• Title/Summary/Keyword: Recombination rate

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Delayed auger recombination in silicon measured by time-resolved X-ray scattering

  • Jo, Wonhyuk;Landahl, Eric C.;Kim, Seongheun;Lee, Dong Ryeol;Lee, Sooheyong
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1230-1234
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    • 2018
  • We report a new method of measuring the non-radiative recombination rate in bulk Silicon. Synchrotron timeresolved x-ray scattering (TRXS) combines femtometer spatial sensitivity with nanosecond time resolution to record the temporal evolution of a crystal lattice following intense ultrafast laser excitation. Modeling this data requires an Auger recombination time that is considerably slower than previous measurements, which were made at lower laser intensities while probing only a relatively shallow surface depth. We attribute this difference to an enhanced Coulomb interaction that has been predicted to occur in bulk materials with high densities of photoexcited charge carriers.

A study on the characteristics of inner cell pressure for sealed type Ni-MH rechargeable battery using Zr-based hydrogen storage alloy as anode (Zr-based 수소저장합금을 음극으로 사용한 밀패형 Ni-MH 2차전지의 내압특성에 관한 연구)

  • Kim, Dong-Myung;Lee, Ho;Jang, Kuk-Jin;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.2
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    • pp.79-90
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    • 1997
  • Extensive work has been done on investigating the inner cell pressure characteristics of sealed type Ni-MH battery in which Zr-Ti-Mn-V-Ni alloy is used as anode. The inner cell pressure of this type Ni-MH battery much more increases with the charge/discharge cycling than that of the other type Ni-MH battery where commercialized $AB_5$ type alloy is used as anode. The increase of inner cell pressure in the sealed type Ni/MH battery using Zr-Ti-Mn-V-Ni alloy system is mainly due to the accumulation of oxygen gas during charge/discharge cycling. The accumulation of oxygen gas arises mainly due to the low rate of oxygen recombination on the MH electrode surface during charge/discharge cycling. The difference of oxygen recombination rate between $AB_5$ type electrode and Zr-Ti-Mn-V-Ni electrode is caused by the difference of electrode reaction surface area resulting from different particle size after their activation and the difference of surface catalytic activity for oxygen recombination reaction, respectively. After EIS analysis, it is identified that the surface catalytic activity affects much more dominantly on the oxygen recombination reaction than the reaction surface area does. In order to suppress the inner cell pressure of Ni-MH battery where Zr-Ti-Mn-V-Ni is used as anode, it is suggested that the surface catalytic activity for oxygen recombination should be improved.

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Quantum Beats in Recombination of Spin-correlated Radical Pairs

  • Yu. N. Molin
    • Bulletin of the Korean Chemical Society
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    • v.20 no.1
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    • pp.7-15
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    • 1999
  • The present paper is a review of the current studies of quantum beats in recombination of spin-correlated radical pairs in solutions as well as of future applications of quantum beats technique for studying these pairs. Examples are given of the use of this method for determining the hfi constants and relaxation times of short-lived radical ions, for finding the rate constants of the reactions of alkane radical cations and for estimating a fraction of singlet-correlated pairs in the pairs in the tracks of ionizing particles. The potentialities of this method, its advantages and limitations are discussed.

An optimal design for the local back contact pattern of crystalline silicon solar cells by using PC1D simulation (PC1D Simulation을 통한 결정질 실리콘 태양전지의 국부적 후면 전극 최적화 설계)

  • Oh, Sungkeun;Lim, Chung-Hyun;Cho, Younghyun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.43.1-43.1
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    • 2010
  • In the crystalline silicon solar cells, the full area aluminum_back surface field(BSF) is routinely achieved through the screen-printing of aluminum paste and rapid firing. It is widely used in the industrial solar cell because of the simple and cost-effective process to suppress the overall recombination at the back surface. However, it still has limitations such as the relatively higher recombination rate and the low-to-moderate reflectance. In addition, it is difficult to apply it to thinner substrate due to wafer bowing. In the recent years, the dielectric back-passivated cell with local back contacts has been developed and implemented to overcome its disadvantages. Although it is successful to gain a lower value of surface recombination velocity(SRV), the series resistance($R_{series}$) becomes even more important than the conventional solar cell. That is, it is a trade off relationship between the SRV and the $R_{series}$ as a function of the contact size, the contact spacing and the geometry of the opening. Therefore it is essential to find the best compromise between them for the high efficiency solar cell. We have investigated the optimal design for the local back contact by using PC1D simulation.

