• Journal of the Korean Society for Industrial and Applied Mathematics
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• 제11권3호
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• pp.7-20
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• 2007

We examined the steady state solution for a strongly exothermic mixtures in some class A geometries subjected to different boundary conditions under Arrhenius, Bimolecular and Sensitised reactions. The solution of the governing nonlinear reaction diffusion equation was obtained using the variational method formulation executed in Mathematica package. The paper elucidates the influence of geometry, boundary conditions and types of reaction on the thermal ignition of the reactive mixture. Apart from validating known results in literature, the solution gave further insight into the influence of material properties and conditions on the occurrence of thermal ignition.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.394-394
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• 2012

We fabricated organic-inorganic superlattice films using molecular layer deposition (MLD) and atomic layer deposition (ALD). The MLD is a gas phase process in the vacuum like to atomic layer deposition (ALD) and also relies on a self-terminating surface reaction of organic precursor which results in the formation of a monolayer in each sequence. In the MLD process, 'Alucone' is very famous organic thin film fabricated using MLD. Alucone layers were grown by repeated sequential surface reactions of trimethylaluminum and ethylene glycol at substrate temperature of $80^{\circ}C$. In addition, we developed UV-assisted $Al_2O_3$ with gas diffusion barrier property better than typical $Al_2O_3$. The UV light was very effective to obtain defect-free, high quality $Al_2O_3$ thin film which is determined by water vapor transmission rate (WVTR). Ellipsometry analysis showed a self-limiting surface reaction process and linear growth of each organic, inorganic film. Composition of the organic films was confirmed by infrared (IR) spectroscopy. Ultra-violet (UV) spectroscopy was employed to measure transparency of the organic-inorganic superlattice films. WVTR is calculated by Ca test. Organic-inorganic superlattice films using UV-assisted $Al_2O_3$ and alucone have possible use in gas diffusion barrier for OLED.

• 대한기계학회논문집B
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• 제21권11호
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• pp.1527-1537
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• 1997

Extinction characteristics and acoustic response of hydrogen-air diffusion flames at various pressures are numerically studied by employing counterflow diffusion flame as a model flamelet in turbulent flames in combustion chambers. The numerical results show that extinction strain rate increases linearly with pressure and then decreases, and increases again at high pressures. Thus, flames are classified into three pressure regimes. Such nonmonotonic behavior is caused by the change in chemical kinetic behavior as pressure rises. The investigation of acoustic-pressure response in each regime, for better understanding of combustion instability, shows different characteristics depending on pressure. At low pressures, pressure-rise causes the increase in flame temperature and chain branching/recombination reaction rates, resulting in increased heat release. Therefore, amplification in pressure oscillation is predicted. Similar phenomena are predicted at high pressures. At moderate pressures, weak amplification is predicted since flame temperature and chain branching reaction rate decreases as pressure rises. This acoustic response can be predicted properly only with detailed chemistry or proper reduced chemistry.

• 대한기계학회논문집B
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• 제22권2호
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• pp.193-204
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• 1998

Numerical analysis was performed with multicomponent transport properties and detailed reaction mechanisms for axisymmetric 2-D CH$_{4}$ jet diffusion flame. Calculations were carried out twice with the $C_{2}$-Thermal Mechanism including $C_{2}$ and thermal NO reactions and the $C_{2}$-Full Mechanism including prompt NO reactions in addition to the above $C_{2}$-Thermal NO mechanism. The results show that the flame structures such as flame temperature, major and minor species concentration are indifferent to respective mechanisms. The production path of Thermal NO is dominant comparing with that of Prompt NO in total NO production of pure CH$_{4}$ jet diffusion flame. This is because thermal NO mechanism mainly contributes to positive formation of NO in the whole flame region, but Prompt NO mechanism contributes to negative formation in the fuel rich region. In addition, 0$_{2}$ penetration near the nozzle outlet affects the flame structures, especially N0$_{2}$ formation characteristics.

• 대한기계학회논문집B
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• 제31권12호
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• pp.1009-1016
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• 2007

Numerical study on preferential diffusion effects in flame structure in $CH_4-H_2$ diffusion flames is conducted with detailed chemistry. Comparison of flame structures with mixture-averaged species diffusion and suppression of the diffusivities of $H_2$ and H was made. Discernible differences in flame structures are displayed with three species diffusion models. The behaviors of maximum flame temperatures with those species diffusion models are not explained by scalar dissipation rate but by the nature of chemical kinetics. It is seen that the modifcation of flame structure is mainly due to the preferential diffusion of H2 and thereby the nature of chemical kinetics. It is also found that the behaviors of major species with the three species diffusion models are addressed to the nature of chemical kinetics, and this is evident by examining importantly contributing reaction steps to the production and destruction of those chemical species.

