• Title/Summary/Keyword: Reactive Fuel

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Efficient Method of fixing the Setting(4M standardization) in Melting furnace Operation (용해로 운전에서 Setting고정(4M 표준화)의 효율적 방안)

  • Jang, Do-Soo;Lee, Sae-Jae;Suh, Jung-Yul;Kim, I-Nam;Chung, Chong-Won;Cho, Jin-Hyung
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.30 no.1
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    • pp.96-104
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    • 2007
  • Glass melting process is influenced by both control and observation factors, where control factors include quantity and mixing ratio of raw material, the amount of fuel and air in-take. Further observation factors include temperature and pressure at each step of process inside glass melting furnace. Ambient Control is an effective means to eliminate complications from excessive variation among raw materials, or external disturbance from wide fluctuation of environment around equipments. Ambient Control uses both control and observation factors mentioned above. This study suggests an effective Proactive Control System that can enable genuine 4M standardization in glass melting furnace by applying Ambient Control.

High Rate Deposition System by Inductively Coupled Plasma Assisted Sputter-sublimation (유도 결합 플라즈마 스퍼터 승화법을 이용한 고속증착 시스템)

  • Choi, Ji-Sung;Joo, Jung-Hoon
    • Journal of the Korean institute of surface engineering
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    • v.45 no.2
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    • pp.75-80
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    • 2012
  • A sputter-sublimation source was tested for high rate deposition of protective coating of PEMFC(polymer electrolyte membrane fuel cell) with high electrical conductivity and anti-corrosion capability by DC biasing of a metal rod immersed in inductively coupled plasma. A SUS(stainless steel) tube, rod were tested for low thermal conductivity materials and copper for high thermal conductivity ones. At 10 mTorr of Ar ICP(inductively coupled plasma) with 2.4 MHz, 300 W, the surface temperature of a SUS rod reached to $1,289^{\circ}C$ with a dc bias of 150 W (-706 V, 0.21 A) in 2 mins. For 10 min of sputter-sublimation, 0.1 gr of SUS rod was sputter-sublimated which is a good evidence of a high rate deposition source. ICP is used for sputter-sublimation of a target material, for substrate pre-treatment, film quality improvement by high energy particle bombardment and reactive deposition.

Effect of CNT Addition on the Hydriding and Dehydriding Rates of Mg-Ni-Fe2O3 Alloy

  • Song, Myoung Youp;Kwak, Young Jun;Lee, Byung-Soo;Park, Hye Ryoung;Kim, Byoung-Goan
    • Korean Journal of Metals and Materials
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    • v.49 no.12
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    • pp.989-994
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    • 2011
  • Samples with compositions of 80 wt% Mg-14 wt% Ni-6 wt% $Fe_2O_3$ (named $Mg-Ni-Fe_2O_3$), and 78 wt% Mg-14 wt% Ni-6 wt% $Fe_2O_3-2$ wt% CNT (named $Mg-Ni-Fe_2O_3-CNT$ ) were prepared by reactive mechanical grinding. Hydriding and dehydriding properties and effects of CNT addition on the hydriding and dehydriding rates of $Mg-Ni-Fe_2O_3$ were then investigated. Activation of the $Mg-14Ni-6Fe_2O_3$ sample was completed after three hydriding (under 12 bar $H_2$)-dehydriding (under 1.0 bar $H_2$) cycles at 573 K. The addition of CNT to the $Mg-14Ni-6Fe_2O_3$ sample made the activation process unnecessary, with a small decrease in the hydrogen-storage capacity.

In-situ functionalized biomass derived graphite-supported BiFeO3 for eradication of pollutants

  • Deepeka, Deepeka;Paramdeep, Kaur;Jyoti, Jyoti;Sandeep, Bansal;Sonal, Singhal
    • Advances in nano research
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    • v.13 no.6
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    • pp.527-543
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    • 2022
  • A novel, green, versatile and magnetically retrievable BiFeO3/CDR (Bismuth ferrite/coriander) nanocomposites were fabricated via simple wet chemical method utilizing in situ functionalized, cheap coriander seed powder (CDR 5%, 10%, 15% and 20 wt%) as a fuel to enhance the efficiency of pristine BiFeO3. A comparative study was performed between BiFeO3/CDR and BiFeO3/CNT (Bismuth ferrite/carbon nanotubes) nanocomposites for the removal of various hazardous pollutants from waste water. The successful synthesis of the fabricated nanomaterials was monitored via FT-IR, Powder XRD, FE-SEM, CV, VSM, CHNS/O and XPS studies. The synthesized nanomaterials were employed for the oxidative degradation of Carbol fuchsin, Reactive black 5, Ciprofloxacin and Doxorubicin; adsorption of a pesticide malathion; and reduction studies for Para-nitrophenol (PNP). The fabricated nanomaterials (BiFeO3/CDR) showcased excellent efficiency and comparable results with (BiFeO3/CNT) for the removal of model pollutants. Moreover, synthesized green heterojunction was also testified for mixture of textile and pharmaceutical waste. Hence CDR can be utilized as a better alternative of CNTs.

