• 제목/요약/키워드: Reaction characteristic

검색결과 746건 처리시간 0.031초

모형 가스터빈 연소기에서 희박 예혼합 화염의 연소 특성 및 유동 해석에 관한 연구 (A Study on Combustion Characteristics and Flow Analysis of a Lean Premixed Flame in Lab-Scale Gas Turbine Combustor)

  • 유혜연;김규보;전충환;장영준
    • 대한기계학회논문집B
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    • 제32권8호
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    • pp.574-581
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    • 2008
  • The characteristics of combustion and flow for a lean premixed flame in lab-scale gas turbine combustor was studied through experiment and numerical analysis. From the experiment, flame structure and heat release rate were obtained from OH emission spectroscopy. Qualitative comparisons were made line-integrated OH chemiluminescence image and abel-transformed one. NOx analyzer was implemented to get the characteristic of NOx exhaust from the combustor. From the numerical analysis, the thermal distribution and characteristic of recirculation zone with the change of fuel-air mixing degree, the characteristic of methane distribution with equivalence ratio in the combustor respectively. Total heat release rate is increased with increasing equivalence ratio. Thermal Nox is reduced with increasing fuel-air mixing degree. Increasing equivalence ratio results in the decrease of the size of reaction zone and alteration of the position of the reaction zone into the entrance of the combustor.

역청탄과 아역청탄 혼합연소조건에서 입자크기와 혼소율이 열물성반응과 연소특성에 미치는 영향 (Effect of Particle size and Blending Ratio on Thermo Reaction and Combustion Characteristics in Co-firing with Bituminous and Sub-bituminous Coals)

  • 성연모;안재우;문철언;안성율;김성철;서상일;김태형;최경민;김덕줄
    • 한국연소학회지
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    • 제15권4호
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    • pp.65-73
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    • 2010
  • In order to provide fundamental information for developing reaction model in the practical blended coal power plants, effects of particle size and blending ratio on combustion characteristics and thermal reaction in co-firing with bituminous and sub-bituminous coals were experimentally investigated using a TGA and a laboratory-scale burner. Characteristic parameters including ignition, burnout temperature and activation energy were determined from TG and DTG combustion profiles. Distributions of flame length and mean particle temperature were investigated from the visualization of flames in slit-burner system. As coal particle size decreased and volatile matter content increased, characteristic temperatures and activation energy decreased. The ignition/burnout characteristics and activation energy are linearly influenced by a variation in particle size and blending ratio. These results indicated that the control of the coal blending ratio can improve the combustion efficiency for sub-bituminous coals and the ignition characteristics for bituminous coals.

고체로켓 추진기관용 연소관단열재의 내열성능평가를 위한 시험장치 개발 (A Development of Test Equipment for Thermal Protection Performance on Insulator used in Solid Rocket Motor)

  • 강윤구;윤덕진;김수영;이종성;권태하
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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    • pp.543-546
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    • 2017
  • 고체로켓 추진기관의 연소관 내부에 사용되는 연소관단열재의 열반응 특성을 평가하기 위한 모사시험장치를 개발하였다. 연소실 압력 2,500 psi, 연소시간 40 s까지 시험을 할 수 있으며, 삭마가 일어나는 조건에 대해 재료의 열반응 특성을 확인할 수 있고, 여러 시편을 동시에 상대 비교할 수 있다. 시험 장치의 안전성을 확인하기 위하여 연소실 유효평균압력 878 psi, 유효연소시간 10.7 s, 연소가스속도 100 m/s 조건에서 각기 다른 시편 4 종을 동시에 장착하여 시험을 수행하였으며, 열반응 특성 분석에 필요한 기본 데이터들, 즉 연소실의 압력-시간 선도, 재료 내부에서의 온도-시간 선도, 재료의 열파괴두께를 획득하였다.

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Phytosterylferulate가 米糠油 暗色化에 미치는 影響에 關한 硏究 (The Darkening Effect of Phytosterylferulate on the Rice Bran Oil)

  • 김점식
    • 대한화학회지
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    • 제13권4호
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    • pp.325-332
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    • 1969
  • An attempt has been made to investigate the nature of the characteristic darkening reaction occurring in the rice bran oil during the storage. Several pigments were separated by using column and thin layer chromatography of the pigments was made in the light of the knowledge of absorption spectral behavior. The presence of trace amount of iron and phytosteryl esters of ferulic acid (3-methoxy-4-hydroxy-cinnamic acid) was found to be responsible for the development of the characteristic color in rice bran oil. The model reactions with the ferulate, iron and fatty acids could be suggested the mechanism.

