• 제목/요약/키워드: Reactive flux

검색결과 80건 처리시간 0.018초

Canonical Sampling Method for Initial Conditions for Reactive Flux Calculations Using Nose-Hoover Chains

  • Lee, Song-Hi;Pak, Young-Shang
    • Bulletin of the Korean Chemical Society
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    • 제25권4호
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    • pp.533-538
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    • 2004
  • Canonical sampling method has been presented to generate the initial conditions for reactive flux studies of organic reactions in water. Velocity Verlet version of Nose-Hoover chain dynamics algorithm has been employed to sample the initial conditions according to canonical distribution. The unstable normal mode of a transition state has been introduced to define a dividing plane separating reactant and product regions in reaction processes. This method has been implemented and tested for the case iels-Alder reaction of methyl vinyl ketone (MVK) and cyclopentadiene (CPD) in water, providing a reliable tool for further reactive flux molecular dynamics studies in condensed media.

Reactive Sputtering Process for $CuIn_{1-x}Ga_xSe_2$ Thin Film Solar Cells

  • Park, Nae-Man;Lee, Ho Sub;Kim, Jeha
    • ETRI Journal
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    • 제34권5호
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    • pp.779-782
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    • 2012
  • $CuIn_{1-x}Ga_xSe_2$ (CIGS) thin films are grown on Mo/soda lime glass using a reactive sputtering process in which a Se cracker is used to deliver reactive Se molecules. The Cu and $(In_{0.7}Ga_{0.3})_2Se_3$ targets are simultaneously sputtered under the delivery of reactive Se. The effects of Se flux on film composition are investigated. The Cu/(In+Ga) composition ratio increases as the Se flux increases at a plasma power of less than 30 W for the Cu target. The (112) crystal orientation becomes dominant, and crystal grain size is larger with Se flux. The power conversion efficiency of a solar cell fabricated using an 800-nm CIGS film is 8.5%.

가상 자속관측기를 이용한 3상 AC/DC PFC PWM 컨버터의 직접 전력 센서리스 제어 (Direct Power Sensorless Control of Three-Phase AC/DC PFC PWM Converter using Virtual Flux Observer)

  • 김영삼;권영안
    • 전기학회논문지
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    • 제61권10호
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    • pp.1442-1447
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    • 2012
  • In this paper, direct power control system for three-phase PWM AC/DC converter without the source voltage sensors is proposed. The sinusoidal input current and unity effective power factor are realised based on the estimated flux in the observer. Both active and reactive power calculated using estimated flux. The estimation of flux is performed based on the Reduced-order flux observer using the actual currents and the command control voltage. The source voltage sensors are replaced by a flux estimator. The active and reactive powers estimation are performed based on the estimated flux and Phase anble. The proposed algorithm is verified through simulation and experiment.

가상자속관측기를 이용한 3상 AC/DC PWM PFC 컨버터의 입력전압 센서리스 제어 개선 (Improved Input Voltage Sensorless Control of Three-Phase AC/DC PWM PFC Converter using Virtual Flux Observer)

  • 김영삼;소상호
    • 한국군사과학기술학회지
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    • 제16권4호
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    • pp.566-574
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    • 2013
  • In this paper, direct power control system for three-phase PFC AC/DC converter without the source voltage sensors is proposed. The sinusoidal input current and unity effective power factor are realised based on the estimated flux in the observer. Both active and reactive power calculated using estimated flux. The estimation of flux is performed based on the reduced-order virtual flux observer using the actual currents and the command control voltage. Moreover, source voltage sensors are replaced by a estimated flux. DC output voltage has been compensated by DC output ripple voltage estimation algorithm. The active and reactive powers estimation are performed based on the estimated flux and Phase angle. The proposed algorithm is verified through simulation and experiment.

