• Korean Journal of Metals and Materials
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• v.50 no.11
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• pp.855-859
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• 2012

Samples with compositions of 80 wt% Mg-14 wt% Ni-6 wt% $Fe_2O_3$ and 80 wt% Mg-14 wt% Ni-6 wt% Ti were prepared by mechanical grinding under hydrogen (reactive mechanical grinding). Their hydrogen absorptions during reactive mechanical grinding were examined. TGA and BET analysis were employed to investigate the hydrogen storage properties of the prepared alloys. TGA analysis of the $Mg-14Ni-6Fe_2O_3$ showed an absorbed hydrogen quantity of 6.91 wt% while that of Mg-14Ni-6Ti was 2.59 wt%. BET analysis showed that the specific surface areas of $Mg-14Ni-6Fe_2O_3$ and Mg-14Ni-6Ti after reactive mechanical grinding were $264m^2/g$ and $64m^2/g$, respectively. The larger absorbed hydrogen quantity and the larger specific surface area of $Mg-14Ni-6Fe_2O_3$ after RMG than those of Mg-14Ni-6Ti after RMG showed that the effects of $Fe_2O_3$ addition are much stronger than those of Ti addition during reactive mechanical grinding.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.24 no.7
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• pp.9-19
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• 2010

Fuel cell (FC) distributed generation (DG) is gradually becoming more attractive to mainstream electricity users as capacity improves and costs decrease. New technologies including inverters are becoming available to provide a uniform standard interconnection of DGs with an electric power system. Some of the operating conflicts and the effect of DG on power quality are addressed and investigated through simulations on a real distribution network with an FC power plant. The results of these simulations have proved load tracking capability following the real and reactive power change of the load and have shown the flow of overcurrent from an FC power plant during the ground fault of a distribution line.

• Journal of the Korean Society for Aviation and Aeronautics
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• v.15 no.4
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• pp.17-23
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• 2007

This paper describes the flow and performance characteristics inside the post-chamber of the multi-port hybrid rocket motor. Using the computational fluid dynamics (CFD) technique, the non reactive compressible flow fields in the downstream of the fuel grain was numerically calculated. The motor performance obtained from computational results were in agreement with that conducted by the ground motor firing test. Besides, the flow field characteristics inside the post-chamber were discussed under different port numbers (1 port and 3 ports) of the fuel grain. The flow pattern showed that the performance of multi-port hybrid rocket motor having three grain ports is higher than that of the single-port one due mainly to the difference of incoming mass flow rate irrespective to the pressure field.

• Journal of the Korean Ceramic Society
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• v.43 no.11 s.294
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• pp.746-750
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• 2006

NiO films and Ru co-sputtered NiO films were deposited by reactive magnetron sputtering for micro-solid oxide fuel cell anode applications. The deposited films were reduced to form porous films. The reduction kinetics of the Ru doped NiO film was more sluggish than that of the NiO film, and the resulting microstructure of the former exhibited finer pore networks. The possibility of using the films for the anodes of single chamber micro-SOFCs was investigated using an air/fuel mixed environment. It was found that the abrupt increase in the resistance is suppressed in the Ru co-sputtered film, as compared to undoped film.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.6
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• pp.75-82
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• 2021

Low-temperature combustion (LTC) strategies, such as HCCI (Homogeneous Charge Compression Ignition), PCCI (Premixed Charge Compression Ignition), and RCCI (Reactivity Controlled Compression Ignition), have been developed to effectively reduce NOx and PM while increasing the thermal efficiency of diesel engines. Through numerical analysis, this study examined the effects of the injection timing and two-stage injection ratio of diesel fuel, a highly reactive fuel, on the performance and exhaust gas of RCCI engines using gasoline as the low reactive fuel and diesel as the highly reactive fuel. In the case of two-stage injection, combustion slows down if the first injection timing is too advanced. The combustion temperature decreases, resulting in lower combustion performance and an increase in HC and CO. The injection timing of approximately -60°ATDC is considered the optimal injection timing considering the combustion performance, exhaust gas, and maximum pressure rise rate. When the second injection timing was changed during the two-stage injection, considering the combustion performance, exhaust gas, and the maximum pressure increase rate, it was judged to be optimal around -30°ATDC. In the case of two-stage injection, the optimal result was obtained when the first injection amount was set to approximately 60%. Finally, a two-stage injection rather than a single injection was considered more effective on the combustion performance and exhaust gas.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.5
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• pp.513-520
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• 2012

