• 제목/요약/키워드: Recombination rate

검색결과 166건 처리시간 0.024초

Advanced Nano-Structured Materials for Photocatalytic Water Splitting

  • Chandrasekaran, Sundaram;Chung, Jin Suk;Kim, Eui Jung;Hur, Seung Hyun
    • Journal of Electrochemical Science and Technology
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    • 제7권1호
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    • pp.1-12
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    • 2016
  • The production of oxygen and hydrogen from solar water splitting has been considered to be an ultimate solution for energy and environmental issues, and over the past few years, nano-sized semiconducting metal oxides alone and with graphene have been shown to have great promise for use in photocatalytic water splitting. It is challenging to find ideal materials for photoelectrochemical water splitting, and these have limited commercial applicability due to critical factors, including their physico-chemical properties, the rate of charge-carrier recombination and limited light absorption. This review article discusses these main features, and recent research progress and major factors affect the performance of the water splitting reaction. The mechanism behind these interactions in transition metal oxides and graphene based nano-structured semiconductors upon illumination has been discussed in detail, and such characteristics are relevant to the design of materials with a superior photocatalytic response towards UV and visible light.

THE EFFECTS OF POPULATION SIZE AND DOMINANCE OF QUANTITATIVE TRAIT LOCI (QTL) ON THE DETECTION OF LINKAGE BETWEEN MARKERS AND QTL FOR LIVESTOCK

  • Jeon, G.J.
    • Asian-Australasian Journal of Animal Sciences
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    • 제8권6호
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    • pp.651-655
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    • 1995
  • A simulation study on detection of linkage between genetic markers and QTL in backcross design was conducted. The effects of various sample sizes and the degree of QTL dominance on detention of linkage were examined by using a simple regression analysis. The results indicated that as sample size increased, the standard error of the estimated slope became smaller. When the dominance effect of QTL was complete, the estimated slope tended to be negative but was statistically not significant at all with type I error of greater than 50%. With complete linkage between genetic Marker and QTL, the estimated intercept value was smallest but the estimated slope was largest as expected. In most cases with various degree of dominance and sample sizes, when the actual recombination rate became larger, greater values were obtained for the slope except in the case of complete dominance of QTL.

반도체 레이저 다이오드의 횡방향 1차모드의 특성 해석 (An analysis of the lateral first-order mode characteristics for the semiconductor laser diodes)

  • 김형래;곽계달
    • 전자공학회논문지A
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    • 제32A권12호
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    • pp.91-100
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    • 1995
  • This paper represents the lateral first-order mode characteristics for the semiconductor laser diodes using a two-dimensional numerical simulator. In order to analyze the lateral first-order mode characteristics, Helmholtz wave equation is solved twice for the lateral fundamental and the first-order mode considering the mode gain, total losses, and the recombination rate due to the stimulated emission radiation for the each mode independantly. Through this procedure, we find that the lateral first-order mode was easily guided as increasing the stripe width for the index-guiding structures, and that the lateral first-order mode seems to be dominated in the distribution of total light intensity when its output power reaches nearly half of that of the lateral fundamental mode. This results may be used to design the device structure which guides only the lateral fundamental mode.

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A Study on Optimal Dye-coating Conditions to Reduce Dye-adsorption Time with Improved DSSC Efficiency

  • 서영호;최은창;홍병유
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.481.1-481.1
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    • 2014
  • Dye-sensitized solar cell (DSSC) has been extensively investigated as the next generation energy source. Despite attractive features of simple fabrication process and its economical efficiency, there are some problems such as low efficiency and low long-term stability. Many groups have attempted the proposed way to improve the cell efficiency and long-term stability such as low recombination rate between $TiO_2$ surface and electrolyte, the development of new dye molecules capable of light adsorption as broadly as possible, the fabrication of a solid-state DSSC by replacing the liquid electrolyte, and protective coating on glass. In this work, we confirmed new dye-coating conditions to maximize the dye adsorption between the dye and $TiO_2$ nanoparticle surface. The experiment results coating conditions with the coating temperature of $70^{\circ}C$, the dye concentration of 10 mM and the coating time of 3 min. Conditions have two times, three times cycle the experiment in progress efficiency rises.

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수치모델을 이용한 ICP-CVD 장치의 증착 균일도 해석 (Numerical Modeling of Deposition Uniformity in ICP-CVD System)

  • 주정훈
    • 한국표면공학회지
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    • 제41권6호
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    • pp.279-286
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    • 2008
  • Numerical analysis is done to investigate which would be the most influencing process parameter in determining the uniformity of deposition thickness in TiN ICP-CVD(inductively coupled plasma chemical vapor deposition). Two configurations of ICP antenna are modeled; side and top planar. Side and top gas inlets are considered with each ICP antenna geometries. Precursor for TiN deposition was TDMAT(Tetrakis Diethyl Methyl Amido Titanium). Two step volume dissociation of TDMAT is used and absorption, desorption and deposition surface reactions are included. Most influencing factors are H and N concentration dissociated by electron impact collisions in plasma volume which depends on the relative positions of gas inlet and ICP antenna generated hot plasma region. Low surface recombination of N shows hollow type concentration, but H gives a bell type distribution. Film thickness at substrate edges is sensitive to gas flow rate and at high pressures getting more dependent on flow characteristics.