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Numerical Analysis of Optical Damage in Dielectrics Irradiated by Ultra-Short Pulsed Lasers (극초단 펄스 레이저에 의한 절연체의 광학 손상 해석)

  • Lee, Seong-Hyuk;Kang, Kwang-Gu;Lee, Joon-Sik;Choi, Young-Ki;Park, Seung-Ho;Ryou, Hong-Sun
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1213-1218
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    • 2004
  • The present article reports extensive numerical results on the non-local characteristics of ultra-short pulsed laser-induced breakdowns of fused silica ($SiO_{2}$) by using the multivariate Fokker-Planck equation. The nonlocal type of multivariate Fokker-Planck equation is modeled on the basis of the Boltzmann transport formalism to describe the ultra-short pulsed laser-induced damage phenomena in the energy-position space, together with avalanche ionization, three-body recombination, and multiphoton ionization. Effects of electron avalanche, recombination, and multiphoton ionization on the electronic transport are examined. From the results, it is observed that the recombination becomes prominent and contributes to reduce substantially the rate of increase in electron number density when the electron density exceeds a certain threshold. With very intense laser irradiation, a strong absorption of laser energy takes place and an initially transparent solid is converted to a metallic state, well known as laser-induced breakdown. It is also found that full ionization is provided at intensities above threshold, all further laser energy is deposited within a thin skin depth.

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A Study on the Performance of Catalysts for the Recombination of Oxyhydrogen Gas Generated in Secondary Battery (이차전지내 발생하는 수소-산소 혼합기체 재결합용 촉매의 성능 측정 및 이론적 모델 연구)

  • Kim, Yong-Sik;Chang, Min-Hwan;Ju, Jeh-Beck
    • Journal of the Korean Electrochemical Society
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    • v.17 no.1
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    • pp.71-77
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    • 2014
  • The performance of catalysts for the recombination of oxyhydrogen gas was measured and compared with the results obtained from theoretical model. The oxyhydrogen gas was generated by the electrolysis cell and recombined through the fixed bed catalytic reactor. The yield that is the ratio of water-amount produced to the water-amount consumed in the electrolysis cell was increased with the increase of KOH concentration in electrolysis cell and the applied current. The catalyst 1 showed the best performance and the yield was under 60 %. The faradic yield calculated by Faraday's law showed about 100% in maximum with catalyst 1. The production rate of water generated by the recombination was 5-40 g/day dependent on the flow rate of mixed gas. Considering the results calculated from the pseudo-homogeneous catalytic reactor model, the hot point inside the reactor was moved to the direction of outlet and the maximum temperatures were $440-480^{\circ}K$ when the gas flow rate increased. The production rate of water calculated from the theoretical model showed good agreement with experimental results below the flow rate of $0.5cm^3/sec$, but there were much differences above that flow rate.

Performance Enhancement of Organic Light-emitting Diodes with an Electron-transport Layer of Bathocuproine

  • Honga, Jin-Woong;Guo, Yi-Wei;Shin, Jong-Yeol;Kim, Tae Wan
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.1
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    • pp.37-40
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    • 2016
  • Performance enhancement of organic light-emitting diodes (OLEDs) is investigated in a device structure of ITO/TPD/Alq3/LiF/Al and ITO/TPD/Alq3/BCP/LiF/Al. Here, bathocuproine (BCP) is used as an electron-transport layer. Current density-voltage-luminance characteristics of the OLEDs show that the performance of the device is better with BCP layer than without BCP layer. The current density, luminance, luminous efficiency, and external-quantum efficiency are improved by approximately 22%, 50%, 2%, and 18%, respectively. Since the BCP layer lowers the electron energy barrier, electron transport is facilitated and the movement of hole is blocked as the applied voltage increases. This results in an increased recombination rate of holes and electrons.

