• Title/Summary/Keyword: Reaction characteristic

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The gas sensing characteristic of the porous tungsten oxide thin films based on anodic reaction (양극반응으로 제조된 다공질 WO3 박막의 가스센서 특성)

  • Lee, Hong-Jin;Song, Kap-Duk;Lee, Duk-Dong
    • Journal of Sensor Science and Technology
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    • v.17 no.1
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    • pp.9-14
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    • 2008
  • In this paper, the gas responses of tungsten oxide films prepared by anodic reaction was discussed. Sensing electrodes and heating electrodes were patterned by photolithography method on quartz substrate. Porous tungsten oxide was fabricated in electrolyte solutions of 5 % HF (HF :$C_2H_6OH:H_2O$=3 : 2 : 20) by anodic reaction. The anodic reaction with metal (platinum wire) as a cathode and the sensing device as an anode was conducted under the various reaction times (1-10 min) at 10 mA/$cm^2$ The surface structure and morphology of the fabricated sensor have been analysed by X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM). All the peaks of XRD results were well indexed to the pure phase pattern. The average diameter of the porous tungsten oxide surface were ranged about 100 nm. The fabricaed sensor showed good sensitivity to 200 ppm toluene at operating temperature of $250^{\circ}C$.

A Study on the Reaction Force Characteristics of the Gas Spring for the Automotive (자동차용 가스 스프링의 반력 특성에 관한 연구)

  • Lee, Choon Tae
    • Journal of Drive and Control
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    • v.12 no.4
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    • pp.35-40
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    • 2015
  • A gas spring provides support force for lifting, positioning, lowering, and counterbalancing weights. It offers a wide range of reaction force with a flat force characteristic, simple mounting, compact size, speed controlled damping, and cushioned end motion. The most common usage is as a support on a horizontally hinged automotive tail gate. However, its versatility and ease of use has been applied in many other industrial applications ranging from office equipment to off-road vehicles. The cylinder of a gas spring is filled with compressed nitrogen gas, which is applied with equal pressure on both sides of the piston. The surface area of the rod side of the piston is smaller than the opposite side, producing a pushing force. The magnitude of the reaction force is determined by the cross-sectional area of the piston rod and the internal pressure inside the cylinder. The reaction force is influenced by many design parameters such as initial chamber volume, diameter ratio, etc. In this paper, we investigated the reaction force characteristics and carried out parameter sensitivity analysis for the design parameters of a gas spring.

Characterization of Graphene Sheets Formed by the Reaction of Carbon Monoxide with Aluminum Sulfide

  • Yoon, Il-Sun;Kim, Chang-Duk;Min, Bong-Ki;Kim, Young-Ki;Kim, Bong-Soo;Jung, Woo-Sik
    • Bulletin of the Korean Chemical Society
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    • v.30 no.12
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    • pp.3045-3048
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    • 2009
  • Graphene sheets formed by the reaction of carbon monoxide (CO) with aluminum sulfide ($Al_2S_3$) at reaction temperatures ${\leq}$ 800 $^{\circ}$ were characterized by X-ray diffraction (XRD), Raman spectroscopy, and high-resolution transmission electron microscopy (HRTEM). The graphene sheets, formed as CO was reduced to gaseous carbon by the reaction with $Al_2S_3$, in the temperature range 800 - 1100 $^{circ}C$, did not exhibit their characteristic XRD peaks because of the small number of graphene layers and/or low crystallinity of graphene sheets. Raman spectra of graphene sheets showed that the intensity ratio of the D band to the G band decreased and the 2D band was shifted to higher frequencies with increasing reaction temperature, indicating that the number of graphene layers increased with increasing reaction temperature.

