• Title/Summary/Keyword: Real Gas Effects

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Development of Real-time and Simultaneous Quantification of Volatile Organic Compounds in Ambient with SIFT-MS (Selected Ion Flow Tube-Mass Spectrometry) (선택적다중이온질량분석기를 이용한 대기 중 휘발성유기화합물 실시간 동시분석법 개발 및 적용)

  • Son, Hyun Dong;An, Joon Geon;Ha, Sung Yong;Kim, Gi Beum;Yim, Un Hyuk
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.3
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    • pp.393-405
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    • 2018
  • Volatile organic compounds (VOCs) are representative air pollutants due to their detrimental effects on human health and their role in formation of secondary organic aerosols. Assessments and monitoring programs of VOCs using periodic grab sampling like Tedlar bags, canisters, and sorbent traps provide limited information, often with delay times of days or weeks. Selected ion flow tube mass spectrometry (SIFT-MS) is an emerging analytical technique for the real-time quantification of VOCs in air. It relies on chemical ionization of the VOCs molecules in air introduced into helium carrier gas using $H_3O^+$, $NO^+$, and $O_2{^+}$ precursor ions. Real-time monitoring method of 60 VOCs in the ambient air was developed using TO-15 standard gas mixture. Calibration curves, method detection limit, and quantitation reproducibility of the target compounds were tested. Dynamic dilution system was used to dilute standard gas from 0.174 ppbv to 100 ppbv, where calibration curves showed good linearity with $r^2$> 0.95 in all target analytes. Limit of detection (LOD) all compounds were sub ppbv, and some halogenated compounds showed pptv levels. Seven consecutive analyses of target compounds showed good repeatability with relative standard deviation of less than 10%. One day monitoring of VOCs in ambient air was conducted in Geoje. Average concentration of target VOCs in Geoje were relatively lower than other regions, among which formaldehyde showed the highest concentration ($15.4{\pm}5.78ppbv$). SIFT-MS provided good temporal resolution data (1 data per 3.2 minute), which can be used for identifying ephemeral short-term event. It is expected that SIFT-MS will be a versatile monitoring platform for VOCs in ambient air.

Study on the Distortion of Detecting Signals with the Multi-Defects in Magnetic Flux Leakage System (자기누설탐상시스템에서 밀집된 다수의 결함에 의한 탐상 신호 왜곡에 관한 연구)

  • Seo, Kang;Kim, Dug-Gun;Han, Jea-Man;Park, Gwan-Soo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.5
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    • pp.876-883
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    • 2007
  • The magnetic flux leakage(MFL) type nondestructive testing(NDT) method is widely used to detect corrosion, defects and mechanical deformation of the underground gas pipelines. The object pipeline is magnetically saturated by the magnetic system with permanent magnet and yokes. Hall sensors detect the leakage fields in the region of the defect. The defects are sometimes occurred in group. The accuracy of the detecting signals in this defect cluster become lowered because of the complexity of the defect cluster. In this paper, the effects of the multi -defects are analyzed. The detecting signals are computed by 3-dimensional finite element method and compared with real measurement. The results say that, rather than the size of the defects, the effects of the relative position of the multi-defects are very important on the detecting signals.

High resolution 5" full color field emission displays with new aging technique

  • Kim, J.M.;Hong, J.P.;Park, N.S.;Ryu, Y.S.;Jung, J.E.;Hong S.S.
    • Proceedings of the Korean Vacuum Society Conference
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    • 1998.02a
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    • pp.23-23
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    • 1998
  • High resolution field emission dispplay(FED) devices of 5 inch diagonal in size are fully developped for the applications of near-future flat ppanel dispplays. Under the unique gate-switching drive scheme electron trajectory pprofiles are simulated and tested by considering leakage effects of each ppixel. Uniquely-pprinted sppacer with high asppect ratio are fabricated on real ITO glass for high vacuum ppackaging. In addition new gas aging scheme of stabilizing field emitting array are extensively investigated during the sealing and exhausting pprocess in order to pprevent oxidation effects on the micro tipp. Finally fulll color images of 64 gray scale will be demonstrated.

