• Title/Summary/Keyword: Reaction System

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Water Gas Shift Reaction Research of the Synthesis Gas for a Hydrogen Yield Increase (수소 수율 증가를 위한 합성가스의 수성가스전환 반응 연구)

  • Kim, Min-Kyung;Kim, Jae-Ho;Kim, Woo-Hyun;Lee, See-Hoon
    • New & Renewable Energy
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    • v.5 no.2
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    • pp.9-14
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    • 2009
  • Automobile Shredder Residue (ASR) is very appropriate in a gasification melting system. Gasification melting system, because of high reaction temperature over than $1,350^{\circ}C$, can reduce harmful materials. To use the gasification processes for hydrogen production, the high concentration of CO in syngas must be converted into hydrogen gas by using water gas shift reaction. In this study, the characteristics of shift reaction of the high temperature catalyst (KATALCO 71-5M) and the low temperature catalyst (KATALCO 83-3X) in the fixed - bed reactor has been determined by using simulation gas which is equal with the syngas composition of gasification melting process. The carbon monoxide composition has been decreased as the WGS reaction temperature has increased. And the occurrence quantity of the hydrogen and the carbon dioxide increased. When using the high temperature catalyst, the carbon monoxide conversion ratio ($1-CO_{out}/CO_{in}$) rose up to 95.8 from 55.6. Compared with average conversion ratio from the identical synthesis gas composition, the low temperature catalyst was better than the high temperature catalyst.

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Development and application of a batch reaction calorimeter (회분식 반응열 분석 시스템의 개발과 응용)

  • 이기형;이대욱;정상태;이광순
    • 제어로봇시스템학회:학술대회논문집
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    • 1992.10a
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    • pp.947-952
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    • 1992
  • A batch reaction calorimeter is the device for estimating reaction heat along time. Reaction heat formation data are very imoprtant for batch reactor behavior analysis and operatoin. So, many types of reaction calorimeter have been introduced and used. In this study, we analyze the dynamic charateristics of the batch reaction calorimeter that is designed in our laboratory. And we introducde suitable temperature control system. As a result, we analyze reatin heat formation data obtained by simulation and introduce its application examples.

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Immobilization of Trigonopsis variabilis and Conversion of Cephalosporin C to 7$\beta$-(4-Caboxybutanamido)Cephalosporanic Acid (Trigonopsis variabilis의 고정화 및 Cephalosporin C로부터 7$\beta$-(4-Carbohybutanamido)Cephalosporanic Acid의 전환)

  • 김종균;임재윤
    • Microbiology and Biotechnology Letters
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    • v.22 no.3
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    • pp.296-303
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    • 1994
  • An immobilized Trigonopsis variabilis cells having an high activity of D-amino acid oxidase(DAO) was used to convert CPC into GL-7-ACA. The optimal pH of the reaction system was 8.0-8.5, and the optimal temperature was 40$\circ$C. When immobilized cell was used repeatedly in semi-batchwise reaction, the system retained 80% of the initial activity after used of 12 times for over 12 hours. The storage stability of the immobilized cell was maintained for 30 days at 4$\circ$C. The CPC concentration for the maximal reaction rate was about 30 mM and 40 mM for free and immobilized cells, respectively. Substrate inhibition of CPC concentration more than 50 mM was overcomed by 20~25% by immobilization. Pure oxygen supply into reaction system was most efficient in D-amino acid oxidase reaction. Continuous conversion to GL-7-ACA from CPC has been developed with an bioreactor system containing immobilized T variabilis cells. By opera- tion of the reactor for 5 hours, the average conversion yield of >80% and GL-7-ACA production of 40~45 mM per hour could be obtained.

