• Title/Summary/Keyword: Reaction variables

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The rapid synthesis of MoSi$_2$ for high-temperature furnace heating elements

  • Soh, Deawha;Korobova, Natalya
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.38-41
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    • 2001
  • The combustion characteristics of the disilicides molybdenum system have been studied experimentally. The pertinent reaction parameters that control self-propagating high temperature synthesis reactions have been examined. These include reactant particle size, powder mixing and compaction, reaction stoichiometry, diluents. The inf1uence of experimental variables on integrity, uniformity, structure, and related material properties will be discussed. Formation mechanism of MoSi$_2$ during SHS might be different and depending on experimental conditions.

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Preparation and Optical Properties of $SrGa_2S_4$:Eu Phosphor

  • Do, Yeong Nak;Bae, Jae U;Kim, Yu Hyeok;Yang, Hong Geun
    • Bulletin of the Korean Chemical Society
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    • v.21 no.3
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    • pp.295-299
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    • 2000
  • The photoluminescence and cathodoluminescence of $SrGa_2S_4:EU$ phosphor were optimized with the process and chemical variables (activators, fluxes and reaction temperature) used in solid state reaction. Firing the powder with flux at $800^{\circ}C$ for 2hr gave the highest photoluminescence efficiency under near-UV excitation and the highest cathodoluminescence efficiency of 20.1 lm/W at 2 kV and 33.3 lm/W at 10 kV. The suitability of $SrGa_2S_4:EU$ for application as a phosphor in LCDs and FEDs is discussed.

The Characteristics of Negative lons in Silane Plasma Changing the Process Variables (공정 변수 변화에 따른 실란 플라즈마내 음이온 특성)

  • Kim, Dong-Joo;Kim, Kyo-Seon
    • Journal of Industrial Technology
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    • v.15
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    • pp.15-22
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    • 1995
  • We have studied the generation and behavior of negative ions in silane plasmas. The negative ions were formed by homogeneous reaction in silane plasma and the behavior of negative ions were predicted by solving the model equations. The concentration profiles of negative ions were shown as a function of reactor length and time. The effects of process variables such as reactor pressure, flow rate and electrical field strengths on the behavior of negative ions were analyzed.

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Design Variables of Chemical-Mechanical Polishing Conditioning System to Improve Pad Wear Uniformity (패드 마모 균일성 향상을 위한 CMP 컨디셔닝 시스템 설계 변수 연구)

  • Park, Byeonghun;Park, Boumyoung;Jeon, Unchan;Lee, Hyunseop
    • Tribology and Lubricants
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    • v.38 no.1
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    • pp.1-7
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    • 2022
  • Chemical-mechanical polishing (CMP) process is a semiconductor process that planarizes a wafer surface using mechanical friction between a polishing pad and a substrate surface during a specific chemical reaction. During the CMP process, polishing pad conditioning is applied to prevent the rapid degradation of the polishing quality caused by polishing pad glazing through repeated material removal processes. However, during the conditioning process, uneven wear on the polishing pad is inevitable because the disk on which diamond particles are electrodeposited is used. Therefore, the abrasion of the polishing pad should be considered not only for the variables during the conditioning process but also when designing the CMP conditioning system. In this study, three design variables of the conditioning system were analyzed, and the effect on the pad wear profile during conditioning was investigated. The three design variables considered in this study were the length of the conditioner arm, diameter of the conditioner disk, and distance between centers. The Taguchi method was used for the experimental design. The effect of the three design variables on pad wear and uniformity was assessed, and new variables used in conditioning system design were proposed.

Negative Support Reactions of the Single Span Twin-Steel Box Girder Curved Bridges with Skew Angles (단경간 2련 강박스 거더 곡선교의 사각에 따른 부반력 특성)