단일 인버터 기반 에어컨용 실외기 팬 모터 병렬운전에서의 무효전력보상기를 이용한 맥동저감 기법 (The Vibration Suppression using Reactive Power Compensator for Speed Control of Parallel Connected Dual Fan Motors fed by a Single Inverter)

  • 윤철;권우현;조내수
    • 전기학회논문지
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    • 제65권12호
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    • pp.2008-2013
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    • 2016
  • This paper proposes analysis and suppression method for reactive power vibration of the slave motor caused by back-EMF mismatch between the master and the slave motor and stator resistance during middle-low speed operation. The master and slave motors are parallel connected dual SPMSMs(Surface mounted Permanent Magnet Synchronous Motors) fed by a single inverter. To suppress vibration of reactive power, RPC(Reactive Power Compensator) proposed in this paper analyzes flux-axis current vibration of the slave motor that occurs in middle-low speed operation using a mathematical model of the fan motor. And RPC adds vibration components detected from flux-axis current of the slave motor to flux-axis current of the master motor. The results of experiment conducted verify the efficacy of the proposed method.

NF막에 의한 다양한 염료용액의 막분리 특성 (Study on the Nanofiltration of Various Dye Solutions)

  • 양정목;김탁현;박철환;김지형;김상용
    • 청정기술
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    • 제10권1호
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    • pp.37-45
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    • 2004
  • 본 연구는 섬유산업에서 많이 사용되고 있는 주요염료인 분산성, 반응성, 산성염료를 대상으로 일반적인 수질오염항목인 COD, T-N, TOC, color, SS, TDS, conductivity 등을 분석하여 각각의 염료용액의 성상을 비교 분석하였고, NF막을 투과시켰을 경우 투과 flux와 배제율이 염료용액 종류에 따라서 어떻게 다른 양상을 나타내는지를 연구하였다. 결과적으로, 염료종류별 화학적 성질 및 구조적인 차이에 의하여 염료용액의 용해도 및 유기물부하 등이 달라짐을 알 수 있었고, 특히, 분산성 염료와 반응성염료는 이들 화학적 성질의 차이가 매우 현격하게 달라서 투과 flux 감소현상과 유기물, color, 부유물 및 용존 고형물, 이온성 물질 등의 배제율이 다른 양상을 보임을 알 수 있었다. 반응성염료 용액은 분산성염료 용액에 비하여 투과 flux는 높지만, TDS의 배제율이 낮은 반면, 분산성염료 용액은 부유성 고형물 농도가 높아 투과 flux가 낮고, 유기물질의 배제율이 낮은 특성을 나타낸다.

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Impaired Autophagic Flux in Glucose-Deprived Cells: An Outcome of Lysosomal Acidification Failure Exacerbated by Mitophagy Dysfunction

  • Eun Seong Hwang;Seon Beom Song
    • Molecules and Cells
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    • 제46권11호
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    • pp.655-663
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    • 2023
  • Autophagy dysfunction is associated with human diseases and conditions including neurodegenerative diseases, metabolic issues, and chronic infections. Additionally, the decline in autophagic activity contributes to tissue and organ dysfunction and aging-related diseases. Several factors, such as down-regulation of autophagy components and activators, oxidative damage, microinflammation, and impaired autophagy flux, are linked to autophagy decline. An autophagy flux impairment (AFI) has been implicated in neurological disorders and in certain other pathological conditions. Here, to enhance our understanding of AFI, we conducted a comprehensive literature review of findings derived from two well-studied cellular stress models: glucose deprivation and replicative senescence. Glucose deprivation is a condition in which cells heavily rely on oxidative phosphorylation for ATP generation. Autophagy is activated, but its flux is hindered at the autolysis step, primarily due to an impairment of lysosomal acidity. Cells undergoing replicative senescence also experience AFI, which is also known to be caused by lysosomal acidity failure. Both glucose deprivation and replicative senescence elevate levels of reactive oxygen species (ROS), affecting lysosomal acidification. Mitochondrial alterations play a crucial role in elevating ROS generation and reducing lysosomal acidity, highlighting their association with autophagy dysfunction and disease conditions. This paper delves into the underlying molecular and cellular pathways of AFI in glucose-deprived cells, providing insights into potential strategies for managing AFI that is driven by lysosomal acidity failure. Furthermore, the investigation on the roles of mitochondrial dysfunction sheds light on the potential effectiveness of modulating mitochondrial function to overcome AFI, offering new possibilities for therapeutic interventions.

