• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 춘계학술대회
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• pp.166-169
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• 2006

We fabricated hexagonal copper sulfide $Cu_2S$ nanowires to obtain a larger contact area of $Cu_2S/CdS$ solar cell. Copper sulfide nanowires were grown on Cu foil at room temperature by gas-sol id reaction. The size, density and shape of nanowires seemed to be affected by the change or reaction time temperature, crystallographic orientation of Cu foil, and molar ratio of the mixed gas. We controled the length and the diameter of the nanowires and we obtained suitable nanowire arrays which has fitting size for uniform deposition with n-type CdS. CdS layer was deposited on the nanowire array by electrodeposition and it seemed to be uniform. The $Cu_2S/CdS$ nanowires/CdS junction showed diode characteristics, A large contact area is expected with the $Cu_2S/CdS$ nanowire structure as compared with the $Cu_2S/CdS$ thin film.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2000년도 제21회 KOSCO SYMPOSIUM 논문집
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• pp.212-216
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• 2000

Combustion phenomenon in scale-downed combustor is investigated. As the combustor volume decreases surface to volume ratio increases. for increased surface to volume ratio means increased heat loss and this increased heat loss affects reaction in combustion chamber. Plastic mini combustor is made. Stoichiometricaly premixed Hydrogen I air gas is used as fuel. Initial chamber pressure and chamber size are varied and the effects are evaluated. Peak pressure decreases with the decrease in chamber height. As initial chamber pressure decreases peak pressure decreases. And this change is more important than scale down effect till the chamber height of 1mm. With this result and further information following the experiments design parameter for micro engine can be established.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집B
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• pp.698-703
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• 2000

The characteristics of NOx emission in reburning process have been experimentally studied. The design point of burner is creative of three distinct reaction zones; a primary flame zone that NOx producted, reburn zone to reduce the primary zone NOx and burnout zone. Liquefied Petroleum Gas(LPG) was used as main and reburn fuels. Process parameters investigated included main/reburn fuel ratio, primary/secondary air ratio, reborn fuel injector position and different designed quarl. The NOx emission characteristic of aerodynamic designed burner relied on reborn fuel ratio and was slightly affected by a reburn fuel injector position and quarl shape.

• 동력기계공학회지
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• 제4권1호
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• pp.39-44
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• 2000

The purpose of this study is to investigate the flame structure and combustion characteristics in the model gas turbine combustor changing equivalence ratio. For this purpose, temperature and ion current were measured and these data were analyzed by the PDF and power spectra technique. We found that the flame length is longer while increasing the equivalence ratio in experimental condition, and especially ${\psi}=0.19$, combustion reaction was active by the stable swirl flow. and these flames were governed by the random three dimensional eddy.

• Journal of Korean Society for Atmospheric Environment
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• 제15권E호
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• pp.17-28
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• 1999

Gas-liquid contact tests above a perforated-plate were conducted with air and water at flooding gas-flow conditions in order to study two-phase flow characteristics in a limestone-gypsum SO2 absorber. Gas layers were in the form of air pockets and confined to the limited areas around each duct pipe, while the remaining tary area were in the wet condition. The liquid above the tray was always in the flooded and even fluidized conditions at gas flows over the range studied, although vigorous bubbly or churn-turbulent two-phase regime was only observed in the immediate vicinity of the gas hole exit at low gas loads. The froth zone was extremely active to provide intimate contact between gas and liquid so that the necessary mass transfer operation can take place, which is the primary purpose of high-performance SO2 absorbers. Howefer, the absorber $\Delta$P was 250mmH2O for the initial water level at 150mm, which is an important issue to be resolved for economical operation of the SO2 absorber. It was seen in the liquid level-and gas flow-transient tests that changes in the absorber liquid inventory were much more pronounced for intimate gas-liquid contact than changes in the gas flow. Based on the 4- and 8-duct pipe test results, grouping the duct pipes near the center of the test tray seemed to promote better recirulation of liquid from gas-liquid contact zone back to the reaction tank so that the absorbed SO2 can be neutralized.

• 한국입자에어로졸학회지
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• 제15권1호
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• pp.1-13
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• 2019

Current desulfurization and denitrification technologies have reached a considerable level in terms of reduction efficiency. However, when compared with the simultaneous reduction technology, the individual reduction technologies have issues such as economic disadvantages due to the difficulty to scale-up apparatus, secondary pollution from wastewater/waste during the treatment process, requirement of large facilities for post-treatment, and increased installation costs. Therefore, it is necessary to enable practical application of simultaneous SOx and NOx treatment technologies to remove two or more contaminants in one process. The present study analyzes a technology capable of maintaining simultaneous treatment of SOx and NOx even at low temperatures due to the electrochemically generated strong oxidation of the wet-pulse complex system. This system also reduces unreacted residual gas and secondary products through the wet scrubbing process. It addresses common problems of the existing fuel gas treatment methods such as SDR, SCR, and activated carbon adsorption (i.e., low treatment efficiency, expensive maintenance cost, large installation area, and energy loss). Experiments were performed with varying variables such as pulse voltage, reaction temperature, chemicals and additives ratios, liquid/gas ratio, structure of the aeration cleaning nozzle, and gas inlet concentration. The performance of individual and complex processes using the wet-pulse discharge reaction were analyzed and compared.