The electrochemical reaction of refuse derived fuel (RDF) and refuse plastic/paper fuel (RPF) was investigated in the direct carbon fuel cell (DCFC) system. The open circuit voltage (OCV) of RPF was higher than RDF and other coals because of its thermal reactive characteristic under carbon dioxide. The thermal reactivity of fuels was investigated by thermogravimetric analysis method. and the reaction rate of RPF was higher than other fuels. The behavior of all sample's potential was analogous in the beginning region of electrochemical reactions due to similar functional groups on the surface of fuels analyzed by X-ray Photoelectron Spectroscopy experiments. The potential level of RDF and RPF decreased rapidly comparing to coals in the next of the electrochemical reaction because the surface area and pore volume investigated by nitrogen gas adsorption tests were smaller than coals. This characteristic signifies the contact surface between electrolyte and fuel is restricted. The potential of fuels was maintained to the high current density region over 40 $mA/cm^2$ by total carbon component. The maximum power density of RDF and RPF reached up to 45~70% comparing to coal. The obvious improvement of maximum power density by increasing operating temperature was observed in both refuse fuels.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.16 no.1
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• pp.75-79
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• 2007

The cathode design is one of the most important parts in order to enhance the performance of fuel cells. A 3-D model of the porous oxygen reducing cathode with perforated current collectors is analysed for the enhanced design in fuel cells. Simulation is performed using equations of electric potential balance, momentum balance, and mass balance. The gas concentrations are quite large and are significantly affected by the reactions that take place. The weight fraction of oxygen, velocity field for the gas phase, and local overvoltage are illustrated in the porous reactive cathode layer. The current density is also analysed and the result shows the distribution and variation are stated in a wide range. It is found that the rate of reaction and the current production is higher beneath the orifice, and decreases as the distance to the gas inlet increases. The significance of the results is discussed in the viewpoint of the mass transportation phenomena, which is inferred that the mass transport of reactants dictates the efficiency of the electrode in this design and at these conditions.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.03a
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• pp.346-357
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• 2008

Endothermic fuels are known as a probable fuel for hypersonic atmospheric flight vehicles and advanced propulsion systems, as well as cryogenic fuels. Especially, from the standpoint of the advanced regenerative cooling use, they are quite useful as a coolant fuel because of their large heat sink due to their chemical decompositions; so-called endothermic cooling effect. However, no heat transfer equations have been proposed taking into account such endothermic reactive behaviors concretely. This paper describes an analytical method for evaluation of the heat transfer rates between endothermic reacting coolant fuel and coolant-side wall in the regenerative cooling passages. Heat transfer mechanism is indicated based on a classical transport-phenomenological approach. A new relational expression of Nusselt number ratio for forcedconvective heat transfer with such endothermic reactions is also proposed by theoretical approaches using some classical hypotheses. Its applicability is assessed provisionally by comparison with confirmed results of heated tube tests for supercritical JP-7 fuel carried out at NASA Lewis Research Center, using its heat sink characteristics evaluated by United Technologies Research Center(UTRC). As a result, it has been suggested that the proposed relational equation is applicable to the evaluation of enhancement of Nusselt numbers due to such reactions in developed turbulent flows such as in the regenerative cooling passages.

• Journal of the Korean Society of Propulsion Engineers
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• v.26 no.6
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• pp.74-85
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• 2022

Since the late 1990s, the demand for developing green or reduced-toxic storable propellants has been rising to replace the existing toxic propellants. Most of the research activities are focusing on development of new hypergolic fuels and either white fuming nitric acid or hydrogen peroxide is utilized as an oxidizer. The newly-developed hypergolic fuels are classified as three types, catalytic fuel, reactive fuel, and ionic fuel. In the present study, recent R&D trend of ionic liquid propellants is described and the main results in the previous studies are analyzed.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.2
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• pp.250-258
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• 2010

A numerical analysis of reactive flow in a liftoff flame is accomplished to elucidate the characteristics of flame propagation velocity and volume integral of reaction rate with the variation of nozzle diameter and fuel injection flow rate in a liftoff flame consisted with fuel rich region, fuel lean region and diffusion flame region. The increase of fuel injection velocity enhances flame propagation velocity for the selected three nozzle diameter(d=0.25, 0.30, 0.35mm), but its effect on the flame propagation velocity is not much greater than 4.3%. The increase of fuel flow rate is directly and linearly related with the volume reaction rate and so the volume reaction rate, not the flame propagation velocity, might be considered to accommodate the variation of fuel flow rate in a liftoff flame.