침적 모형에 의한 습성침적 플럭스 수치모의 (Numerical simulation of wet deposition flux by the deposition model)

  • 이화운;문난경;임주연
    • 한국환경과학회지
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    • 제11권12호
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    • pp.1235-1242
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    • 2002
  • The purpose of this study is to estimate wet deposition flux and to investigate wet deposition characteristics by using the ADOM model. Wet deposition flux of highly reactive $SO_2$ is estimated by applying observed meteorological parameters and concentrations of chemical species to the ADOM model. Wet deposition is largely dependent on large scale precipitation and cloud thickness. Wet deposition flux of sulfate depends on $SO_2$ oxidation in clouds. When large amount of $SO_2$ is converted to sulfate, deposition flux of sulfate increases, but wet deposition flux of $SO_2$ is small. On the whole, the pattern of sulfate wet deposition flux agrees with the typical pattern of sulfate wet deposition that is high in the summer(July) and low in the winter(January).

압력구배의 주기적 변화에 따른 한외여과 Flux의 변화 (Response of Ultrafiltration Flux to Periodic Oscillations in Transmembrane Pressure Gradient)

  • 서창우;이은규
    • KSBB Journal
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    • 제14권2호
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    • pp.230-234
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    • 1999
  • 한외여과공정에서 압력구배를 주기적으로 변화시켜 막 표면의 용질층을 불안정화시켜 여과 flux의 총괄적 향상을 유도한 실험을 수행하였다. 일정압력에서의 여과 flux 감소현상을 Hernia 식을 사용하여 모사하였고, 또한 압력구배의 주기적 변화를 Fourer series로 표현하여 압력구배의 변화에 따른 flux 변화를 수학적으로 모사하였고 이 결과를 실제의 실험결과와 비교하여 보았다. 수학적 모사결과 압력변화의 형태, 진폭, 주기 등의 변화에 따른 평균 flux의 변화는 미미하였다. 하지만 실제실험결과 주기적으로 압력구배를 변화시킨 경우 약 11%의 향상을 관찰할 수 있었다. 이는 압력구배가 주기적으로 변하는 과정에서의 응질층의 압축이완속도가 다른 것에 기인하는 것으로 유추된다. 주기적 압력구배변화외에 feed pump interruption을 이용하여 평균총괄 flux를 약 32%까지 향상 시켰다. 역확산에 의한 용질층의 이완에는 일정한 시간이 필요함을 찾아내었고 interruption은 용질층이 형성되기 전부터 시작하는 것이 유리하다고 판단되었다. 본 실험을 위하여 한외여과의 자동제어 시스템을 설계제작하여 다양한 압력함수를 이용할 수 있었고, 공정운영 중 압력구매와 여과 flux를 실시간 모니터링 및 제어할 수 있었다. 자동제어 시스템을 통해 압력구매를 주기적으로 변화시켜 총괄 flux의 극대화를 도모하는 기법은 기존장치를 최소로 변경시키면서 한외여과성능을 극대화시킬 수 있는 방법으로 기대된다.

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Sensitivity Study of the Flow-through Dynamic Flux Chamber Technique for the Soil NO Emissions

  • Kim Deug-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • 제21권E3호
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    • pp.75-85
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    • 2005
  • A mathematical sensitivity analysis of the flow-through dynamic flux chamber technique, which has been utilized usually for various trace gas flux measurement from soil and water surface, was performed in an effort to provide physical and mathematical understandings of parameters essential for the NO flux calculation. The mass balance equation including chemical reactions was analytically solved for the soil NO flux under the steady state condition. The equilibrium concentration inside the chamber, $C_{eq}$, was found to be determined mainly by the balance between the soil flux and dilution of the gas concentration inside the chamber by introducing the ambient air. Surface deposition NO occurs inside the chamber when the $C_{eq}$ is greater than the ambient NO concentration ($C_{0}$) introducing to the chamber; NO emission from the soil occurs when the $C_{eq}$ is less than the ambient NO concentration. A sensitivity analysis of the significance of the chemical reactions of NO with the reactive species (i.e. $HO_{2},/CH_{3}O_{2},/O_{3}$) on the NO flux from soils was performed. The result of the analysis suggests that the NO flux calculated in the absence of chemical reactions and wall loss could be in error ranges from 40 to $85\%$ to the total flux.