An Experimental Study on the Characteristics of Electrochemical Reactions of RDF/RPF in the Direct Carbon Fuel Cell (직접탄소 연료전지에서 RDF 및 RPF의 전기화학반응 특성에 관한 실험적 연구)

  • Ahn, Seong Yool;Rhie, Young Hoon;Eom, Seong Yong;Sung, Yeon Mo;Moon, Cheor Eon;Kang, Ki Joong;Choi, Gyung Min;Kim, Duck Jool
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.513-520
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    • 2012
  • The electrochemical reaction of refuse derived fuel (RDF) and refuse plastic/paper fuel (RPF) was investigated in the direct carbon fuel cell (DCFC) system. The open circuit voltage (OCV) of RPF was higher than RDF and other coals because of its thermal reactive characteristic under carbon dioxide. The thermal reactivity of fuels was investigated by thermogravimetric analysis method. and the reaction rate of RPF was higher than other fuels. The behavior of all sample's potential was analogous in the beginning region of electrochemical reactions due to similar functional groups on the surface of fuels analyzed by X-ray Photoelectron Spectroscopy experiments. The potential level of RDF and RPF decreased rapidly comparing to coals in the next of the electrochemical reaction because the surface area and pore volume investigated by nitrogen gas adsorption tests were smaller than coals. This characteristic signifies the contact surface between electrolyte and fuel is restricted. The potential of fuels was maintained to the high current density region over 40 $mA/cm^2$ by total carbon component. The maximum power density of RDF and RPF reached up to 45~70% comparing to coal. The obvious improvement of maximum power density by increasing operating temperature was observed in both refuse fuels.

Effect on the Heat of Reaction to Temperature and Absorption Capacity in the Reaction of Cyclic Amines with Carbon Dioxide (고리형 아민과 이산화탄소의 반응에서 온도와 흡수능이 반응열에 미치는 영향)

  • CHOI, JEONG HO;JANG, JONG TACK;YUN, SOUNG HEE;JO, WON HEE;JUNG, JIN YOUNG;YOON, YEO IL
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.5
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    • pp.530-537
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    • 2018
  • The effect of temperature and absorption capacity on heat of reaction, which is one of the characteristic studies of $CO_2$ absorption, were investigated in a differential reaction calorimeter (DRC) by using piperazine (PZ) and 2-methylpiperazine (2-MPZ). For all absorbents, $CO_2$ loading capacity decreased with increasing the temperature, while the heat of reaction increased, it figured out that these had a linear correlation between $CO_2$ loading capacity and/or heat of reaction and the temperature. The heat of reaction of all absorbents increased with increasing $CO_2$ loading capacity, especially 2-MPZ rapidly increased at $70^{\circ}C$. The reason for increase in the heat of reaction was occurred the regeneration of $CO_2$, which is a reverse-reaction, simultaneously with the absorption.

Soil Stress Analysis Using Discrete Element Method for Plate-Sinkage Tests (DEM 모델을 이용한 평판재하시험의 토양 수직응력 해석)

  • Jang, Gichan;Lee, Soojin;Lee, Kyu-Jin
    • Korean Journal of Computational Design and Engineering
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    • v.20 no.3
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    • pp.230-237
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    • 2015
  • Soil deformation on the off-load ground is significantly affected by soil conditions, such as soil type, water content, and etc. Thus, the soil characteristics should be estimated for predicting vehicle movements on the off-load conditions. The plate-sinkage test, a widely-used experimental test for predicting the wheel-soil interaction, provides the soil characteristic parameters from the relationship between soil stress and plate sinkage. In this study, soil stress under the plate-sinkage situation is calculated by the DEM (Discrete Element Method) model. We developed a virtual soil bin with DEM to obtain the vertical reaction forces under the plate pressing the soil surface. Also parametric studies to investigate effects of DEM model parameters, such as, particle density, Young's modulus, dynamic friction, rolling friction, and adhesion, on the characteristic soil parameters were performed.

Characteristic Analysis of Double sided Permanent Magnet Linear Generator by using Analytical Method (해석적 방법을 이용한 양측식 선형 영구자석 발전기의 특성해석)

  • Kang, Han-Bit;Choi, Jang-Young;Kim, Kyong-Hwan;Hong, Keyyong
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.63 no.5
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    • pp.652-659
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    • 2014
  • This paper deals with characteristic analysis of double sided permanent magnet linear generator using analytical method. We derived magnetic field solutions produced by permanent magnet and armature reaction based on the 2D polar coordinate and magnetic vector potential. based on the derived magnetic field solutions, Induced voltage is obtained when arbitrary sinusoidal input condition. In addition, electrical parameters such as back-EMF constant, resistance, and inductance are obtained. Finally, generating performance characteristic at the rated load and various load is examined by using equivalent circuit.