Numerical Investigation on detonation combustion waves of hydrogen-air mixture in pulse detonation combustor with blockage

  • Pinku Debnath;K.M. Pandey
    • Advances in aircraft and spacecraft science
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    • v.10 no.3
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    • pp.203-222
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    • 2023
  • The detonation combustion is a supersonic combustion process follows on shock wave oscillations in detonation tube. In this paper numerical studies are carried out combined effect of blockage ratio and spacing of obstacle on detonation wave propagation of hydrogen-air mixture in pulse detonation combustor. The deflagration to detonation transition of stoichiometric (ϕ=1)fuel-air mixture in channel has been analyzed for effect of blockage ratio (BR)=0.39, 0.51, 0.59, 0.71 with spacing of 2D and 3D. The reactive Navier-Stokes equation is used to solve the detonation wave propagation mechanism in Ansys Fluent platform. The result shows that fully developed detonation wave initiation regime is observed near smaller vortex generator ratio of BR=0.39 inside the combustor. The turbulent rate of reaction has also a great significance role for shock wave structure. However, vortices of rapid detonation wave are appears near thin boundary layer of each obstacle. Finally, detonation combustor demonstrates the superiority of pressure gain combustor with turbulent rate of reaction of 0.6 kg mol/m3 -s inside the detonation tube with obstacle spacing of 12 cm, this blockage enhanced the turbulence intensity and propulsive thrust. The successful detonation wave propagation speed is achieved in shortest possible time of 0.031s with a significance magnitude of 2349 m/s, which is higher than Chapman-Jouguet (C-J) velocity of 1848 m/s. Furthermore, stronger propulsive thrust force of 36.82 N is generated in pulse time of 0.031s.

Influence of Mixtures and Curing Conditions on Strength and Microstructure of Reactive Powder Concrete Using Ternary Pozzolanic Materials (배합 및 양생조건이 3성분계 포졸란재를 이용한 RPC의 강도발현 특성에 미치는 영향)

  • Janchivdorj, Khulgadai;Choi, Seung-Hoon;So, Hyoung-Seok;Seo, Ki-Seog;So, Seung-Young
    • Journal of the Korea Concrete Institute
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    • v.25 no.4
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    • pp.457-465
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    • 2013
  • This study discussed the influence of mixtures and curing conditions on the development of strength and microstructure of RPC using ternary pozzolanic materials. Through pilot experiment, various RPC was manufactured by adding single or mixed ternary pozzolanic materials such as silica fume, blast furnace slag and fly ash by mass of cement, up to 0~65%, and cured by using 4 types of method which are water and air-dried curing at $20^{\circ}C$, steam and hot-water curing at $90^{\circ}C$. The results show that the use of ternary pozzolanic materials and a suitable curing method are an effective method for improving development of strength and microstructure of RPC. The unit volume of cement was greatly reduced in RPC with ternary pozzolanic materials and unlike hydration reaction in cement, the pozzolanic reaction noticeably contributes to a reduction in hydration heat and dry shrinkage. A considerable improvement was found in the flexural strength of RPC using ternary pozzolanic materials, and then the utilization of a structural member subjected to bending was expected. The X-ray diffractometer (XRD) analysis and Scanning Electronic Microscope (SEM) revealed that the microstructure of RPC was denser by using the ternary pozzolanic materials than the original RPC containing silica fume only.

Absorbance Elevation of Orimax Blue 2N, Orimax Green 151, Quinizarin, Topasol (P-250) and Lubricant (P-8) on the Spectrophotometric Analysis of Unimark 1494 DB (식별제(Unimark 1494DB) 정량시험에서 파란색 색소(Orimax Blue 2N, Orimax Green 151), Quinizarin, 토파졸(P-250) 및 윤활유 원료(P-8)의 흡광도상승 효과)

  • Lee, Ji-Yun;Kim, Chang-Jong
    • YAKHAK HOEJI
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    • v.50 no.5
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    • pp.313-321
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    • 2006
  • There are three kinds of liquid petroleum marker which is extracted by the basic or acidic, and both developer. Korean marker, Unimark 1494 DB (marker) have been spectrophotometrically analysed by the determination of absorbance at 582 nm after base extraction by Unimark 1494 DB Developer C-5 (developer). Some blue dyes which have same reactive radical of marker and can be changed deep blue color in base developer extraction (BDE), may be increased absorbance at 582 nm, but dyes or markers which can be increased the absorbance, were not unclear. In this experiment, effects of three dyes or marker such as Orimax Green 151 (the mixture of CI Solvent Yellow 16 and CI Solvent Blue 70), quinizarin and Orimax Blue 2N (CI Solvent Blue 35), and two solvent such as topasol (P-250) and lubricant (P-8) on the absorbance were studied by HITACHI Recording Spectrophotometer U-3300. It shows that all of them increased absorbance at 582 nm after BDE. Absorbance at 582 nm can be showed 0.0544 by Orimax Green 151 at the concentration of 3.96 mg/l, quinizarin at the concentration of 1.38 mg/l, and Orimax Blue 2N at the concentration of 2.73 mg/l in the artificial petroleum (normal diesel oil: topasol: lubricant=2 : 4: 4), respectively. Absorbance, 0.0544 indicates that concentration of marker is 1.64 mg/l in the reference curves, respectively. And also these results can be showed that the artificial petroleum have about 10% cheep fuel such as kerosene which have marker (16.0 mg/l). Absorbance of P-250 was 0.01361-0.22842 depending upon the purchasing date, and that of P-8 was 0.05644. pH of developer was 14.83, and so this result indicates that Unimark 1494 DB is a base extractable petroleum marker, phenylazophenol (US Patent No. 5,252,106). In the BDE, the slight color of Orimax Blue 2N, Orimax Green 151 and quinizarin in artificial petroleum changed to deep bright blue color, respectively. These result indicate that the absorbance at 582 nm by BDE may be increased not only by azo, diazo, amine and ketone (anthraquinone, coumarin) dyes or markers, but also the contaminants of P-250 and P-8 which have same as reactive radical of dyes or markers.