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Enzymatic Synthesis of Cyclodextrin in an Heterogeneous Enzyme Reaction System Containing Insoluble Extruded Starch (Extrusion 전분을 기질로 한 불균일상 효소반응계에서의 Cyclodextrin 효소합성)

  • 이용현;박동찬
    • Microbiology and Biotechnology Letters
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    • v.19 no.5
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    • pp.514-520
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    • 1991
  • Direct synthesis of cyclodextrin (CD) from extruded insoluble corn starch without liquefaction procedure using cyclodextrin glucanotransferase (CGTase) was carried out. Increased CD production rate and yield were achieved in heterogeneous enzyme reaction system containing extruded corn starch compared with those of conventional system employing liquefied or partially cyclized starch. At extruded starch concentration of 100 g/l the CD concentration and conversion yield were reached up to 54 g/l and 0.54, respectively. High purity of $\alpha \beta \gamma$-CDs without accumulation of undesirable malto-oligosaccharides was produced, furthermore, the residual extruded starch was easily separated by centrifugation from reaction mixture, whlch will facilitate the purification procedure. Granular structure of extruded starch was observed by SEM to investigate enzyme reaction mechanism. Supplemental addition of $\alpha$-amylase enhanced slightly the initial CD production rate, but it decomposed produced CD at the late stage. Various! extruded raw starches, such as, corn, rice, and barley were also suitable substrates for CD production.

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Model System Study for the Mutagenicity of Sugar-Glycine Systems

  • Lee, Jae-Hwan;Shin, Han-Seung
    • Food Science and Biotechnology
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    • v.17 no.4
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    • pp.839-841
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    • 2008
  • The mutagenicity after heating of different sugars (glucose, fructose, galactose, and tagatose) on the non-enzymatic browning reaction in different sugars and glycine model system was investigated. The model system containing 0.2 M glycine and 0.2 M of different sugars in 10 mL water was heated at $150{\pm}5^{\circ}C$ for 30 min. After heating, degree of non-browning reaction intensity and mutagenicity using Salmonella typhimurium TA 98 were examined. Heated glycine model systems containing different sugars increased their mutgenicity ranged from 30 to 372 revertant colonies. After heating for 40 min, mutagenicity was achieved with glycine model systems containing 4 different sugars with by 145, 356, 206, and 369 revertants per plate, respectively. The glycine model systems containing fructose or tagatose were significantly (p<0.05) higher mutagenic activity than glycine model systems containing glucose or galactose after 40 min of heating. The linear regression between Maillard reaction intensity and mutagenic activities (slope=32.38, $R^2=0.93$) indicates that mutagenicity could be fully ascribed to Maillard reaction products.

Identification of Input Force for Reaction Wheel of Satellite by Measured Action Force on Decelerating (감속 시의 고정부 작용력 측정을 이용한 반작용휠 계의 가진 입력 특성 규명)

  • Shin, Yun-Ho;Heo, Yong-Hwa;Oh, Shi-Hwan;Kim, Dae-Kwan;Kim, Kwang-Joon;Yong, Ki-Lyuk
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2009.10a
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    • pp.671-677
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    • 2009
  • A reaction wheel is commonly used, as an important actuator, to control the attitude of a satellite. Operation of the reaction wheel plays a role of an excitation source to loading equipment inside the satellite. As requirements for environmental vibration to manifest the performance of precision equipment are getting more stringent, the research for analysis or reduction of unwanted action force in high frequency range when operating the reaction wheel is necessary. In this paper, the procedure to extract input forces and damping of a rotor system of reaction wheel is suggested. The analysis for measured action forces of reaction wheel is accomplished and important higher harmonics of action forces are determined. The input forces and damping of the rotor system are, then, extracted by curve-fitting and a particular solution for input force.

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Correlation between sway magnitude and joint reaction force during postural balance control (자세 균형 제어 시 동요의 강도와 관절 반발력의 상관관계)

  • 서민좌;조원학;최현기
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.1160-1165
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    • 2004
  • The purpose of this study was to calculate three dimensional angular displacements, moments and joint reaction forces of the ankle joint during the waist pulling, and to assess the ankle joint reaction forces according to different perturbation modes and different levels of perturbation magnitude. Ankle joint model was assumed 3-D ball and socket joint which is capable of three rotational movements. We used 6 cameras, force plate and waist pulling system. Two different waist pulling systems were adopted for forward sway with three magnitudes each. From motion data and ground reaction forces, we could calculate 3-D angular displacements, moments and joint reaction forces during the recovery of postural balance control. From the experiment using falling mass perturbation, joint moments were larger than those from the experiment using air cylinder pulling system with milder perturbation. However, JRF were similar nevertheless the difference in joint moment. From this finding, we could conjecture that the human body employs different strategies to protect joints by decreasing joint reaction forces, like using the joint movement of flexion or extension or compensating joint reaction force with surrounding soft tissues. Therefore, biomechanical analysis of human ankle joint presented in this study is considered useful for understanding balance control and ankle injury mechanism.

