• Title/Summary/Keyword: Reaggregation

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Reduction of Cake Resistance by Floc Reaggregation in a Membrane-Feed-Pipe (관내 입자 재응집에 의한 케이크 저항의 감소)

  • KIM, Taeyoung;PARK, Heekyung
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.6
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    • pp.717-726
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    • 2007
  • Fully-grown flocs in a mixing tank of membrane filtration with dead-end membrane are ruptured while passing through a pump and the ruptured flocs are aggregated again in a Membrane-Feed-Pipe (MFP). To look at more details, this study tries to relate the reaggregation to a parameter of mixing intensity in MFP, i.e., G-value. The G-value is a function of Reynolds number, pipe diameter, friction factor and average velocity in MFP. To deal with polydispersity condition, we develop a representative particle size called in this study EDPD (Effective Diameter for Polydispersity condition in Dead-end filtration). The experimental results show that as the G-value increases, the EDPD decreases and also the cake resistance increases. Through comparison between EDPD and cake resistance, these results show that cake resistances are controlled by reaggregation phenomenon in MFP. The effect of detention time in MFP, however, does not affect the reaggregation of the broken flocs as G-values are increased.

Effect of cake resistance by first-aggregation of in-line injection system (인라인 주입방식의 최초응집이 케이크 저항에 미치는 영향)

  • KIM, Taeyoung;PARK, Heekyung
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.3
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    • pp.281-288
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    • 2008
  • Cake resistance is influenced by floc size deposited on membrane surface. Enlarging floc size can reduce cake resistance. The small particles are enlarged by coagulation and flocculation process in conventional mixing tank at membrane filtration system. Fully-grown flocs for reducing the cake resistance, however, are ruptured while passing through a pump. In light of this fact, this study aims to experimentally look at the reaggregation phenomenon of mixing system. In addition, reaggregation phenomenon of mixing system is compared with first-aggregation of in-line injection system in which coagulant is injected just before a pump. These results suggest that first-aggregation of in-line injection system is better than reaggregation of mixing system for G-value above $3100sec^{-1}$. Since G-value in pipe of actual membrane filtration system are usually larger than $3100sec^{-1}$. The performance of in-line injection system is expected to be better than the conventional mixing tank system.

Relationship between Physical Property of Re-agglomerated Floc and Turbulent flow (난류모델을 이용한 재응집 Floc의 물리적 특성 연구)

  • Park, No-Suk;Kim, Seong-Su;Kim, Kwan-Youp;Kim, Jong-Oh
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.1
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    • pp.103-108
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    • 2010
  • Until now, research reports that it is difficult for brokenup floc after coagulation to reaggregate and settling efficiency of reaggregated floc is relatively low have dominated in water treatment process. In contrast, from recent study conducted by the French researcher, because the density of the reaggregated floc was higher than the previous floc, the settling efficiency of reaggregated floc increased. In this study, 15 times wet test were carried out and the removal efficiency of reagrregated floc was considerably increased. Moreover, this result was explained using the turbulent model for the flow occurred around the floc. Consequently, in the case of suitable hydrodynamic condition for the reaggregation, the characteristics of the reaggregated floc was changed into the favorable condition for improvement of settling efficiency. Also, the most important factor for reaggregation of floc was governed by hydrodynamic shear stress.

Dynamic Mechanical and Morphological Properties of Natural Rubber Vulcanizates Containing Fillers

  • Lee, Hae Gil;Park, Chan Young
    • Elastomers and Composites
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    • v.51 no.3
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    • pp.218-225
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    • 2016
  • In order to examine correlation between silane coupling agent and activator which affects the physical properties of silica filled natural rubber compound, such as heat buildup, rebound property, dynamic mechanical and morphological properties were measured. With incorporation of silane coupling agent, $tan{\delta}$ at $0^{\circ}C$ was increased and at $60^{\circ}C$ was decreased, which resulted in improving of wet grip and rolling resistance. When silane coupling agent which is corresponding to 8~10% of silica was used, most favorable heat build up and $tan{\delta}$ was obtained. And also when activator was used, dispersibility of silica was improved as a result of reduction of reaggregation of silica.