• 한국환경과학회지
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• 제27권8호
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• pp.621-629
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• 2018

Many chemically active species such as ${\cdot}H$, ${\cdot}OH$, $O_3$, $H_2O_2$, hydrated $e^-$, as well as ultraviolet rays, are produced by Dielectric Barrier Discharge (DBD) plasma in water and are widely use to remove non-biodegradable materials and deactivate microorganisms. As the plasma gas containing chemically active species that is generated from the plasma reaction has a short lifetime and low solubility in water, increasing the dissolution rate of this gas is an important challenge. To this end, the plasma gas and water within reactor were mixed using the air-automizing nozzle, and then, water-gas mixture was injected into water. The dissolving effect of plasma gas was indirectly confirmed by measuring the RNO (N-Dimethyl-4-nitrosoaniline, indicator of the formation of OH radical) solution. The plasma system consisted of an oxygen generator, a high-voltage power supply, a plasma generator and a liquid-gas mixing reactor. Experiments were conducted to examine the effects of location of air-automizing nozzle, flow rate of plasma gas, water circulation rate, and high-voltage on RNO degradation. The experimental results showed that the RNO removal efficiency of the air-automizing nozzle is 29.8% higher than the conventional diffuser. The nozzle position from water surface was not considered to be a major factor in the design and operation of the plasma reactor. The plasma gas flow rate and water circulation rate with the highest RNO removal rate were 3.5 L/min and 1.5 L/min, respectively. The ratio of the plasma gas flow rate to the water circulation rate for obtaining an RNO removal rate of over 95% was 1.67 ~ 4.00.

• 한국수소및신에너지학회논문집
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• 제22권2호
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• pp.191-198
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• 2011

According to the propagation of fuel cell system, the importance of that system efficiency is being magnified. Thus, the efficiency improvement of reformer which is the important factor of fuel cell system will be required. This study has been experimentally performed to evaluated the performance of plate type STR reactor. At first, we changed fuel flow rate (2, 3 and 4 l/min) in burner, and then we measured a proportion of hydrogen in produced gas through the STR reactor by G.C for evaluating the performance of plate type STR reactor in various fuel supply conditions. And we changed S/C ratio (2 and 4) and measured a proportion of hydrogen in produced gas through the STR reactor. As a results, condition at fuel flow rate 2 and 3 l/min could not be supplied amount of heat for STR sufficiently. Condition at fuel flow rate 4 l/min could supplied a heat excessively. And condition at S/C ratio 2, reaction occurred insufficiency. But condition at S/C ratio 4 was excess. From above, we found the optimum conditions that were fuel rate 3.5 l/min and S/C ratio 3.

• 한국수소및신에너지학회논문집
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• 제23권1호
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• pp.93-99
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• 2012

The investigation of clean and environment-friendly coal utilization technology is actively progressed due to high oil price and serious climate change caused by greenhouse gas emissions. In this study, the plasma gasification was performed using a 6kW microwave plasma unit under various reaction conditions: the particle sizes of coal ($45{\mu}m-150{\mu}m$), $O_2$/fuel ratio (0 - 1.3), and steam/fuel ratio (0 - 1.5). The $H_2$ composition decreases with decreasing coal particle size. With increasing $O_2$/fuel ratio, the $H_2$ composition in the syngas decreased while the $CO_2$ composition increased. As the steam/fuel ratio increased from 0 to 1.5, the $H_2$ composition in the syngas increased while the $CO_2$ composition decreased. From the results, it was proven that the variation of syngas composition greatly affected by $O_2$/fuel ratio than steam/fuel ratio. The $H_2$ composition in the syngas, carbon conversion, and cold gas efficiency increased with increasing plasma power.

• 한국응용과학기술학회지
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• 제21권1호
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• pp.45-50
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• 2004

The effects of reaction temperature and flow rate of reactants on the methane conversion, product selectivity, product ratio, and carbon deposition were investigated with 13wt% Ni/MgO catalyst. Reaction temperatures were changed from 600 to $850^{\circ}C$, and reactants flow rates were changed from 100 to 200 mL/mim. There were no significant changes in the methane conversion observed in the range of temperatures used. It is possibly stemmed from the nearly total exhaustion of oxygen introduced. The selectiveties of hydrogen and carbon monoxide did not largely depend on the reaction temperature. The selectivities of hydrogen and carbon monoxide were 96 and 90%, respectively. Carbon deposition observed was the smallest at $750^{\circ}C$ and the largest at $850^{\circ}C$. It is found that the proper reaction temperature is $750^{\circ}C$. The best reactant flow rate was 150 ml/min.