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Identification of Input Force for Reaction Wheel of Satellite by Measured Action Forceon Decelerating (감속 시의 고정부 작용력 측정을 이용한 반작용휠 계의 가진 입력 특성 규명)

  • Shin, Yun-Ho;Heo, Yong-Hwa;Oh, Shi-Hwan;Kim, Dae-Kwan;Kim, Kwang-Joon;Yong, Ki-Lyuk
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.20 no.3
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    • pp.263-271
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    • 2010
  • A reaction wheel is commonly used, as an important actuator, to control the attitude of a satellite. Operation of the reaction wheel plays a role of an excitation source to loading equipment inside the satellite. As requirements for environmental vibration to manifest the performance of precision equipment are getting more stringent, the research for analysis or reduction of unwanted action force in high frequency range when operating the reaction wheel is necessary. In this paper, the procedure to extract input forces and damping of a rotor system of reaction wheel is suggested. The analysis for measured action forces of reaction wheel is accomplished and important higher harmonics of action forces are determined. The input forces and damping of the rotor system are, then, extracted by curve-fitting and a particular solution for input force.

Comparison of Complications in Direct and Indirect Osseointegration of Prosthetic Auricular Reconstruction (인조귀 부착술에서 직접 및 간접골통합법의 합병증에 대한 비교)

  • Park, Mu Shik;Han, Ki Hwan;Kim, Jun Hyung
    • Archives of Plastic Surgery
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    • v.32 no.3
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    • pp.293-298
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    • 2005
  • Osseointegrated prosthetic auricular reconstruction can be classified as either direct or indirect. In the $Br{\aa}nemark $ system of direct osseointegration, implants are placed into the mastoid process of the temporal bone. In the Epitec system of indirect osseointegration, implants are inserted into a three-dimensional carrier plate that is fixed to the mastoid by means of screws. We experienced forty-four cases using the indirect system and seventeen cases using the direct system. We compared with two systems by complications, such as skin reaction, implant loosening, implant loss. There were no specific differences in the skin reaction around the implants and abutments in relation to age or system used. The degree of skin reaction was different according to the conditions around the implant: in cases of virgin microtia, a skin flap was used to cover the implant, in contrast to grafted skin coverage for failed autogenous reconstruction. In both systems, the skin reaction was more severe and frequent in skin flap than in grafted skin. Loosening of the implant was more frequent in the direct system; however, accidental detachment of the implant from the abutment was more frequent in the indirect system. To reduce complications of skin reaction in osseointegrated prosthetic auricular reconstruction, it is important for soft tissue around implant to immobilize. Therefore, grafted skin is better than skin flap as soft tissue around implant. And immobilization of soft tissue around implant by wound dressing is major facter.

Development of a Driving Operation System for Vehicle Simulator (차량 시물레이터의 운전석 시스템 개발)

  • 유성의;박민규;유기성;이민철
    • 제어로봇시스템학회:학술대회논문집
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    • 2000.10a
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    • pp.291-291
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    • 2000
  • A vehicle driving simulator is a virtual reality device which a human being feels as if the one drives a vehicle actually. Driving Operation System acts as an interface between a driver and a driving simulator. This paper suggests the driving operation system for a driving simulator. This system consists of a controller, DC geared motor, MR brake, rotary encoders, steeping motor and bevel gear box. Reaction force and torque on the steering system were made by DC_Motor and MR_Brake. Reaction force and torque on the steering system were compare between real car and a driving simulator. The controller based on the 80C196KC micro processor that manage and transfer signal.

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