Effect of Fluorination on Electrical Behaviors of Carbon Blacks-filled HDPE Polymeric Switch

  • Seo, Min-Kang;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1337-1340
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    • 2009
  • Electrical properties of a fluorinated carbon black (CB)-filled high-density polyethylene (HDPE) polymeric switch were investigated as a function of fluorination pressure at 0.1 ~ 0.4 MPa. From the FT-IR results, the absorption spectra of the fluorinated CB show an absorption band at 1400 ~ 1000 $cm^{-1}\;for\;{\nu}_{C-F}$ and the peak intensity increased with increasing fluorination pressure. Also, the analysis of XPS spectra of the fluorinated CB indicated that fluorine content increased with increasing fluorination pressure. Meanwhile, the surface free energy of the fluorinated CB decreased with increasing fluorination pressure. Consequently, the increase of fluorine contents of CB made a disappearance of negative temperature coefficient (NTC) behavior of the polymeric switch, which was probably due to the reduction of CB reaggregation after melting point of the HDPE, resulted from the decreasing of London dispersive component of the surface free energy for CB particles.

A Study on PTC/NTC Behavior of Fluorinated Carbon Black-filled HDPE Matrix Compounds (불소처리된 카본블랙을 충전한 HDPE 기지 컴파운드의 PTC/NTC 특성에 관한 연구)

  • Soo-Jin Park;Su-Wan Song;Min-Kang Seo;Jae-Sup Shin;Kyuchul Kim
    • Journal of the Korean Chemical Society
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    • v.47 no.2
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    • pp.147-154
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    • 2003
  • In this study, the fluorinated carbon blacks(CB) were used to reduce the negative temperature coefficient (NTC) phenomenon of the CB-filled high density polyethylene(HDPE) compounds in the fluorination pressure of 0.1-0.4 MPa. The changes in surface properties of the CB were investigated by using FT-IR, XPS and contact angle measurements. From the FT-IR results, the fluorinated CB showed the C-F absorption peak at 1400-1000 cm$^{-1}$ and the peak intensity was increased with increasing the fluorination pressure. Also, the analysis of XPS spectra of the fluorinated CB indicated that fluorine content was increased with increasing the fluorination pressure. Meanwhile, the surface free energy of the fluorinated CB was decreased with increasing the fluorination pressure. Consequently, the increase of fluorine contents on CB made a disappearance of NTC behaviors of CB/HDPE compounds, which was probably due to the reduction of CB reaggregation after melting point of the HDPE, resulting from decreasing the surface free energy of CB particles.

A Study on Tensile Properties of Multi-Welled Carbon Nanotube/Epoxy Composites (다중벽 탄소나노튜브/에폭시 복합재료의 인장 물성에 관한 연구)

  • Lee Sang-Eui;Lee Won-Jun;Kim Chun-Gon
    • Composites Research
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    • v.17 no.6
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    • pp.1-7
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    • 2004
  • The studies of particulate reinforced composites have been conducted for many years. The nanocomposites to be studied vigorously in recent years are one of them. We fabricated and studied multi-walled carbon nanotube(MWNT)/epoxy composites which may be useful as matrix for continuous fiber-reinforced composites. We investigated tensile properties of MWNT/epoxy composites as a function of MWNT concentration, which were prepared by the fabrication method established in this study. Tensile stiffness and strength increased 19% at 0.5 wt% and 12% at 0.2 wt%, respectively. We observed the reaggregation phenomenon of MWNTS during curing, which should be controlled to obtain higher tensile properties.

N2 plasma treatment of pigments with minute particle sizes to improve their dispersion properties in deionized water

  • Zhang, Jingjing;Park, Yeong Min;Tan, Xing Yan;Bae, Mun Ki;Kim, Dong Jun;Jang, Tae Hwan;Kim, Min Su;Lee, Seung Whan;Kim, Tae Gyu
    • Journal of Ceramic Processing Research
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    • v.20 no.6
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    • pp.589-596
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    • 2019
  • Pigments with minute particle sizes, such as carbon black (CB) and pigment red 48:2 (P.R.48:2), are the most important types of pigment and have been widely used in many industrial applications. However, minute particles have large surface areas, high oil absorption and low surface energy. They therefore tend to be repellent to the vehicle and lose stability, resulting in significant increases in viscosity or reaggregation in the vehicle. Therefore, finding the best way to improve the dispersion properties of minute particle size pigments presents a major technical challenge. In this study, minute particle types of CB and P.R.48:2 were treated with nitrogen gas plasma generated via radio frequency-plasma enhanced chemical vapor deposition (RF-PECVD) to increase the dispersion properties of minute particles in deionized (DI) water. The morphologies and particle sizes of untreated and plasma treated particles were evaluated using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The average distributions of particle size were measured using a laser particle sizer. Fourier transform infrared spectroscopy was carried out on the samples to identify changes in molecular interactions during plasma processing. The results of our analysis indicate that N2 plasma treatment is an effective method for improving the dispersibility of minute particles of pigment in DI water.