• 에너지공학
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• 제4권2호
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• pp.297-302
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• 1995

Ignition of a reactive solid in a shape of square corner by a hot surface is studied theoretically. Ignition time and the location of ignition point are determined as a function of dimensionless parameters, with the use of the homogeneous model of ignition. The effect of geometry on the ignition of solid fuel results in the local characteristics: the reaction is initiated in a hot point in depth of the substance. It is shown that ignition time is proportional to the dimensionless initial temperature, whereas for the ignition of the semiinfinite body this dependence was quadratic.

• 방사성폐기물학회지
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• 제13권3호
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• pp.181-186
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• 2015

사용후핵연료 파이로프로세싱에서 발생하는 방사성폐기물의 양을 최소화하기 위해서는 방사성 핵종 함유 염폐기물을 효과적으로 처리할 수 있는 기술개발이 필요하다. 이를 위해 탄산화물(Li₂CO₃, K₂CO₃)을 이용한 반응증류공정에서 LiCl-KCl 공융염 내 NdCl₃의 분리특성을 관찰하였다. HSC-Chemistry 프로그램을 이용한 탄산화물과 NdCl₃의 반응모델결과에서 NdCl₃는 탄산화물의 주입조건 및 온도변화에 따라 산염화물(NdOCl) 또는 산화물(Nd₂O₃) 형태로 전환됨이 확인되었으며, 탄산화물의 주입조건에 따른 LiCl-KCl-NdCl₃계의 반응증류시험에서 반응모델결과와 유사한 경향을 확인하였다. 이 결과들을 이용하여 LiCl-KCl 공융염 내 NdCl₃를 고화가 용이한 산화물 형태로 분리하기 위한 공정조건을 도출하였다.

• Computers and Concrete
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• 제10권4호
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• pp.349-360
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• 2012

In this paper, compressive strength, water permeability and abrasion resistance of concretes containing high volume fine fly ash (FFA) and fine ground palm oil fuel ash (GPA) were studied. Portland cement type I was replaced with FFA and GPA at dosages up to 70% by weight of binder. Ground river sand (GRS) was also used to replace Portland cement in order to indicate the level of filler effect. Results indicated that FFA was slightly more reactive than GPA. The replacement of 40-70% of FFA produced concretes with compressive strength, permeability and abrasion resistance comparable to those of normal concretes. The incorporation of GPA slightly reduced the performances of concretes as compared to those of FFA concretes. The reduction of Portland cement was partly compensated by the increase in pozzolanic activity of the fine fly ash and palm oil fuel ash and thus enabled the large replacement levels.

• 한국자동차공학회논문집
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• 제3권5호
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• pp.111-121
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• 1995

The initiation and propagation of detonation waves in the air/fuel spray mixture has been numerically analyzed. An improved pressure-based method has been applied to predict the transient heterogeneous reacting flows at all speeds. Numerical results indicate that variations in the temperature gradient, the droplet size, and the fuel vapor concentration have the significant effects on the development of detonation wave in the multi-phase reactive media. The interaction mechanism between the flame-generated pressure wave and the combustion wave is discussed in detail.

• KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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• 제4B권4호
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• pp.217-224
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• 2004

A novel anti-islanding method for the distributed power generation system (DPGS) is proposed in this paper. Three different islanding scenarios are explored and presented based on the analysis of real and reactive power mismatch. It is shown via investigation that islanding voltage is a function of real power alone, where its frequency is a function of both real and reactive power. Following this analysis, a robust anti-islanding algorithm is developed. The proposed algorithm continuously perturbs ($\pm$5%) the reactive power supplied by the DPGS while simultaneously monitoring the utility voltage and frequency. In the event of islanding, a measurable frequency deviation takes place, upon which the real power of the DPGS is further reduced to 80%. A drop in voltage positively confirms islanding and the DPGS is then safely disconnected. This method of control is shown to be robust: it is able to detect islanding under resonant loads and is also fast acting (operable in one cycle). Possible islanding conditions are simulated and verified through analysis. Experimental results on a 0.5kW fuel cell system connected to a utility grid are discussed.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.487-490
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• 2008