Numerical Study of Flow Characteristics in a Solid Particle Incinerator for Various Design Parameters of Injectors (고체 입자 소각로에서 분사기의 설계 인자에 따른 유동 특성에 관한 수치해석적 연구)

  • Son, Jin Woo;Kim, Su Ho;Sohn, Chae Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.12
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    • pp.1079-1089
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    • 2013
  • The flow characteristics in a solid particle incinerator are investigated numerically for high burning rate of wastes. The studied incinerator employs both a swirl flow used in the furnace of powerplants and a design concept applied to a rocket combustor. As the first step, the non-reactive flow field is analyzed in the incinerator with primary and secondary injectors through which solid fuel and air are injected. The deflection angle of a primary injector, inclination angle of a secondary injector, and gap between the two types of injectors are selected as design parameters. The swirl number is adopted for evaluating the degree of swirl flow and estimated over wide ranges of three parameters. The swirl number increases with deflection angle, but it is affected little by inclination angle. Recirculation zones are formed near the injectors, and their size affects the swirl number. The swirl number decreases with the zonal size of recirculation. From the numerical results, the design points can be found with strong swirl flow.

Fabrication and Electrochemical Characterization of All Solid-State Thin Film Micro-Battery by in-situ Sputtering (In-situ 스퍼터링을 이용한 잔고상 박막 전지의 제작 및 전기화학적 특성 평가)

  • Jeon Eun Jeong;Yoon Young Soo;Nam Sang Cheol;Cho Won Il;Shin Young Wha
    • Journal of the Korean Electrochemical Society
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    • v.3 no.2
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    • pp.115-120
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    • 2000
  • All solid-state thin film micro-batteries consisting of lithium metal anode, an amorphous LiPON electrolyte and cathode of vanadium oxide have been fabricated and characterized, which were fabricated with cell structure of $Li/LiPON/V_2O_5Pt$. The effect of various oxygen partial pressure on the electrochemical properties of vanadium oxide thin films formed by d.c. reactive sputtering deposition were investigated. The vanadium oxide thin film with deposition condition of $20\%\;O_2/Ar$ ratio showed good cycling behavior. In in-siか process, the LiPON electrolyte was deposited on the $V_2O_5$ films without breaking vacuum by r.f. magnetron sputtering at room temperature. After deposition of the amorphous LiPON, the Li metal films were grown by a thermal evaporator in a dry room. The charge-discharge cycle measurements as a function of current density and voltage variation revealed that the $Li/LiPON/V_2O_5$ thin film had excellent rechargeable properly when current density was $7{\mu}A/cm^2$. and cut-off voltage was between 3.6 and 2.7V In practical experiment, a stopwatch ran on this $Li/LiPON/V_2O_5$ thin film micro-battery. This result means that thin film micro-battery fabricated by in-siか process is a promising for power source for electronic devices.

A Three-phase Current-fed DC-DC Converter with Active Clamp (연료전지용 3상 전류형 능동클램프 DC-DC 컨버터)

  • Cha, Han-Ju;Choi, Jung-Wan;Yoon, Gi-Gab
    • The Transactions of the Korean Institute of Power Electronics
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    • v.12 no.6
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    • pp.456-464
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    • 2007
  • This paper proposes a novel three-phase current-fed active clamp DC-DC converter for fuel cells. A single common active clamp branch is used to limit transient voltage across the three-phase full bridge and to realize zero-voltage switching(ZVS) in all switches. To apply for the power generation system current-fed type has been combined with the three-phase power conversion system. The proposed approach has the following advantages: an increase (by a factor of three) of input current and output voltage chopping frequencies; lower RMS current through the inverter switches with higher power transfer capability; reduction in size of reactive later components and the power conditioning system; better transformer utilization; increase of the system reliability. Therefore, the proposed three-phase current-fed active clamp DC-DC converter is appropriate for the boost type DC-DC converter for fuel cells and also applicable for the photovoltaic and battery charge system. The paper details the analysis, simulation and hardware implementation of the proposed system. Finally, experimental results with the proposed PWM strategy demonstrate the feasibility of the proposed scheme on a 500W prototype converter.