Vanadium Oxide 나노구조 형성 (Anodic Growth of Vanadium Oxide Nanostructures)

  • 이현권;이기영
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2018년도 춘계학술대회 논문집
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    • pp.68-68
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    • 2018
  • Nanoporous or nanotubular metal oxide can be fabricated by anodization of metal substrate in fluoride contained electrolytes. The approach allows various transition metals such as Zr, Hf, Nb, Ta to form highly ordered oxide nanostructures. These oxide nanostructures have various advantages such as high surface area, fast electron transport rate and slow recombination in semiconductive materials. Recently, vanadium oxide nanostructures have been drawn attentions due to their superior electronic, catalytic and ion insertion properties. However, anodization of vanadium metal to form oxide layers is relatively difficult due to ease formation of highly soluble complex in water contained electrolyte during anodization. Yang et al. reported $[TiF_6]^{2-}$ or $[BF_4]^-$ in electrolyte helps to formation of stable oxide layer [1, 2]. However, the reported approaches are very sensitive in other parameters. In this presentation, we deal with the other important key parameters to form ordered anodic vanadium oxide such as pH, temperatures and applied potential.

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Cosmic Infrared Background from the First Stars and Relic H II Regions

  • 안경진
    • 천문학회보
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    • 제36권2호
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    • pp.72.2-72.2
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    • 2011
  • We have performed the first self-consistent, large-scale simulation of cosmic reionization by stellar sources, including the Population III stars that emerged and were hosted by minihalos at very high redshifts (z~40). Based on this result, we calculate the redshifted radiation background from these stars and the relic H II regions which can be observed at near-infrared and infrared regime. Formation of the first stars inside minihalos are quenched by radiative feedback at z~15, while the relic H II regions have much longer lifetime due to the slow recombination rate. Therefore, the radiation output from the relic H II regions, dominated by Lyman alpha photons, will be observed both in the near-infrared and infrared regime. The estimated background from the first stars inside minihalos are still sub-dominant compared to that from stars inside larger halos, however, and thus complementary observations are necessary, such as redshifted 21-cm line observation.

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Genetic Linkage Plays an Important Role in Maintaining Genetic Variability under Stabilizing Selection in Changing Environment

  • Jeung, Min-Gull;Janes N. Thompson, Jr;Lee, Chung-Choo
    • Animal cells and systems
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    • 제1권4호
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    • pp.619-627
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    • 1997
  • Maintenance of polymorphism in a two-locus system with two alleles under stabilizing selection has been tested by Monte-Carlo simulation. The effect of each allele was additive. Only gene x environment interactions and degree of genetic linkage between loci were considered. There were no other evolutionary forces acting except stabilizing selection. Fixation rates were influenced by the extent of environmental change and the degree of genetic linkage. In most cases, stabilizing selection depleted genetic variability when two loci have a lower degree of linkage (10 cM). When two loci are closely linked (0.1 cM), however, stabilizing selection promoted balanced heterozygotes in changing environments. Thus, environment-dependent selection and recombination rate are important parameters which should be incorporated into mechanisms of maintenance of genetic variability.

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유한요소법에 의한 DI 스위칭 소자의 모델링에 관한 연구 (A Study on the Modeling of DI Switching Device by FEM)

  • Lee, Hyun-Seok;Lee, Kye-Hoon;Rhle, Dong-Hee;Park, Sung-Hee
    • 대한전기학회논문지
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    • 제43권2호
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    • pp.285-295
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    • 1994
  • Double Injection(DI) switching devices consist of PS0+T and nS0+T contact separated by a nearly intrinsic semiconductor region containing deep trap. The equation set for DI switching device simulation by FEM is proposed. The existance of deep trap requires the modification of conventional equation set. So recombination rate equation is modified and a new equation is included in the equation set which conventionally consists op Poisson equation and current continuity equation. Consequently, the modeling equation set, which is proposed in this paper, can be applied to other semiconductor devices with trap.

Finite Element Study on the Micro-cavity Effect in OLED Devices

  • Lee, Hyeongi;Hwang, Youngwook;Won, Taeyoung
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제14권1호
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    • pp.23-28
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    • 2014
  • In this paper, we discuss on the optimal design scheme of the bilayer OLED (Organic Light Emitting Diodes) with micro-cavity structure. We carried out the optical simulation on the OLED device and calculated optimal scale of devices with taking the micro-cavity effect into account. Our emission model is based upon an ensemble of radiating dipole antennas. Consequently, we applied Maxwell's equation to this sequence, followed by the analysis on the electrical behaviors of OLED device using Poisson's equation. It contains carrier injection and transportation mechanism. In this process, we found out the thickness of each layer can affect the recombination rate at the emission layer. Therefore, we optimized the thickness of each layer to improve the efficiency of the device.