• 한국연소학회:학술대회논문집
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• 한국연소학회 제26회 KOSCO SYMPOSIUM 논문집
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• pp.129-136
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• 2003

Numerical study with momentum-balanced boundary conditions has been conducted to grasp chemical effects of added $CO_{2}$ and $H_{2}O$ to fuel- and oxidizer-sides on flame structure and NO emission behavior in $CH_{4}$/Air counterflow diffusion flames. The dilution with $H_{2}O$ results in significantly higher flame temperatures and NO emission, but dilution with $CO_{2}$ has much more chemical effects than that with $H_{2}O$. Maximum reaction rate of principal chain branching reaction due to chemical effects decreases with added $CO_{2}$. but increases with added $H_{2}O$. The NO emission behavior is closely related to the production rate of OH, CH and N. The OH radical production rate increases with added $H_{2}O$ but those of CH, N decrease. On the other hand the production rates of OR CH and N decrease with added $CO_{2}$. It is found that NO emission behavior is considerably affected by chemical effects of added $CO_{2}$ and $H_{2}O$.

• 대한화학회지
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• 제41권8호
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• pp.385-391
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• 1997

Co$(dimethyl bipyridine)_3(ClO_4)_2$의 확산계수$(D_0)$와 전극반응속도상수$(K_0)$를 순환전압전류법과 대시간전류법으로 구하였다. 확산계수에 대한 용매, 농도, 주사속도 등의 영향과 반응속도상수에 대한 온도변화의 영향을 조사하였다. 25$^{\circ}C$에서 확산계수는 $5.54{\times}10^{-6 }cm^2/sec$이었고, 반응속도상수는 $2.39{\times}10^{-3 }/s$ 이었으며, 용매의 점도가 커질수록 봉우리전류값과 확산계수는 감소하였다. 반응속도상수에 대한 온도의 영향으로부터, ${\Delta}G^{\neq},\;{\Delta}H^{\neq},\;{\Delta}S$ 등의 열역학적 파라미터를 구하였다. 이 화합물은 $O_2$분자의 환원에서 봉우리전류를 크게 증가시키고, 환원전위를 양(+)전위방향으로 이동시키는 열역학적 전극촉매현상을 보였다.

• 한국항행학회논문지
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• 제22권6호
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• pp.648-653
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• 2018

영상 신호의 특정 파장대역에 대한 분석은 오래된 연구 분야다. 그러나 특정 파장대의 특성을 갖는 신호에 대한 분석이나 샘플의 생성에 관한 연구는 최근에도 활발하게 이루어지고 있다. 특히 블루 노이즈 특성을 갖는 샘플링 방법에 관한 연구들이 다양하게 이루어지고 있으며 본 논문에서는 디지털 하프토닝 영상에 대한 신호를 분석한다. 하프토닝을 신호의 관점에서 해석한 것은 Ulichney에 의해 처음 이루어졌다. 하프토닝에 사용되는 픽셀간의 신호 특성을 블루 노이즈일 경우 보기에 좋은 결과를 낸다는 관점으로 접근하였다. Lau는 출력의존피드백을 오차확산법에 활용하여 그린 노이즈 특성을 보이는 하프토닝 방법을 개발하였다. Jho는 반응확산 모델을 이용하여 하프토닝 영상을 만들어 내는 방법을 개발하였다. 본 연구에서는 반응확산 하프토닝을 신호의 관점에서 분석하여 그린 노이즈를 나타냄을 보이고 기존의 그린 노이즈 하프토닝과 비교하고자 한다.

• East Asian mathematical journal
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• 제32권3호
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• pp.387-397
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• 2016

This paper is concerned with the optimal control problem for some reaction diusion model. That is, we show the existence of the global weak solution for the Field-Noyes model. We also show the existence of the optimal control.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.207-212
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• 2002

Reportedly, the use of mineral admixtures make concrete more durable and tighten against water. But, it is needed to study more about the relationship between the admixtures and the chloride ion diffusion. When concrete is mixed with fly-ash, pozzolanic reaction occur to time. So we should consider the factors that can evaluate inner structure of concrete in order to evaluate the chloride diffusion of the concrete more accurately. Therefore, in this study, we analyzed the correlation between chloride ion diffusion and physical properties such as compressive strength, void ratio, air permeability of the concrete, and tried to use them as fundamental data for analyzing chloride ion diffusion mechanism of the concrete mixed with fly-ash.