycling
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    • v.32 no.3
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    • pp.3-8
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    • 2023
  • This study discussed production, demand, and future prospects of rubidium, which is an alkali group metal that is highly reactive to various media and requires carefulness in handling, but no significant environmental hazard of rubidium has been reported yet. Rubidium is used in various fields such as optoelectronic equipment, biomedical, and chemical industries. Because of difficulty in production as well as limited demand, the transaction price of rubidium is relatively high, but its detail information such as market status and potential growth is uncertain. However, if the mass production of versatile ultra-high-performance equipment such as quantum computers and the necessity of rubidium use in the equipment are confirmed, there is a possibility that the rubidium market will expand in the future. Rubidium is often found together with lithium, beryllium, and cesium, and may be present in granite containing minerals such as lepidolite and pollucite, as well as in seawater and industrial waste. Several technologies such as acid leaching, roasting, solvent extraction, and adsorption are used to recover rubidium. The maximum recovery efficiency of the rubidium from the sources and the processing above is generally high, but, in many practices, rubidium is not the main recovery target, and therefore the actual recovery effects should depend on presence of other valuable components or impurities, together with recovery costs, energy consumption, environmental issues, etc. In conclusion, although the current production and consumption of rubidium are limited, with consideration of the possible market fluctuations according to the emergence of large-scale demand sources, etc., further investigations by related institutions should be necessary.