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Investigation on the Effect of Strength Mismatch on Residual Stresses in Welds with Different Strength Used in Buried Natural Gas Pipeline (매설 가스 배관 이종금속 용접부의 강도 불일치가 잔류응력에 미치는 영향 고찰)

  • Kim, Jong-Sung;Kim, Woo-Sik;Baek, Jong-Hyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.4
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    • pp.413-421
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    • 2010
  • In this study, residual-stress distributions in welds with different strength used in natural gas pipelines are calculated by using finite-element analysis and simulating a realistic welding process. The temperature and residual-stress analysis results are compared with the real fusion profile and the application results of the Fitness-For-Service assessment code, API 579 in order to validate the finite-element analysis model and procedure. Parametric study is performed to assess the effect of welding and material variables such as mechanical strength mismatch, the strength of weld metal, reinforcement, and heat input on the residual stress distributions. Finally, on the basis of the parametric study results, the effects of these variables on residual stress distributions are investigated. In particular, the strength mismatch between base metals has an insignificant effect on residual-stress distributions.

Analysis of the Relationships among Energy, Economic Growth and Greenhouse Gas Emissions Using Metropolitan City/Province Level Data (광역시·도별 자료를 이용한 에너지, 경제성장, 온실가스 배출 간의 관계 분석)

  • Lee, Jaeseok;Lee, Keun-Dae;Yu, Bok-Keun
    • Environmental and Resource Economics Review
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    • v.30 no.3
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    • pp.503-533
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    • 2021
  • This paper analyzes the relationships among the energy consumption, renewable energy production, real gross regional domestic product(GRDP), and greenhouse gas(GHG) emissions. It uses the metropolitan city and province level data for Korea from 2010 to 2018, employing a panal vector autoregressive(VAR) model. We find that an increase in energy consumption has a limited impact on boosting renewable energy production or gross regional domestic product, while it leads to an increase in greenhouse gas emissions. A rise in renewable energy production can increase gross regional domestic product, but it has no meaningful effects on energy consumption and the reduction of green house gas emissions. Our finding indicates that it is crucial to expand the supply of renewable energy as well as to decrease energy consumption in order to achieve the goal of reducing greenhouse gas emissions and reaching economic growth.

Control Indian meal moth Plodia interpunctella by gas treatment

  • Han, Gyung Deok;Kwon, Hyeok;Jin, Hyun Jung;Kum, Ho Jung;Kim, Bo Hwan;Kim, Wook
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.45-45
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    • 2017
  • The Indian meal moth, Plodia interpunctella, is one of the most important pests of stored food in the food processing industry worldwide. To control the Indian meal moth, methyl bromide, phosphine, high carbon dioxide, sulfuryl fluoride and plant essential oil fumigation have been considered. However, these treatments have disadvantages. For example, depleting the ozone layer, showing resistance in insect, low control efficacy or need high cost for treatment. Chlorine dioxide ($ClO_2$) is strong disinfectant and insecticide. The gas caused a malfunction in enzymes. The oxidative stress induced by $ClO_2$ gas treatment damaged to a physiological system and all life stages of P. interpunctella. The gaseous $ClO_2$ is a convincing alternative to methyl bromide for controlling P. interpunctella. The gaseous $ClO_2$ was generated by a chlorine dioxide generator (PurgoFarm Co., Ltd., Hwasung, Korea). It generated highly pure $ClO_2$ gas and the gas blown out through a vent into a test chamber. Gas entry to the chamber was automatically controlled and monitored by a PortaSene II gas leak detector (Analytical Technology, Collegeville, PA, USA). The properly prepared eggs, larvae, pupae, and adults of P. interpunctella were used in this experiment. Data were analyzed using SAS 9.4. Percentage data were statistically analyzed after arcsine-root transformation. Analysis of variance was performed using general linear model, and means were separated by the least significant difference test at P < 0.05. Fumigation is an effective management technique for controlling all stages of P. interpunctella. We found that $ClO_2$ gas treatment directly effects on egg, larvae, pupae and adults of P. interpunctella. The gas treatment with proper concentration for over a day achieved 100 % mortality in all stages of P. interpunctella and short time treatment or low concentration gas treatment results showed that the egg hatchability, pupation rate, and adult emergency rate were lowered compare with untreated control. Also, abnormal pupae or adult rate were increased. Gaseous $ClO_2$ treatment induced insecticidal reactive oxygen species (ROS), and it resulted in fatal oxidative stress in P. interpunctella. Taken together, these results showed that exposure proper concentration and time of the gas control all stages of P. interpunctella by inducing fatal oxidative stress. Further studies will be required to apply the gas treatment under real-world condition and to understanding physiological reaction in P. interpunctella caused by oxidative stress.

