• Journal of Environmental Science International
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• v.20 no.8
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• pp.929-942
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• 2011

A novel conductivity technique was developed to detect penetration depth of the vessel fluid into the feedpipe. For a given reactor geometry, critical agitator speeds were experimentally determined at the onset of feedpipe backmixing using Rushton 6 bladed disk turbine (6BD) and high efficiency axial flow type 3 bladed (HE-3) impellers. The ratio of the feedpipe velocity to the critical agitator speed ($v_f/v_t$) was constant for either laminar or turbulent feedpipe flow regimes. Compared to the results of fast competitive reaction, feedpipe backmixing had to penetrate at least one feedpipe diameter into the feedpipe to significantly influence the yield of the side product. However, higher $v_f/v_t$ than that for L/d = 0 (position at the feedpipe end) of the conductivity technique is recommended to completely eliminate feedpipe backmixing in conservative design criteria. The conductivity technique was successful in all feedpipe flow conditions of laminar, transitional and turbulent flow regimes.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.03a
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• pp.111-116
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• 2004

An experiment was carried out to confirm the validity of time series evaluation of supersonic mixing condition by using catalytic reaction on a platinum wire. Geseous hydrogen was injected parallel to supersonic freestream (M$\infty$ $\approx$ 1.81) from a slit injector, which was located at backward facing step. Time series condition of supersonic mixing was evaluated by using W-type probe which has a platinum wire and reference wire (nickel wire). The evaluation was by simultaneously measuring each electric circuit which kept the temperature of wire constant. Investigations were also conducted for helium, air and no secondary injectant cases to compare with the hydrogen injectant case. The results indicated that it was possible to measure the time series behavior of air and hydrogen supersonic mixing layer or coherent motion of turbulence by using this evaluation.

• Journal of the Korean Society of Propulsion Engineers
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• v.20 no.3
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• pp.71-77
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• 2016

Characteristic of thermal reaction of Kevlar/EPDM internal insulator used in a solid rocket motor chamber was investigated at 1,030 psi, 35.86 s and 1,406 psi, 36.63 s. Surface status after test was similar each other and thermal destruction depth was 4.10 mm and 4.18 mm, respectively. Kinetic constant ${\xi}$, ${\zeta}$ and thermal destruction velocity $V_{TD}$ were also similar. It was concluded that characteristics of thermal reaction of Kevlar/EPDM internal insulator were not affected by change of chamber pressure.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.5
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• pp.1269-1279
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• 1995

An experimental study is carried out on turbulent diffusion flames stabilized by a circular cylinder in a divergent duct flow. A commercial grade gaseous propane is injected from two slits on the rod as fuel. Flame stability limits, as well as size and temperrature of recirculation zone, are measured by direct and schlieren photographs to clarify the characteristics and structure of diffusion flames and to assess the effect of various divergent angle of duct. The results of the present study are as follows. Temperature in the recirculation zone decreases with increasing divergent angle. The blow-off velocity in parallel duct is higher than that in divergent duct. Critical blow-off velocity is expected to be about 8-12 degree through blow-off velocity pattern. Regardless of divergent angles, the length of recirculation zone is nearly constant, and this length becomes longer with rod diameter. Pressure gradient has an effect on the eddy structure in shear layer behind the rod. With the increase of divergent angle, large scale eddies by dissipated energy in shear layer are split into small scale eddies, and the flame becomes a typical distributedreacting flame.

• Fire Science and Engineering
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• v.27 no.6
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• pp.64-69
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• 2013

The Numerical simulation was performed on the flow field around the two-dimensional rectangular bluff body in order to simulate an engine nacelle fire and to complement the previous experimental results of the bluff body stabilized flames. Fire Dynamic Simulator (FDS) based on the Direct Numerical Simulation (DNS) was employed to clarify the characteristics of reacting flow around bluff body. The overall reaction was considered and the constant for reaction was determined from flame extinction limits of experimental results. The air used atmosphere and the fuel used methane. For both fuel ejection configurations against an oxidizer stream, the flame stability and flame mode were affected mainly by vortex structure near bluff body. In the coflow configuration, air velocity at the flame extinction limit are increased with fuel velocity, which is comparable to the experiment results. Comparing with the isothermal flow field, the reacting flow produces a weak and small recirculation zone, which is result in the reductions of density and momentum due to temperature increase by reaction in the wake zone.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.6
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• pp.593-600
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• 2019