Evaluation of a Possibility of Estimation of Reaction Force of Surgical Robot Instrument using Sliding Perturbation Observer (슬라이딩 섭동 관측기를 이용한 수술용 로봇 인스트루먼트의 반력 추정 가능성 평가)

  • Yoon, Sung-Min;Lee, Min-Cheol;Kim, Chi-Yen;Kang, Byeong-Ho
    • The Journal of Korea Robotics Society
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    • v.7 no.1
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    • pp.20-28
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    • 2012
  • In spite of the difficulties and uncertain characteristic of cable driven method, surgical robot instrument has adopted it as driving mechanism for various reasons. To overcome the problem of cable system, previous research applied SMCSPO (sliding mode control with sliding perturbation observer) algorithm as robust controller to control the instrument and found that the value of SPO (sliding perturbation observer) followed force disturbance, reaction force loaded on the tip very similarly. Thus, this paper confirms that the perturbation observer is sufficient estimator which finds out the mount of loaded force on the surgical robot instrument. To prove the proposition, simulation using the similar model with an actual instrument and experimental evaluation are performed. The results show that it is possible to substitute SPO for sensors to measure the reaction force. This estimated reaction force will be used to realize haptic function by sending the reaction force to a master device for a surgeon. The results will contribute to create surgical benefit such as shortening the practice time of a surgeon and giving haptic information to surgeon by using it as haptic signal to protect an organ by making force boundary.

Interfacial Stability Between Anode and Electrolyte of LSGM-Based SOFCs (LSGM계 고체산화물 연료전지의 전해질-음극 사이의 계면안정성)

  • Kim, Kwang-Nyeon;Moon, Jooho;Son, Ji-Won;Kim, Joosun;Lee, Hae-Weon;Lee, Jong-Ho;Kim, Byung-Kook
    • Journal of the Korean Ceramic Society
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    • v.42 no.7 s.278
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    • pp.509-515
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    • 2005
  • Interfacial reactions at LSGM electrolyte and NiO-GDC anode interfaces were thoroughly investigated with Environmental Scanning Electron Microscopy (ESEM-PHlLIPS XL-30) and Energy Dispersive X-ray (EDX-Link XL30). According to the analysis, serious reaction zone was observed at LSGM/NiO-GDC interface. It was found that the reaction layer was originated from the chemical reaction between NiO and LSGM. The reaction products were identified as La deficient form of LSGM based perovskite and Ni-La-O compounds such as LaSrGa$_{3}$O$_{7}$ and LaNiO$_{3}$ from the X-Ray Diffraction (XRD, Philips) analysis. According to the electrical characterization, interfacial layer was very electrically resistive which would be the cause of high internal resistance and low power generating characteristic of the unit cell.

A Study on the Reaction-Stoichiometry of Autotrophic Denitrification based on Growth Characteristic of Microorganism (미생물 성장 특성에 기초한 독립영양탈질의 화학양론식 연구)

  • Lee, Su-Won;Kim, Gyu-Dong;Choi, Young-Gyun;Kim, Dong-Han;Chung, Tai-Hak
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.2
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    • pp.121-127
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    • 2004
  • It is necessary to supply external carbon source for enhancement of biological nitrogen removal from domestic wastewater with low influent C/N ratio. Sulfide was chosen as a cost effective electron donor and reaction stoichiometry for autotrophic denitrification was investigated by conducting bench-scale experiments in this study. Higher sulfur to nitrogen (S/N) ratio than the calculated value from theoretical reaction stoichiometry was required when the anoxic reactor was operated at open condition because dissolved oxygen introduced by surface aeration reacted with sulfide with ease. In addition, higher sulfate production and lower yield of microorganism could be observed under the same condition. It was possible to obtain reliable reaction stoichiometry for autotrophic denitrification by establishing pure anoxic condition. Linear relationship between bacterial growth and consumption of nitrate, sulfide, alkalinity, and sulfate production enabled to derive a relatively correct reaction stoichiometry for autotrophic denitrification when sulfide was used as an electron donor.