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$CaO-Al_2O_3-SiO_2$계 유리의 수화반응특성 (A study on the characteristic of hydration reaction in $CaO-Al_2O_3-SiO_2$ system glass)

  • 조재우;김승진;김영근;손진군
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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    • pp.289-292
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    • 1999
  • The charateristic of hydration reaction was studied in CaO-Al2O3-SiO2 system glass. As a result, the rate of heat liberation curves of synthestized glass becomes fixed after having increased by degrees. And it is decreasing after having increased suddenly. It was found that the total heat liberation with hydration for synthesized glass has a close relationship with the formation amount of ettringite.

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Reactions of Two Isomeric Thiols with Thianthrene Cation Radical

  • Park, Hyun-Ju;Lee, Wang-Keun
    • Bulletin of the Korean Chemical Society
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    • 제26권9호
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    • pp.1335-1338
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    • 2005
  • Thianthrene cation radical perchlorate ($Th^{+{{\cdot}}}{ClO_4}^-$) reacted readily with two isomeric thiols, benzylthiol (1) and 4-methylbenzenethiol (7) in an acetonitrile solution at room temperature. From the reaction of 1, the major products, N-benzylacetamide (4) and benzyl sulfide (5), are characteristic of benzyl carbocations while the minor one, benzyl disulfide (6) implies free radical component of the reaction. It is unprecedented that the formation of a benzyl carbocation was caused by the extrusion of sulfur atoms from benzyl sulfur cations (3). In contrast, from the reaction of 7, only p-tolyl disulfide (10) was obtained from both sulfur radicals and cations. In the reaction of 7 the thio-extrusion was not observed from the p-tolyl sulfur cation (9). A thianthrene cation radical ($Th^{+{{\cdot}}}$) was reduced quantitatively to thianthrene (Th) in both reactions.

수송기기 유압 실린더 블록 재료의 Fe-Cu 계면반응 특성 (A Characteristic of Fe-Cu Interfacial Reaction in the Hydraulic Cylinder Block for Vehicle Parts)

  • 김해지;김남경
    • 한국기계가공학회지
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    • 제3권1호
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    • pp.90-94
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    • 2004
  • Generally, a hydraulic cylinder block which is one of a vehicle parts that plays Important role in excavator power transmission, has copper alloy separation phenomenon by sliding motion between metals in high pressure condition. In this paper, to solve this problem, the interfacial reaction layer of Fe-Cu With SCM440 and copper alloy is studied through the melting method. As the result of this study, it is found that the interfacial reaction layer of $1{\mu}m$ created in the interface of Fe-Cu which has very strong physical bonding. It has been also confirmed that the melting method can improve life of the hydraulic cylinder block.

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동특성을 고려한 스프레더용 충격흡수기의 시스템 변화에 따른 최적설계 (The Optimum Design according to System Variation of Impact Absorbing System for Spreader Considering Dynamic Characteristic)

  • 안찬우;홍도관;김동영;한근조
    • 한국정밀공학회지
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    • 제20권6호
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    • pp.230-237
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    • 2003
  • On this study, we operated the dynamic response for impact load of impact absorbing system for spreader by the finite element analysis and showed respectively the spring constant and the damping coefficient which the reaction force by impact was the lowest value for three types impact absorbing system according to the change of system, also we presented the change of impact reaction force according to the spring constant and the damping coefficient. Additionally, among the three types impact absorbing system according to the change of system, the reaction force of model II was the lowest value and the next model which has higher value than model II was model Iand model III has the highest value in the three types.

하중흐름을 통한 대형구조실험용 반력시설물의 설계 (Design Approach of Large-scale Experimental Facilities Reflect the Load Flow)

  • 이성은;고동우
    • 한국공간구조학회논문집
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    • 제16권2호
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    • pp.69-77
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    • 2016
  • The purpose of this study is to present a method that can estimate the height of reaction facilities for large structural experiment through load flow as primary design procedure. The characteristic of the load transmission according to the type of experiment was analyzed to obtain tensile and compressive forces occurring on the reaction facilities. Strong walls that are affected by the bending moment is applied the post-tensioning method, and the strong floor under the control of the tension and compression is designed in accordance with the load flow. And the optimum cross-section of the reaction facilities was obtained by comparing the stresses of the tensile stress and crack the concrete. Through validating elastic analysis, the design results were satisfied a given design conditions.