Temperature programmed oxidation (TPO) is used to characterize coke species deposited on commercial nickel catalyst, C11-PR during propane pre-reforming. Propane pre-reforming performed under various condition, S/C from 1.5 to 2.5 and temperature from $350^{\circ}C$ to $450^{\circ}C$. There are three kinds of coke species detected by TPO: (i) reactive coke, (ii) coke deposited on metal site and (iii) coke deposited on acid support. Coke deposited on metal and support are minimized although reactive coke is generated at temperature of $400^{\circ}C$ and S/C of 2.0. Reactive coke is expected to remove easily below temperature of $200^{\circ}C$. Therefore, optimized pre-reforming condition for propane is $400^{\circ}C$ and S/C of 2.0.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2008년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
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• pp.239-241
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• 2008

A powered system with fuel cell is regarded as a high current and low voltage source. Effects of the loads on the electrical power source are important to optimize the integrated power system. The design parameters of the system should be chosen by taking into account the characteristics of the fuel cell, so the costs of the power system at given operating conditions can be reduced. Furthermore, the dynamics characteristic of the system is crucial to acquire performance in applications, particularly interactions between loads and the fuel cell system. Currently, no integrated simulation has been approached to analyze interrelated effects. Therefore, the dynamic models of power conversion system with a PEM fuel cell that includes the PEM fuel cell stack, DC/DC converter and associated controls is developed. Electric lads for the system are derived by using a power theory that separates a load current into active, reactive, distortion or a mixed current component. Dependency of the DC capacitor on the loads are analyzed.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 제33회 추계학술대회논문집
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• pp.289-292
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• 2009

본 연구에서는 감광유리를 이용한 PEM 마이크로 연료전지 바이폴라 플레이트의 제작 공정을 확립하고 성능 측정을 수행하였다. 감광유리는 무게가 가볍고 내화학성이 뛰어나며 제작이 용이하다. 비등방성 식각, 열 및 UV 접합, 그리고 금속 층 적층을 통한 MEMS 제작 공정이 확립되었다. 성능 측정 결과 활성화 영역에 은이 적층된 마이크로 연료전지의 성능이 그렇지 않은 것보다 우수하였으며 두 경우에서 측정된 마이크로 연료전지의 성능은 모두 국내외 마이크로 연료전지 연구 수준과 동등한 수준이었다.

• 대한금속재료학회지
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• 제50권6호
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• pp.463-468
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• 2012

A 71.5 wt%Mg-23.5 wt%Ni-5 wt%$Fe_2O_3$ (Mg-23.5Ni-$5Fe_2O_3$) sample was prepared by a quite simple process, reactive mechanical grinding, and its hydriding and dehydriding properties were then investigated. The reactive mechanical grinding of Mg with Ni and $Fe_2O_3$ is considered to facilitate nucleation and shorten the diffusion distances of the hydrogen atoms. After the hydriding-dehydriding cycling, the Mg-23.5Ni-$5Fe_2O_3$ sample contained $Mg_2Ni$ phase. Expansion and contraction of the hydride-forming materials (Mg and $Mg_2Ni$) with the hydriding and dehydriding reactions are also considered to increase the hydriding and dehydriding rates of the mixture by forming defects and cracks leading to the fragmentation of the particles. The temperature dependence of the hydriding rate of the sample is discussed.

• 대한금속재료학회지
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• 제50권10호
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• pp.769-774
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• 2012

Mg-x wt% $Fe_2O_3-y$ wt% Ni samples were prepared by reactive mechanical grinding in a planetary ball mill, and their hydrogen-storage properties were investigated and compared. Activations of $Mg-5Fe_2O_3-5Ni$ was completed after one hydriding (under 12 bar $H_2$) - dehydriding (in vacuum) cycle at 593 K. At n = 2, $Mg-5Fe_2O_3-5Ni$ absorbed 3.43 wt% H for 5 min, 3.57 wt% H for 10 min, 3.76 wt% H for 20 min, and 3.98 wt% H for 60 min. Activated $Mg-10Fe_2O_3$ had the highest hydriding rate, absorbing 2.99 wt% H for 2.5 min, 4.86 wt% H for 10 min, and 5.54 wt% H for 60 min at 593 K under 12 bar $H_2$. Activated $Mg-10Fe_2O_3-5Ni$ had the highest dehydriding rate, desorbing 1.31 wt% H for 10 min, 2.91 wt% H for 30 min, and 3.83 wt% H for 60 min at 593 K under 1.0 bar $H_2$.