• Title/Summary/Keyword: Reaction stability

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The Effect of Machinery House Location on the Stability of High Efficiency Gantry Crane (기계실 위치 변화가 고효율 갠트리 크레인의 안정성에 미치는 영향 분석)

  • Lee S.W.;Han G.J.;Shim J.J.;Han D.S.;Gwon S.G.;Kim T.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.1605-1608
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    • 2005
  • This study was carried out to analyze the effect of machinery house location on the stability of high efficiency gantry crane which can improve the productivity of the container transportation wok by reducing cycle time. The wind load was evaluated according to 'Load Criteria of Building Structures' enacted by the ministry of construction & transportation. The uplift forces of high efficiency gantry crane under this wind load were calculated by analyzing reaction forces at each supporting point. And variation of reaction forces at each supporting point was analyzed according to machinery house location.

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Analysis of Stability on Single-leg Standing by Wearing a Head Mounted Display

  • Woo, Byung Hoon
    • Korean Journal of Applied Biomechanics
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    • v.27 no.2
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    • pp.149-155
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    • 2017
  • Objective: The purpose of this study was to investigate the effects of three visual conditions (eyes opened, eyes closed, and wearing of a head mounted display [HMD]) on single-leg standing through kinematics and kinetic analysis. Method: Twelve college students (age: $24.5{\pm}2.6years$, height: $175.0{\pm}6.4cm$, weight: $69.2{\pm}5.1kg$) participated in this study. The study method adopted three-dimensional analysis with six cameras and ground reaction force measurement with one force plate. The analysis variables were coefficient of variation (CV) of the center of body mass, head movement, ground reaction force, and center of pressure, which were analyzed using one-way analysis of variance with repeated measures according to visual conditions. Results: In most cases, the results of this study showed that the CV was significantly higher in the order of HMD wearing, eyes closed, and eyes opened conditions. Conclusion: Our results indicated that body sway was the largest in the HMD wearing condition, and the risk of falling was high owing to the low stability.

The Effect of Wind Load on the Stability of a Container Crane (풍하중이 컨테이너 크레인의 안정성에 미치는 영향 분석)

  • Lee Seong Wook;Shim Jae Joon;Han Dong Seop;Park Jong Seo;Han Geun Jo;Lee Kwon Soon;Kim Tae Hyung
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.2
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    • pp.148-155
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    • 2005
  • This study was carried out to analyze the effect of direction of wind load and machinery house location on the stability of container crane loading/unloading a container on a vessel. The overturning moment of container crane under wind load at 50m/s velocity was estimated by analyzing reaction forces at each supporting point. And variations of reaction forces at each supporting point of a container crane were analyzed according to direction of wind load and machinery house location. The critical location of machinery house was also investigated to install a tie-down which has an anti-overturning function of container crane at the land side supporting point.

Surface Potential Behavior of Nano $CeO_2$ Particles in Aqueous Media (수계분산매체에서 나노 $CeO_2$ 입자의 계면전위 거동)

  • 이태원;백운규;최성철;이상훈;임형섭;김철진
    • Journal of the Korean Ceramic Society
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    • v.37 no.7
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    • pp.721-725
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    • 2000
  • In this study, the dispersion stability of nano-sized CeO2 particles, synthesized by hydrothermal method in aqueous was evaluated from observing the surface potential behavior of CeO2 particle synthesized by solid state reaction. The isoelectric point(IEP) of nano-sized CeO2 synthesized by hydrothermal synthesis was found to be pH 9 contrary to the isoelectric point of micro-sized CeO2 synthesized by solid state reaction at pH 6.7. IEP was shifted to pH 2.0 as the addition of D-3019 from 0.1 to 1.0 wt%. The surface potential of CeO2 particles synthesized by hydrothermal synthesis was reduced as the addition of B-1001 used as a binder without change of IEP because the absorption of B-1001 polymer on the CeO2 particles shifted the shear plane of CeO2 particles outward away from the surface. This surface potential behavior was well correlated with the dispersion stability of slurry.

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Effect of Cobalt Loading on the Performance and Stability of Oxygen Reduction and Evolution Reactions in Rechargeable Zinc-air Batteries

  • Sheraz Ahmed;Joongpyo Shim;Gyungse Park
    • Journal of the Korean Chemical Society
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    • v.68 no.2
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    • pp.87-92
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    • 2024
  • The commercialization of rechargeable metal-air batteries is extremely desirable but designing stable oxygen reduction reaction (ORR) catalysts with non-noble metal still has faced challenges to replace platinum-based catalysts. The nonnoble metal catalysts for ORR were prepared to improve the catalytic performance and stability by the thermal decomposition of ZIF-8 with optimum cobalt loading. The porous carbon was obtained by the calcination of ZIF-8 and different loading amounts of Co nanoparticles were anchored onto porous carbon forming a Co/PC catalyst. Co/PC composite shows a significant increase in the ORR value of current and stability (500 h) due to the good electronic conductive PCN support and optimum cobalt metal loading. The significantly improved catalytic performance is ascribed to the chemical structure, synergistic effects, porous carbon networks, and rich active sites. This method develops a new pathway for a highly active and advantageous catalyst for electrochemical devices.