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Effects of Convective Velocity and Ambient Pressure on the Characteristics of Heptane Droplet Vaporization in Supercritical Environments (초임계상태에서 주위 유동 속도와 압력 변화에 따른 헵탄 액적의 기화 특성)

  • Lim, Jong-Hyuk;Lee, Bong-Su;Koo, Ja-Ye
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.4
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    • pp.71-78
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    • 2005
  • The vaporization characteristics of a liquid heptane droplet in a supercritical nitrogen flow is numerically analyzed. The present model can account for real gas effects, liquid-phase internal circulation, variable thermodynamic properties and high-pressure effects. Time marching method with preconditioning scheme is employed to handle the low Mach number flows in dense heptane droplet region. Computations are made for the wide range of convective velocity and ambient pressure. Numerical results indicate that the droplet deformation becomes stronger by increasing the Reynolds number and it becomes relatively weak by increasing the pressure.

A Study on the Carbon Taxation Method Using the Real Business Cycle Model (실물적 경기변동모형을 이용한 탄소세 부과방식에 관한 연구)

  • Chung, In-sup;Jung, Yong-gook
    • Environmental and Resource Economics Review
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    • v.27 no.1
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    • pp.67-104
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    • 2018
  • In this paper, we compare the spread effects of the carbon tax imposition method using the real business cycle model considering the productivity and energy price shocks. Scenario 1 sets the carbon tax rate that encourages the representative firm to maintain a constant $CO_2$ reduction ratio in accordance with its green house gas reduction targets for each period. Scenario 2 sets the method of imposing the steady state value of the carbon tax rate of Scenario 1 during the analysis period. The impulse response analysis shows that the responses of $CO_2$ emissions to external shocks are relatively sensitive in scenario 2. And simulation results show that the cost of $CO_2$ abatement is more volatile in scenario 1, and $CO_2$ emissions and $CO_2$ stock are more volatile in scenario 2. In particular, the percentage changes in volatility between the two scenarios of $CO_2$ emissions and $CO_2$ stock increase as the green house gas reduction target is harder. When the green house gas reduction target is 60% and over, the percentage changes(absolute value) between the two scenarios exceed the percentage change(absolute value) of the $CO_2$ reduction cost between them.

Greenhouse Gas and Pollutant Emission from Light-Duty Vehicles Regarding the Relative Positive Acceleration (주행패턴의 상대 가속도에 따른 중소형 자동차의 온실가스 및 대기오염물질 배출 특성)

  • Lee, Tae-Woo;Keel, Ji-Hoon;Park, Kyung-Kyun;Park, Jun-Hong;Park, Yong-Hee;Hong, Ji-Hyung;Lee, Dae-Yup
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.4
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    • pp.31-39
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    • 2010
  • Although driving patterns strongly influence greenhouse gas and air pollutant emission rate from light duty vehicles, emission measurements have been mainly based on chassis dynamometer testing with one standard driving pattern. And there has been limited work on quantifying the independent effect of driving parameters on emission rate because of multidimensional nature of real-world driving pattern. The objective of this study is to obtain the quantitative effect of relative positive acceleration (RPA) on vehicle emission rate. RPA has been used to define the occurrence of acceleration demanding large amounts of power in certain driving distance and shown to be a significant affecting parameter for real-world emission rate. 40 driving patterns have been developed with fixed driving parameters to investigate independent effect of RPA. For the same values of average vehicle speed and power, the trend in carbon dioxide emission rate and fuel consumption with respect to RPA is very clear. Emission rate of nitrogen oxide and particulate matter also increase with respect to RPA, but the trend is less clear. Carbon dioxide emission from diesel vehicle appear to be more affected by high accelerations compared to that from gasoline vehicle because of high intake air restriction during acceleration caused by turbocharger and intercooler. The results have implications for the possible reduction of environmental effects through better traffic planning and management, driver education and car design.

Temperature Effects on the Industrial Electricity Usage (산업별 전력수요의 기온효과 분석)

  • Kim, In-Moo;Lee, Yong-Ju;Lee, Sungro;Kim, Daeyong
    • Environmental and Resource Economics Review
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    • v.25 no.2
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    • pp.141-178
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    • 2016
  • This paper, using AMR (Automatic Meter Reading) electricity data accurately measured in real time, analyses the characteristics and patterns of temperature effect on the industrial electricity usage. For this goal, the paper constructs and estimates a model which captures the properties of AMR time series including long-term trends, mid-term temperature effects, and short-term special day effects. Based on the estimated temperature response function and the temperature effect, we categorize the whole industry into two groups: one group with sharp temperature effect and the other with weak temperature effect. Furthermore, the industry group with sharp temperature effect is classified into a summer peak industry group and a winter peak industry group, based on the estimates of the temperature response function. These empirical results carry practical policy implications on the real time electricity demand management.