• Title/Summary/Keyword: Rearrangement

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Preparation of the Polymers Containing Phenylamide and Dimethylaminoethyl Groups and their Properties as a Nagative Photoresist

  • Chae, Kyu-Ho;Kang, Jin-Koo;Kim, Su-Kyung;Chough, Sung-Hyo
    • Journal of Photoscience
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    • v.7 no.2
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    • pp.47-52
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    • 2000
  • The copolymmers of N, N-dimethylaminoethyl methacrylate(DAEM) and N-arylmethacrylamide (AMA) were prepared, and their photochemical properties as a negative photoresist were studied by the measurements of insoluble fraction, and by UV and IR absorption spectral changes. These copolymers are soluble in DMF, actone, methanol, of acidic buffer solutions. Solubility of these copolymer films in the vuffer solutions increased with the amount of DAEM units in the copolymer and decreased with the pH value. The insoluble fraction of the copolymer films in the buffer solution of pH 4 of in methanol increased with irradiation time and the amount of AMA units in the copolymer. UV and IR spectral changes indicated that not only photo-crosslinking but also the photo-Fries rearrangement took place upon irradiation with a 254nm UV light.

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Setting Properties of Disulfide-Crosslinked Silk Fiber (Disulfide 가교 견섬유의 Set 성)

  • ;;M. Sakamoto
    • Textile Coloration and Finishing
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    • v.1 no.1
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    • pp.1-6
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    • 1989
  • The reaction of silk with a disulfide-containing crosslinking agent, i.e. bis($\beta$-isocyanatoethyl)disulfide(BIED), was studied in an attempt to obtain disulfide-crosslinked silk. The setting properties of disulfide-crosslinked silk fibers were studied. The permanent set values of single fibers were evaluated after the set fibers were relaxed in boiling water. When single fibers were set in boiling water or in boiling alkaline solution, the permanent set values of BIED-treated silk fibers were less than those of untreated silk fibers. When the fibers were treated with 2% thioglycolic acid solution at $60^\circ{C}$ followed by oxidation, settability of BIED-treated silk was better than that of untreated silk. The rearrangement of secondary bonds faciliated by cleavage of crosslinks as well as the rearrangement of crosslinks itself seems to be an important role in the set stability.

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Advanced LSB Technique for Hiding Messages in Audio Steganography (오디오 스테가노그래피에 자료를 숨기기 위한 개선된 LSB 기법)

  • Ji, Seon Su
    • Journal of Korea Society of Industrial Information Systems
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    • v.19 no.1
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    • pp.69-75
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    • 2014
  • Audio seganography is the art and science of writing hidden messages that evolves as a new secret communication method. And audio steganography is similar to the process of modifying the Least Significant Bit of image files 8th LSB layer embedding has been done for desired binary messages. The effective of steganographic tools is to obtain imperceptible and robust way to conceal high rate of secret data. The objective of this paper is to propose a method for hiding the secret messages in safer manner from external attacks by modified LSB technique and encryption rearrangement key.

A traffic and interference adaptive DCA algorithm with rearrangement in microcellular systems

  • Kim, Seong-Lyun;Han, Youngnam
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 1995.04a
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    • pp.724-728
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    • 1995
  • A new dynamic channel assignment (DCA) algorithm with rearrangement for cellular mobile communication systems is suggested. Our DCA algorithm is both traffic and interference adaptive, which is based on the mathematical formulation of the maximum packing under a realistic propagation model. In developing the algorithm, we adopt the Lagrangean relaxation technique that has been successfully used in the area of mathematical programming. Computational experiments of the algorithm reveal quite encouraging results. Although our algorithm primarily focuses on microcellular systems, it can be effectively applied to conventional cellular systems under highly nonuniform traffic distributions and interference conditions.

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Object Feature Extraction Using Double Rearrangement of the Corner Region

  • Lee, Ji-Min;An, Young-Eun
    • Journal of Integrative Natural Science
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    • v.12 no.4
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    • pp.122-126
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    • 2019
  • In this paper, we propose a simple and efficient retrieval technique using the feature value of the corner region, which is one of the shape information attributes of images. The proposed algorithm extracts the edges and corner points of the image and rearranges the feature values of the corner regions doubly, and then measures the similarity with the image in the database using the correlation of these feature values as the feature vector. The proposed algorithm is confirmed to be more robust to rotation and size change than the conventional image retrieval method using the corner point.

