• Proceedings of the KIEE Conference
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• 1997.11a
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• pp.314-316
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• 1997

We have studied the epitaxial growth and electrical properties of $Si_{0.8}Ge_{0.2}$, films on Si substrates at $550^{\circ}C$ by LPCVD. In a low $PH_3$, partial pressure region such as below 1.25 mPa, the phosphorus doping concentration increased proportionally with increasing $PH_3$ partial pressure while the deposition rate and the Ge fraction x were constant. In a higher $PH_3$ partial pressure region, the phosphorus doping concentration and the deposition rate decreased, while the Ge fraction slightly increased. The dependence of P incorporation rate on the $PH_3$ partial pressure was similar to the phosphorus doping concentration. According to test results, it suggests that high surface coverage of phosphorus atoms suppress both the $SiH_4$ adsorption/reaction and the $GeH_4$ adsorption/reaction on the surfaces, and the effect is more stronger on $SiH_4$ than on $GeH_4$. In a higher $PH_3$ partial pressure region, the deposition is largely controlled by surface coverage effect of phosphorus atoms.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.8
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• pp.1087-1096
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• 2001

The dynamic structures of unsteady CH$_4$/Air jet diffusion flame with a flame-vortex interaction were numerically investigated. A timed-dependent, axisymmetric computational model and a low mach number approximation were employed in the present calculation. A two-step global reaction mechanism which considers 6 species, was used to calculate the reaction rates. The predicted results including the gravitational effect show that the large outer vortices and the small inner vortices can be well simulated without any additional disturbances near nozzle tip. It was found that the temperature and species concentrations have deviated values even for the same mixture fraction in the flame-vortex interaction region. It was also shown that the flame surface is not deformed by the inner vortex in upstream region, while in downstream region, the flame surface is compressed or stretched by the outer vortex roll-up. The present unsteady jet flame configuration accompanying a flame-vortex interaction is expected to give good implications for the unsteady structures of turbulent flames.

• Bulletin of the Korean Chemical Society
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• v.17 no.3
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• pp.234-238
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• 1996

Second-order rate constants have been measured spectrophotometrically for the reaction of p-nitrophenyl acetate (PNPA) with morpholine, piperazine and piperidine in MeCN-H2O mixtures of varying compositions. The rate of the present aminolysis decreases upon additions of MeCN into H2O up to near 30-40 mole % MeCN and remains nearly constant upon further additions of MeCN. The reaction of PNPA with anionic nucleophiles, such as HO-, p-chlorophenoxide and butane-2,3-dione monoximate, has also exhibited two distinguishable reactivity zones. However, the reactivity trend for the anionic nucleophiles is quite different from the one obtained for the amine system, e.g. an initial rate decrease in the H2O-rich region followed by an increasing rate trend upon further additions of MeCN in the MeCN-rich region. The rate behaviors shown by the amine system in the MeCN-rich and by the anionic system in the H2O-rich region are unexpected based on the Hughes-Ingold rules. The present unusual rate trends have been attributed to changes in the solvent structure and pKa of the nucleophiles upon the addition of MeCN into H2O. The effect of solvent appears to be more significant for the TS than the GS, and the TS structure is considered to become tighter in the higher MeCN concentration.

• Journal of the Korean Society of Propulsion Engineers
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• v.3 no.2
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• pp.18-24
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• 1999

Liquid ramjet combustor is closely connected with complex phenomena due to a series of processes such as intake air, spray, mixing, and combustion. The present numerical experiments were peformed to investigate these flow characteristics for two and three dimensional liquid ramjet combustor. Grid system was made with three domains: intake region where air is supplied and fuel is injected, combustor and nozzle region, and exit atmosphere region. The numerical results showed that two and three dimensional flow patterns in recirculation region of combustor were significantly different each other and spray model was necessary to predict correctly the chemical reaction flow characteristics. Numerically examined for two different location of fuel injector, one is located on the bottom position of curved intake and the other is located on the top position. We found that bottom position of fuel injector is better than top position because fuel influx to the recirculation region which is need to sustain chemical reaction is more than the latter.

