• Title/Summary/Keyword: Recombination rate

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Pulsed ionization Chamber Technique for Measurement of Recombination Rate of Plasmas

  • Kim, Sang-Hoon
    • Nuclear Engineering and Technology
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    • v.6 no.4
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    • pp.253-259
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    • 1974
  • The output signal voltage of the pulsed ionization chamber (PIC) was measured for a range of electron density (10$^{13}$ -10$^{17}$ m$^{-3}$ ) of the 3He plasmas. This experimental data was in excellent agreement with the theory including space charge effects. As an application of the PIC techniques, two-body recombination coefficients were obtained with electron densities measured from output signal voltage of the PIC. These values as a function of pressure were in good agreement with theoretical predictions and ranged from 5$\times$10$^{-14}$ to 3$\times$10$^{-13}$ (㎥/sec) at 300$^{\circ}$K for 1 to 10 atmospheric $^3$He plasma.

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InP crystal growth by modified SSD method (변형된 SSD법에 의한 InP결정 성장)

  • 송복식;정성훈;문동찬;김선태
    • Electrical & Electronic Materials
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    • v.8 no.3
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    • pp.291-297
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    • 1995
  • The InP crystals have been grown by modified synthesis solute diffusion (SSD) method and its properties have been investigated. The crystals have been grown by lowering the crucible quartz for growth in the furnace and crystal growth rate is 1.8mm/day. The lattice constant a. of the grown crystals is 5.867.angs.. Etch pits density along growth direction of crystal changes from 3.0*10.sup 3/cm$\^$-2/ of first freeze part to 6.7*10$\^$4/cm$\^$-2/ of last freeze part and the radial direction of wafer shows nearly uniform distribution. The resistivity and the carrier concentration of the grown crystals are 1.43*10$\^$-1/.ohm.-cm, 7.7*10$\^$15/cm$\^$-3/ at room temperature, respectively. In the photolurninescence at 10K, the radiation transitions are observed by the near band edge recombination, a pair recombination due to Si donor - Zn acceptor and its phonon replica in the InP. The activation energy by Zn diffusion in undoped n-InP crystals is 1.22eV.

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Measurement of Absorbed Dose at the Tissue Surface from a Plain $^{90}Sr+^{90}Y$ Beta Sources (조직 표면에서의 베타선 흡수선량 측정)

  • Hah, Suck-Ho;Kim, Jeong-Mook;Yook, Chong-Chul
    • Journal of Radiation Protection and Research
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    • v.16 no.2
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    • pp.17-26
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    • 1991
  • Beta ray $(^{90}Sr+^{90}Y)$ absorbed dose at tissue surface was measured from the distance of 30cm by use of extrapolation chamber. In the measurement, following factors were considered: effective area of collecting electrode, polarity effect, ion recombination and window attenuation. The measured absorbed dose rate at tissue surface was $1.493{\mu}Gy/sec$ with ${\pm}2.9%$.

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CFD analysis of the effect of different PAR locations against hydrogen recombination rate

  • Lee, Khor Chong;Ryu, Myungrok;Park, Kweonha
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.2
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    • pp.112-119
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    • 2016
  • Many studies have been conducted on the performance of a passive autocatalytic recombiner (PAR), but not many have focused on the locations where the PAR is installed. During a severe accident in a nuclear reactor containment, a large amount of hydrogen gas can be produced and released into the containment, leading to hydrogen deflagration or a detonation. A PAR is a hydrogen mitigation method that is widely implemented in current and advanced light water reactors. Therefore, for this study, a PAR was installed at different locations in order to investigate the difference in hydrogen reduction rate. The results indicate that the hydrogen reduction rate of a PAR is proportional to the distance between the hydrogen induction location and the bottom wall.