Transition Metal-Catalyzed and -Promoted Reactions via Carbene and Vinylidene Complexes Generated from Alkynes

  • Ohe, Kouichi
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2153-2161
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    • 2007
  • The transition metal-induced in situ generation of carbene complexes from alkynes having a carbonyl or imino group as a nucleophilic functionality has been investigated. These reactive carbenoid species are generated with high atom efficiency through a 6-endo-dig cyclization mode based on the electrocyclization of vinylidene complexes or a 5-exo-dig cyclization mode in π-alkyne complexes, and have been found to serve as versatile intermediates in catalytic carbene transfer reactions. Highlighted and reviewed in this account are the generation and preparation of pyranylidene, furylcarbene, pyrrolylcarbene, and vinylcarbene complexes and their application to [3,3]sigmatropic rearrangement of acylcyclopropylvinylidenes, catalytic cyclopropanation reactions, [2,3]sigmatropic rearrangement or condensation reactions via ylides, ring-opening and substitution reactions with heteroaromatic compounds, and catalytic isomerization of oligoynes.

A Study of Hydrogen-Induced Metal Atom Rearrangement

  • Noh, Hak;Park, Choong-Nyeon;Flanagan, Ted B.
    • Transactions of the Korean hydrogen and new energy society
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    • v.7 no.1
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    • pp.111-115
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    • 1996
  • Metal atom rearrangement has been shown to take place under the influence of hydrogen-induced atomic diffusion (HIAD) in initially homogeneous fee palladiumalloys by electron microprobe analysis, optical microscopy, mechanical property tests and hydrogen isotherms. HIAD takes place in palladium alloys at moderate to elevated temperatures leading to phase segregation under conditions where segregation does not normally occur, i.e., in the absence of H over the time scale of the experiments. From these results, it is confirmed that dissolved hydrogen plays a dual role in some of these alloys, i.e. it catalyzes metal atom diffusion. This research demonstrates the potential utility of employing H-induced changes for phase diagram determination of Pd alloys and possibly for other alloy system.

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A Hybrid ARQ Scheme with Changing the Modulation Order (변조 차수 변경을 통한 하이브리드 자동 재전송 기법)

  • Park, Bum-Soo
    • Journal of the Korea Institute of Military Science and Technology
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    • v.17 no.3
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    • pp.336-341
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    • 2014
  • When using a higher-order modulation scheme, there are variations in bit-reliability depending on the bit position in a modulation symbol. Variations of bit-reliability in the codeword block lower the decoding performance. Also, the decoding performance increases as the sum of the bit-reliabilities in the codeword block increases. This paper presents a novel hybrid automatic repeat request scheme that increases the sum of the reliabilities of the transmitted bits by lowering the modulation order, and decreases the variations of bit-reliability in the codeword block by preferentially retransmitting bits with low reliability. The proposed scheme outperforms the constellation rearrangement scheme. Furthermore, the proposed scheme also provides a good solution in cases where the size of the retransmission block is smaller than the size of the initial transmission block.

Creep Mechanisms of Calcium-Silicate-Hydrate: An Overview of Recent Advances and Challenges

  • Ye, Hailong
    • International Journal of Concrete Structures and Materials
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    • v.9 no.4
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    • pp.453-462
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    • 2015
  • A critical review on existing creep theories in calcium-silicate-hydrate (C-S-H) is presented with an emphasis on several fundamental questions (e.g. the roles of water, relative humidity, temperature, atomic ordering of C-S-H). A consensus on the rearrangement of nanostructures of C-S-H as a main consequence of creep, has almost been achieved. However, main disagreement still exists on two basic aspects regarding creep mechanisms: (1) at which site the creep occurs, like at interlayer, intergranular, or regions where C-S-H has a relatively higher solubility; (2) how the structural rearrangement evolutes, like in a manner of interlayer sliding, intra-transfer of water at various scales, recrystallization of gelled-like particles, or dissolution-diffusion-reprecipitation at inter-particle boundary. The further understanding of creep behavior of C-S-H relies heavily on the appropriate characterization of its nanostructure.

Variable Length CAN Message Compression Using Bit Rearrangement (비트 재배열을 이용한 가변길이 CAN 메시지 압축)

  • Cho, Kyung-Ju
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.48 no.4
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    • pp.51-56
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    • 2011
  • In this paper, we propose a CAN message compression method using bit rearrangement to reduce the CAN bus load and the error probability during the transmission of CAN messages. In conventional CAN message compression methods, message compression is accomplished by sending only the differences between the previous data and the current data. In the proposed method, the difference bits are rearranged to further increase the compression efficiency. By simulations in car applications, it is shown that the CAN transmission data is further reduced up to 26% by the proposed method, compared with the conventional method.