• Bulletin of the Korean Chemical Society
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• v.32 no.5
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• pp.1527-1533
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• 2011

The reaction of gas-phase atomic hydrogen with oxygen atoms chemisorbed on a silicon surface is studied by use of the classical trajectory approach. We have calculated the probability of the OH formation and energy deposit of the reaction exothermicity in the newly formed OH in the gas-surface reaction H(g) + O(ad)/Si${\rightarrow}$ OH(g) + Si. All reactive events occur in a single impact collision on a subpicosecond scale, following the Eley-Rideal mechanism. These events occur in a localized region around the adatom site on the surface. The reaction probability is dependent upon the gas temperature and shows the maximum near 1000 K, but it is essentially independent of the surface temperature. The reaction probability is also independent upon the initial excitation of the O-Si vibration. The reaction energy available for the product state is carried away by the desorbing OH in its translational and vibrational motions. When the initial excitation of the O-Si vibration increases, translational and vibrational energies of OH rise accordingly, while the energy shared by rotational motion varies only slightly. Flow of energy between the reaction zone and the solid has been incorporated in trajectory calculations, but the amount of energy propagated into the solid is only a few percent of the available energy released in the OH formation.

• Korean Journal of Human Ecology
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• v.23 no.5
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• pp.773-787
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• 2014

The purposes of this study were to examine effects which work events and affective reaction were experienced by employees on job satisfaction and service quality in local healthy family support center for family health enhancement. For the purpose, survey were conducted with employees working in 56 local healthy family support centers in Seoul and Gyeonggi region, and final data were resulted from analysis of 319 examines of those employees. The results of this study were as follows. First, work events had a significant effect on the affective reaction. Second, affective reaction had a significant effect on the job satisfaction. Third, job satisfaction had a significant effect on the service quality. Fourth, affective reaction worked as mediators between the work events and job satisfaction, affective reaction and job satisfaction worked as double mediators between work events and service quality. Based on those findings, we can propose practical and political implications towards improving service quality considering the work experience of personnel in the healthy family support center.

• Journal of the Korean Society of Combustion
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• v.6 no.2
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• pp.36-42
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• 2001

Usually, we use the flame thickness and turbulence scale to classify the flame structure on a phase diagram of turbulent combustion. The flame structure in turbulence is still in debate, and many studies have been done. Since the flame motion is rapid and its reaction zone thickness is very thin, it is difficult to estimate the flame thickness. Here, we propose a new approach to determine the reaction zone thickness based on ion current signals obtained by an electrostatic probe, which has enough time and space resolution to detect flame fluctuation. Since the signal depends on the flow condition and flame curvature, it may be difficult to analyze directly these signals and examine the flame characteristics. However, ion concentration is high only in the region where hydrocarbon-oxygen reactions occur, and we can specify the reaction zone. Based on the reaction zone existing, we estimate the reaction zone thickness. We obtain the thickness of flames both in the cyclone-jet combustor and on a Bunsen burner, compared with theoretically predicted value, the Zeldovich thickness. Results show that the experimentally obtained thickness is almost the same as the Zeldovich thickness. It is concluded that this approach can be used to obtain the local flame structure for modeling turbulent combustion.

• Korean Journal of Applied Biomechanics
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• v.26 no.2
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• pp.197-204
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• 2016