Physics and current density-voltage characteristics of $a-Si_{1-x}Ge_x:H$ alloy p-i-n solar cells ($a-Si_{1-x}Ge_x:H$ 화합물(化合物) p-i-n 태양전지(太陽電池)의 물리(物理) 및 전류밀도(電流密度)-전압(電壓) 특성(特性))

  • Kwon, Young-Shik
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1435-1438
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    • 1994
  • The effects of Ge composition variation in $a-Si_{1-x}Ge_x:H$ alloy p-i-n solar cells on the physical properties and current density-voltage characteristics are analyzed by a new simulation modelling based on the update published experimental datas. The simulation modelling includes newly formulated density of gap density spectrum corresponding to Ge composition variation and utilizes the newly derived generation rate formulars which include the reflection coefficients and can apply to multijunction structures as well as single junction structure. The effects in $a-Si_{1-x}Ge_x:H$ single junction are analyzed through the efficiency, fill factor, open circuit voltage, short circuit current density, free carriers, trap carriers, electric field, generation rate and recombination rate. Based on the results analyzed in single junction structure, the applications to multiple junction structures are discussed and the optimal conditions reaching to a high performance are investigated.

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Relaxation of Photogenerated Carriers under He, $H_2, Co_2 and\; O_2$ on ZnO

  • 한종수;김혜정;진준
    • Bulletin of the Korean Chemical Society
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    • v.19 no.6
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    • pp.676-680
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    • 1998
  • The relaxation process of photogenerated carriers was investigated using conductivity measurement on ZnO under He, $H_2,\; CO_2\; and\; O_2$. The process was well explained with the rate constant of reaction or recombination of hole and electron, $k_h \;and\; k_e ( k_h > k_e)$, respectively. Generally, $k_h$ increased with the pressure of the gases. The slope of $k_h$ with respect to the pressure increased in the order of $H_2{\le}He, while $k_h$ of $O_2$ was sensitive to the history of the sample. The relaxation process on ZnO which was exposed to oxygen at 298 K and 573 K was observed during the illumination at 298 K and it was found that the rate constant of hole decreased with illumination time. From the result, it was suggested that the rate constant of photogenerated excess carriers was affected by the surface barrier of the semiconductor.

Development of Highly Efficient Dye-Sensitized Solar Cells Using ZnO Post-Treated TiO2 Photoelectrodes (ZnO로 후처리된 TiO2 광전극을 이용한 고효율의 염료감응형 태양전지의 개발)

  • PARK, JUN-YONG;YUN, BYEONG-RO;KIM, TAE-OH
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.4
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    • pp.419-425
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    • 2017
  • In this study, an efficient dye-sensitive solar cells (DSSC) was developed after post-treatment of ZnO on $TiO_2$ photoelectrode. The $TiO_2$ electrode with ZnO post treatment was prepared with Titanium isoporopoxide in Zinc Nitrate Hexahydrate aqueous solution by incineration for 30 min at $450^{\circ}C$. The ZnO-post treated $TiO_2$ electrode showed strong dispersion force between particles in relation to the control $TiO_2$, referring high specific surface area and dye-adsorption rate. Proper addition of ZnO enhanced electron mobility and reduced internal resistance and electron recombination. Light conversion efficiency of DSSCs containing the ZnO-posttreated $TiO_2$ electrode increased 35.4% when compared to the DSSCs using $TiO_2$ electrode. It is similar to the DSSCs with $TiCl_4$ post treatment $TiO_2$ electrode. Increasing of light conversion efficiency was due to high specific surface area and dispersion force, and low dye-adsorption rate and electron recombination. Taken together, ZnO may be used as posttreatment of photoelectrode and replaced $TiCl_4$ that has high toxicity and causticity.