The combustion characteristics of methane/hydrogen pre-mixed flame have been investigated with swirl stabilized flame in a laboratory-scale pre-mixed combustor with constant heat load of 5.81 kW. Hydrogen/methane fuel and air were mixed in a pre-mixer and introduced to the combustor through a burner nozzle with different degrees of swirl angle. The effects of hydrogen addition and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using particle image velocimetry (PIV), micro-thermocouples, various optical interference filters and gas analyzers to provide information about flow velocity, temperature distributions, and species concentrations of the reaction field. The results show that higher swirl intensity creates more recirculation flow, which reduces the temperature of the reaction zone and, consequently, reduces the thermal NO production. The distributions of flame radicals (OH, CH, C₂) are dependent more on the swirl intensity than the percentage of hydrogen added to methane fuel. The NO concentration at the upper part of the reaction zone is increased with an increase in hydrogen content in the fuel mixture because higher combustibility of hydrogen assists to promote faster chemical reaction, enabling more expansion of the gases at the upper part of the reaction zone, which reduces the recirculation flow. The CO concentration in the reaction zone is reduced with an increase in hydrogen content because the amount of C content is relatively decreased.

• BMB Reports
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• v.33 no.3
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• pp.228-233
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• 2000

The steady-state investigation of the mechanism of Dhydroxyisovalerate dehydrogenase was performed in order to understand this type of kinetic patterns. The initial velocity was measured with various amounts of both substrates, NADPH and 2-ketoisovalerate. Double reciprocal plots gave patterns that conversed on or near the abscissa. Binding studies indicated that NADPH bound first to the enzyme. The product $NADP^+$ was found to be a competitive inhibitor with respect to NADPH at a constant concentration of 2-ketoisovalerate. However, it showed noncompetitive inhibition against 2-ketoisovalerate at a fixed amount of NADPH. Another product, D-hydroxyisovalerate, was a non-competitive inhibitor versus NADPH and 2-ketoisovalerate at constant levels of 2-ketoisovalerate and NADPH, respectively. These results were comparable with an ordered bi-bi mechanism, in which NADPH bound first to the enzyme, followed by the binding of 2- ketoisovalerate. $NADP^+$ is the last product to be released. The ordered reaction manner of D-hydroxyisovalerate dehydrogenase from 2-ketoisovalerate to D-hydroxyisovalerate allows the accurate regulation of valine metabolism and it may lead to the regulation of total biosynthesis of enniatins in the Fusarium species.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.11
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• pp.5610-5614
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• 2012

Performance of catalyst was studied with various operating conditions for selective catalytic reduction of $NO_x$ with $NH_3$. It is confirmed that catalysts containing Mn and Cu have a good efficiency in the usage of oxygen by the $H_2$-TPR analysis. In the case of catalyst #1, $NO_x$ conversion was decrease with the increase of reaction temperature. But in the case of catalyst #2, $NO_x$ conversion was increased and then remained constant with the increase of reaction temperature. This phenomenon is due to the difference of the $NH_3$ oxidation of both catalysts.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.21 no.7
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• pp.1058-1072
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• 1997

A head-neck complex dummy, for measuring brain pressure and reaction force in the cervical spine was developed for experimental study related in injury mechanism. Dummy comprised aluminium-casted head with water filled cavity for simulating brain and mechanical neck assembled with six motion segments. Several kinds of experiments (compression, bending, cyclic modulus, relaxation and constant velocity profile) for the developed mechanical neck showed that this neck model is biomechanically reliable compared with in-vitro test results. As an application of developed head-neck complex dummy, shock absorbing properties of protective helmet was chosen. The experiments showed that the maximum pressure increment of brain after impact was tolerable compared with the guide line for mild brain injury pressure (25psi). Constrast to this results, the reaction force in the neck was high enough to produce failure in the cervical spine.

• Journal of the Korean Chemical Society
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• v.15 no.3
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• pp.109-116
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• 1971

The mechanical degradation of poly (${\alpha}$-methyl styrene) in several mixed solvents (toluene-n-butyl alcohol, toluene-sec-butyl alcohol, toluene-kerosene, toluene-methyl ethyl ketone), from $1^{\circ}C to $45^{\circ}C$, was studied using the capillary flow method. The velocity constant of scission reaction (k) and the limited degree of polymerization (g) were compared at the same value of [${\eta}$] at each temperatures. As results, mechanical degradation of polymer in dilute mixed solutions is affected by composition of solvents around the polymer chains.