Objective: The purpose of this study was to analyze the kinematic factors of motion during air pistol shooting. Method: This study aimed to investigate changes in forces during movement and determine the factors that affect changes in force during the first, middle, and last periods of shooting an air pistol. Two ground reaction force systems (force platform), SCATT (a shooting training system), and EMG (electromyogram) to measure the action potentials in the muscles of the upper body were used in this study. Four university air pistol players (age: 19.75 years, height: 175.50 cm, body mass: $69.55{\pm}11.50kg$, career length: $6.25{\pm}6years$) who are training to progress to a higher rank were enrolled. Results: In terms of the actual shooting results, the mean score in the middle section was $42.48{\pm}1.74$ points, higher than those in the first and the last periods when using SCATT. The gunpoint moved 13.48 mm more vertically than horizontally in the target trajectory. With respect to action potentials of muscles measured using EMG, the highest action potentials during the aiming-shooting segments, in order higher to lower, were seen in the trapezius (intermediate region), trapezius (superior region), deltoid (lateral), and triceps brachii (long head). The action potentials of biceps brachii and brachioradialis turned out to be high during grasping motion, which is a preparatory stage. During the final segment, muscle fatigue appeared in the deltoid (lateral), biceps brachii (long head), brachioradialis, and trapezius (intermediate region). In terms of the ground reaction force, during the first period of shooting, there was a major change in the overall direction (left-right $F_x$, forward-backward $F_y$, vertical $F_z$) of the center of the mass. Conclusion: The development and application of a training program focusing on muscle groups with higher muscle fatigue is required for players to progress to a higher rank. Furthermore, players can improve their records in the first period if they take part in a game after warming up sufficiently before shooting in order to heighten muscle action potentials, and are expected to maintain a consistent shooting motion continuously by restoring psychological stability.

• BMB Reports
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• v.34 no.1
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• pp.15-20
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• 2001

One of the innate immune reactions in invertebrates is the pro-phenoloxidase (pro-PO) activation system that is involved in the generation of superoxide, melanin synthesis, and the subsequent sequestration of foreign matter entering the hemocoel of the invertebrates. However, the molecular mechanism of this biological reaction is still obscure. To expand our understanding of the biological roles of the pro-PO activation system in invertebrates, we performed a yeast two-hybrid screening by using three regions of pro-PO as bait and a yeast two-hybrid cDNA library from Tenebrio molitor larvae as prey We isolated a novel partial cDNA clone that encodes a glycine-rich protein that interacted with the active phenoloxidase (termed phenoloxidase interacting protein, POIP). POIP consists of two domains: One is an N-terminal unique domain and the other is a C-terminal glycine-rich domain. The C-terminal glycine-rich domain showed sequential homology with those of insect antifungal proteins. Also, the yeast two-hybrid screen in a reverse orientation (using POIP as bait) yielded PO, suggesting that the PO-POIP interaction is specific. By using a 315 bP PCR fragment of the N-terminal unique region of POIP, we cloned the full-length cDNA of POIP from the Tenebruo cDNA library constructed by using E. coli injected larvae. The interaction analysis between PO, and a truncated fragment lacking the N-terminal unique region of POIP, indicated that the N-terminal unique region is necessary for interaction between PO and POIP. The expression level of the POIP mRNA is increased by bacterial injection into T. molitor larvae. This suggests that POIP might be engaged in the humoral defense reaction.

• Journal of Korean Society of Water and Wastewater
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• v.33 no.2
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• pp.95-101
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• 2019

High voltage impulse(HVI) has been gained attention as an alternate technique controlling $CaCO_3$ scale formation. Investigation of key operational parameters for HVI is important, however, those had not been reported yet. In this study, the effect of temperature and applied voltage of HVI on $Ca^{2+}$ concentration was studied. As the applied voltage from 0 to 15kV and the temperature increased from 20 to $60^{\circ}C$, the $Ca^{2+}$ concentration decreased, indicating that the aqueous $Ca^{2+}$ precipitated to $CaCO_3$. The $Ca^{2+}$ concentration decreased up to 81% under the condition of 15kV and $60^{\circ}C$. Rate constant for the precipitation reaction, k was determined under different temper1ature and voltage. The reaction rate constant under the 15kV and $60^{\circ}C$ condition was evaluated to $66{\times}10^{-3}L/(mmol{\cdot}hr)$, which was 5 times greater than the k of the reaction without HVI at same temperature. The increases in k by HVI at higher temperature region(40 to $60^{\circ}C$) was much greater than at lower temperature region(20 to $40^{\circ}C$), which implies temperature is more important parameter than voltage for reducing $Ca^{2+}$ concentration at high temperature region. These results show that the HVI induction accelerates the precipitation to $CaCO_3$, particularly much faster at higher temperature.