Study of Diffusion Controlled Reactions in Liquids: A Perturbation Series Solution and a Numerical Solution of the Smoluchowski Equations

  • Mino Yang;Sangyoub Lee;Kim Yung Sik;Kook Joe Shin
    • Bulletin of the Korean Chemical Society
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    • v.10 no.6
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    • pp.529-535
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    • 1989
  • A general perturbation series solution of the Smoluchowski equation is applied to investigate the rate of recombination and the remaining probability of a pair of particles in liquids. The radiative boundary condition is employed and the convergence of the perturbation series is analyzed in terms of a convergene factor in time domain. The upper bound to the error introduced by the n-th order perturbation scheme is also evaluated. The long time behaviors of the rate of recombination and the remaining probability are found to be expressed in closed forms if the perturbation series is convergent. A new and efficient method of purely numerical integration of the Smoluchowski equation is proposed and its results are compared with those obtained by the perturbation method. For the two cases where the interaction between the particles is given by (i) the Coulomb potential and (ii) the shielded Coulomb potential, the agreement between the two results is found to be excellent.

Turn-off time improvement by fast neutron irradiation on pnp Si Bipolar Junction Transistor

  • Ahn, Sung Ho;Sun, Gwang Min;Baek, Hani
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.501-506
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    • 2022
  • Long turn-off time limits high frequency operation of Bipolar Junction Transistors (BJTs). Turn-off time decreases with increases in the recombination rate of minority carriers at switching transients. Fast neutron irradiation on a Si BJT incurs lattice damages owing to the displacement of silicon atoms. The lattice damages increase the recombination rate of injected holes with electrons, and decrease the hole lifetime in the base region of pnp Si BJT. Fast neutrons generated from a beryllium target with 30 MeV protons by an MC-50 cyclotron were irradiated onto pnp Si BJTs in experiment. The experimental results show that the turn-off time, including the storage time and fall time, decreases with increases in fast neutron fluence. Additionally, it is confirmed that the base current increases, and the collector current and base-to-collector current amplification ratio decrease due to fast neutron irradiation.

Molecular Evidence of Recombination on Korean Isolates of Tomato yellow leaf curl virus by Nucleotide Transversions and Transitions

  • Lee, Hye-Jung;Park, Jung-An;Auh, Chung-Kyoon;Lee, Kyeong-Yeoll;Kim, Chang-Seok;Lee, Gwan-Seok;Soh, Hyun-Cheol;Choi, Hong-Soo;Lee, Suk-Chan
    • The Plant Pathology Journal
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    • v.27 no.4
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    • pp.378-384
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    • 2011
  • Tomato yellow leaf curl virus (TYLCV), a member of genus Begomovirus, was isolated in Korea in 2008. We sequenced and analyzed the DNA-A of 51 TYLCV isolates from Korea, and 13 of the TYLCV isolates were selected as type representatives of TYLCV from six Korean provinces. The 13 TYLCV isolates were classified into Korea Group 1 (KG1, nine isolates) and Korea Group 2 (KG2, four isolates) based on the results of phylogenetic analysis and genome size (2774 and 2781 nucleotides, respectively). A recombination detection program 3 (RDP3) revealed two recombinations between the TYLCV Korea isolates and other TYLCV isolates [Thailand (AF206674), Iran (AJ132711), and Israel (X76319)]. TYLCV Jeju isolate was characterized by two recombination events (E1 and E2) caused by the presence of E1 in ORF V1 and C3, which may seem to be the mutations of the high nucleotide transversion and transition rate. Collectively, our results suggest that the occurrence of nucleotide transversions and transitions in TYLCV DNA-A might have induced novel recombination events within the TYLCV Korea isolates.