Use of Cylindrical Chambers as Substitutes for Parallel-Plate Chambers in Low-Energy Electron Dosimetry

  • Chun, Minsoo;An, Hyun Joon;Kang, Seong-Hee;Cho, Jin Dong;Park, Jong Min;Kim, Jung-in
    • Progress in Medical Physics
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    • v.29 no.1
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    • pp.16-22
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    • 2018
  • Current dosimetry protocols recommend the use of parallel-plate chambers in electron dosimetry because the electron fluence perturbation can be effectively minimized. However, substitutable methods to calibrate and measure the electron output and energy with the widely used cylindrical chamber should be developed in case a parallel-plate chamber is unavailable. In this study, we measured the correction factors and absolute dose-to-water of electrons with energies of 4, 6, 9, 12, 16, and 20 MeV using Farmer-type and Roos chambers by varying the dose rates according to the AAPM TG-51 protocol. The ion recombination factor and absolute dose were found to be varied across the chamber types, energy, and dose rate, and these phenomena were remarkable at a low energy (4 MeV), which was in good agreement with literature. While the ion recombination factor showed a difference across chamber types of less than 0.4%, the absolute dose differences between them were largest at 4 MeV at approximately 1.5%. We therefore found that the absolute dose with respect to the dose rate was strongly influenced by ion-collection efficiency. Although more rigorous validation with other types of chambers and protocols should be performed, the outcome of the study shows the feasibility of replacing the parallel-plate chamber with the cylindrical chamber in electron dosimetry.

The correlation between ionic conductivity and cell performance with various compositions of polymer electrolyte in dye-sensitized solar cells (염료감응형 태양전지에서의 고분자 전해질 종류에 따른 이온전도도와의 상호관계)

  • Cha, Si-Young;Kim, Su-Jin;Lee, Yong-Gun;Kang, Yong-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.306-308
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    • 2007
  • Poly(ethylene glycol) dimethyl ether (PEGDME)/fumed silica/ 1-methyl -3-propylimidazolium iodide (MPII)/$I_2$ mixtures were used as polymer electrolytes in solid state dye-sensitized solar cells (DSSCs). The contents of MPII were changed and the concentration of $I_2$ was fixed at 0.1 mole% with respect to the MPII. The maximum ionic conductivity was obtained at [EG]:[MPII]:[$I_2$]=10:1.5:0.15. It was supposed that the maximum of ionic conductivities would match with that of cell efficiencies, if the ionic conductivity is a rate determining step in the sol id state DSSCs. However, the maximum composition did not show the maximum solar cell performance, indicating the mismatch between ionic conductivity and cell performance. This suggests that the ionic conductivity may not be the rate controlling step in determining the cell efficiency in these experimental conditions, whereas other parameters such as the electron recombination might play an important role. Thus, we tried to modify the surface of the $TiO_2$ particles by coating a thin metal oxide such as $Al_2O_3$ or $Nb_2O_5$ layer to prevent electron recombination. As a result, the maximum of the cell efficiency was shifted to that of the ionic conductivity. The peak shifts were also attempted to be explained by the diffusion coefficient and the lifetime of electrons in the $TiO_2$ layer.

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Study on Color Shifting Mechanism for Organic Light Emitting Diode with Red Dopant-doped Emitting Layer (적색 도펀트가 도핑된 발광층을 갖는 유기발광다이오드에서의 컬러 시프트 메커니즘 연구)

  • Lee, Ho-Nyeon;Oh, Tae-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.10
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    • pp.4590-4599
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    • 2011
  • The Color shift phenomenon is becoming a major degradation factor of the emitting color purity in the organic emitting diodes which is generating a plurality of colors. In this study, the basic structure of organic light emitting diode device is comprised of ITO/${\alpha}$-NPD/$Alq_3$:DCJTB[wt%]/$Alq_3$/Mg:Ag, we have carry out numerical simulation of the electric-optical characteristics in organic light emitting diode device to estimate the mechanism of color shift phenomenon. We have investigated the causes of the color shift through the change of DCJTB doping concentration ratio. As the result, we have confirmed that the changes of the recombination rate which generated by trapped electrons and holes is one of the major factors for the color shift phenomenon.