  • Park, Chang Min;Lee, Hyung Joon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.4
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    • pp.34-43
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    • 2012
  • The behaviors of the curved bridges which has been constructed in the RAMP or Interchange are very complicate and different than orthogonal bridges according to the variations of radius of curvature, skew angle and spacing of shoes. Occasionally, the camber of girder and negative reactions can be occurred due to bending and torsional moment. In this study, the effects on the negative reaction in the curved bridge were investigated on the basis of design variables such as radius of curvature, skew angle, and spacing of shoes. For this study, the twin-steel box girder curved bridge with single span which is applicable for the RAMP bridges with span length(L) of 50.0m and width of 9.0m was chosen and the structural analysis to calculate the reactions was conducted using 3-dimensional equivalent grillage system. The value of negative reaction in curved bridges depends on the plan structures of bridges, the formations of structural systems, and the boundary conditions of bearing, so, radius of curvature, skew angle, and spacing of shoes among of design variables were chosen as the parameter and the load combination according to the design standard were considered. According to the results of numerical analysis, the negative reaction in curved bridge increased with an decrease of radius of curvature, skew angle, and spacing of shoes, respectively. Also, in case of skew angle of $60^{\circ}$ the negative reaction has been always occurred without regard to ${\theta}/B$, and in case of skew angle of $75^{\circ}$ the negative reaction hasn't been occurred in ${\theta}/B$ below 0.27 with the radius of curvature of 180m and in ${\theta}/B$ below 0.32 with the radius of curvature of 250m, and in case of skew angle of $90^{\circ}$ the negative reaction hasn't been occurred in the radius of curvature over 180m and in ${\theta}/B$ below 0.38 with the radius of curvature of 130m, The results from this study indicated that occurrence of negative reaction was related to design variables such as radius of curvature, skew angle, and spacing of shoes, and the problems with the stability including negative reaction will be expected to be solved as taken into consideration of the proper combinations of design variables in design of curved bridge.

Practical Process Development of AMCA from Recyclable Source MFB (재사용이 가능한 MFB로부터 AMCA의 합성 공정 개발)

  • Kim, Jong Cheon;Ryu, Young;Kim, Seok Chan
    • Applied Chemistry for Engineering
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    • v.27 no.5
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    • pp.508-511
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    • 2016
  • A facile synthesis of 4-(aminomethyl)cyclohexanecarboxylic acid (AMCA) from recyclable methyl 4-formylbenzoate (MFB) was described. In particular, we investigated the best process variables such as catalyst, hydrogen pressure, reaction temperature, and reaction time for AMCA conversion from AMBA through hydrogenation reaction. The best conditions were found to be as follows: the catalyst as [5% Pd/C, 5% Pt/C, 5% Rh/C (1 : 1 : 1)] which is a composite catalyst, the pressure as 30 bar, the reaction time as 8 hours and the reaction temperature at $130^{\circ}C$. Under the condition, a 90% yield (purity 99.9%) for the mass production of AMCA was achieved.

Analysis of Ground Reaction Force by Stance Type during Tennis Forehand Stroke (테니스 포핸드 스트로크 스탠스 유형의 지면반력 분석)

  • Kang, Yong-Teak;Seo, Kook-Eun
    • Korean Journal of Applied Biomechanics
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    • v.19 no.3
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    • pp.449-455
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    • 2009
  • The purpose of this study was to analyze the kinetics variables of GRF by dtance type during forehand stroke. Eight high school tennis players, who have never been injured for last six months, in Busan were chosen for the study. They performed horizontal swing and vertical swing that it was done each five consecutive trial in the condition of square, semi-open and open stance. It was filmed by 6 video camera and used with 3-dimensional motion analyzer system and GRF system. The following kinetic variables were analyzed in relation to left leg and right leg GRF. The conclusion were as follow: 1. In square and semi-open stances, the horizontal ground reaction force was decreased at impact in left leg regardless of swing type, whereas open stance was increased at impact to the tiptoe in both legs. 2. In square and semi-open stances, the vertical ground reaction force was increased at impact in left leg regardless of swing types, whereas open stance was decreased at impact to vertical direction in both legs.

Characteristics of Brazed Joint of Sintered Bronze/steel Using Ag-Cu-Zn Type Filler Materials (Ag-Cu-Zn-Cd 계 용가재를 이용한 Bronze 소결체/강의 브레이징 접합부 특성 평가)