An Evaluation of Thermal Stability of Raw Materials in the Vinyl Acetate Polymerization Process (비닐아세테이트 중합공정에서 원료물질의 열적 안정성 평가)

  • Lee, Keun-Won;Han, In-Soo;Lee, Jung-Suk
    • Journal of the Korean Society of Safety
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    • v.25 no.3
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    • pp.61-65
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    • 2010
  • Most of the chemical reactions performed in the chemical industry are exothermic, meaning that thermal energy is released during the reaction. It is also important to understand the thermal hazards such as thermal stabilities and runaway reactions, which are governed by thermodynamics and reaction kinetics of the mixed materials. The paper was described the evaluation of thermal behavior caused by an exothermic batch process in manufacture of the vinyl acetate resin. The aim of the study was to evaluate the thermal stabilities of raw materials with operating conditions such as a reaction inhibitor, heating rate, reaction atmosphere and the mount of methanol charged in the vinyl acetate polymerization process. The experiments were performed in the differential scanning calorimeter(DSC), C 80 calorimeter, and thermal screening unit($TS^u$). It was suggested that we should provide the thermal characteristics for raw materials to present safe precautions with operating conditions in the vinyl acetate polymerization process.

Characteristics of Oxygen-Enhanced Flame in Swirl Burner (선회연소기를 이용한 산소부화연소화염의 연소 특성 연구)

  • Lee, Yun-Won;Ahn, Kook-Young;Kim, Han-Seok;Lee, Chang-Eon
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.149-154
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    • 2001
  • The emission characteristics, flame stability, the composition of the flame zone and temperature profile were studied experimentally. The compositions of oxydant were varied by substituting $N_2$ with $CO_2$ at the constant $O_2$ concentration. Results showed that flame became unstable due to the high heat capacity, low transport rate and strong radiation effect of $CO_2$ in comparison with those of $N_2$. The reaction zone was cooled, broadened, as the conversion ratio of $CO_2$ to $N_2$ was increased. Temperature has a large effect on the NOx emission. The concentration of NOx in flue gas decreased due to the decreased temperature of reaction zone. It was also shown that the reaction was delayed by the cooling effect. As the conversion ratio of $CO_2$ to $N_2$ was increased, the emission of CO and the higher temperature zone increased due to the decrease of reaction rate by the cooling effect.

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Minimization of Tilting Moment of Co-Rotating Scroll Compressor by Design of Back Pressure Chamber (배압실의 설계를 통한 상호회전 스크롤 압축기의 전복 모멘트 최소화)

  • Gu, In-Hoe;Park, Jin-Mu
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.5 s.176
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    • pp.1305-1313
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    • 2000
  • In a co-rotating scroll compressor, both scrolls rotate on their fixed axes contrary to the conventional orbiting type scroll machine. This implies fixed locations and directions of the gas pressure force and sealing force. Because the tilting moment is mainly caused by interplay between the resultant force of above forces and bearing reaction force, the variation during one cycle is relatively small. Under real operation, this moment is balanced by the restoring moment created by the reaction between the baseplate and thrust bearing or between the scroll tip and baseplate. If these reactions become too large, greater torque is required due to increased friction in addition to the wear of mating parts. Consequently, appropriate study and minimization of tilting moment is important in the design of scroll machines. In this study, taking into account of the small variation of tilting moment during one cycle, we minimize the moment and thrust bearing reaction force by a properly designed back pressure chamber. As a result, for both the driving and driven scrolls, the tilting moment and the reaction force of thrust bearing can be minimized. And the stability is improved for all cases.

Synthesis of Blue Emitting Materials for Organic Light Emitting Device (유기발광디바이스용 청색발광재료의 합성)

  • Chung, Pyung Jin;Cho, Min Ju
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.755-759
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    • 2005
  • This study was based on organic electroluminescence display. Especially, DPAVBi, AVBi and DPVBi for the emitting materials were synthesized by Wittig, Wittig-Horner reaction. This reaction was conducted between phosphorous ylide and 4-(diphenylamino)benzaldehyde, 9-anthraldehyde and benzophenone. The structural property of reaction products were analyzed by FT-IR, $^1H-NMR$ spectroscopy and thermal stability, reactivity and PL property were analyzed by melting point, yield and emission spectrum, respectvely. The photoluminescence spectra of a pure DPAVBi, AVBi and DPVBi were observed at approximately 445nm, 484nm and 450nm, respectively. In this study, it was known that DPAVBi, AVBi, DPVBi had a different reaction properties according to stability of ${\alpha}$-position carbonyl group of the aldehyde, ketone.