  • 이정훈;이창희
    • Journal of Welding and Joining
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    • v.17 no.3
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    • pp.79-89
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    • 1999
  • The study was carried out to examine in more detail metallurgical and mechanical properties of brazed joints of diamond cutting wheel. In this work, shank(mild steel) and sintered bronze-base tips were brazed with three different filler materials(W-40, BAgl and BAg3S). The machine used in this work was a high frequency induction brazing equipment. The joint thickness, porosities and microstructure of brazed joints with brazing variables(brazing temperature, holding time) were evaluated with OLM, SEM, EDS and XRD. Bending(torque) test was also performed to evaluate strength of brazed joints. Further wetting test was performed in a vacuum furnace in order to evaluate the wettability of filler metals on base metals9shank and tips). The brazing temperature had a strong influence on the joint strength and the optimum brazing temperature range was about $700~850^{\circ}C$ for the bronze/steel combinations. The strength of the brazed joint was found to be influenced by the three factors : degree of reaction region, porosity content, joint thickness. The reaction region was formed in the bronze-base tip adjacent to the joint. The reaction region resulted in a bad influence on the strength due to the formation of Cu5.6Sn, CuZn4, $\beta(CuZn)$ and CdAg, etc. Porosities increased as brazing variables(brazing temperature, holding time) increased, and the brazed joints with porosities of less than about 3-5% had an optimum strength for the bronze-base tip.

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Reaction Characteristics of WGS Catalyst for SEWGS Process in a Pressurized Fluidized Bed Reactor (가압 유동층 반응기에서 SEWGS 공정을 위한 WGS 촉매의 반응특성)

  • Kim, Ha-Na;Lee, Dong-Ho;Lee, Seung-Yong;Hwang, Taek-Sung;Ryu, Ho-Jung
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.4
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    • pp.337-345
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    • 2012
  • To check effects of operating variables on reaction characteristics of WGS catalyst for SEWGS process, water gas shift reaction tests were carried out in a pressurized fluidized bed reactor using commercial WGS catalyst and sand(as a substitute for $CO_2$ absorbent) as bed materials. Simulated syngas(mixed with $N_2$) was used as a reactant gas. Operating temperature was $210^{\circ}C$ and operating pressure was 20 bar. WGS catalyst content, steam/CO ratio, gas velocity, and syngas concentration were considered as experimental variables. CO conversion increased as the catalyst content and steam/CO ratio increased. CO conversion at fluidized bed condition was higher than that of fixed bed condition. However, CO conversion were maintained almost same value within the fluidized bed condition. CO conversion decreased as the syngas concentration increased. The optimum operation condition was confirmed and long time water gas shift reaction test up to 24 hours at the optimum operating conditions was carried out.

Flavor Improvement of a Complex Extract from Poor-quality, Individually Quick-frozen Oysters Crassostrea gigas (IQF 굴(Crassostrea gigas) 복합엑스분의 추출 및 풍미개선)

  • Hwang, Seok-Min;Hwang, Young-Suk;Nam, Hyeon-Gyu;Lee, Jae-Dong;Ryu, Seong-Gwi;Oh, Kwang-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.47 no.6
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    • pp.733-739
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    • 2014
  • To develop an effective use for poor-quality individually quick-frozen (IQF) oysters Crassostrea gigas stored for a long period, the extract conditions, quality characteristics, and optimum reaction flavoring (RF) conditions of a complex extract from these IQF oysters were investigated. The moisture, pH, and volatile basic nitrogen contents of IQF oysters stored for 18 months (18M-IQFO) were 77.9%, 6.32, and 17.9 mg/100 g, respectively. Three different kinds of extract were prepared from 18M-IQFO: a hot-water extract (HE), scrap enzymatic hydrolysate (EH), and complex extract (CE). The respective extracts contained 5.5, 8.6, and 6.6% crude protein and 281.7, 366.0, and 343.0 mg/100 g amino nitrogen, and had 811, 359, and 1,170 mL/kg extraction yields. The CE was superior to the traditional HE in terms of the extraction yield, amino-nitrogen content, and organoleptic qualities, except for the odor. To improve flavor via the Maillard reaction, the reaction system used to produce a desirable flavor comprised CE (Brix $30^{\circ}$), 0.4 M glucose, 0.4 M glycine, and 0.4 M cysteine solution (4:2:1:1, v/v). The reaction time and pH were the independent variables, and the sensory scores for baked potato odor, masking shellfish odor, and boiled meat odor were the dependent variables. The surface response methodology (RSM) analysis of the multiple responses optimization gave a reaction time of 120.6 minutes and pH 7.33 at $120^{\circ}C$. The reaction improved the flavor of CE considerably, as compared to that of the unreacted extract.