• Korean Journal of Materials Research
• /
• v.9 no.3
• /
• pp.288-294
• /
• 1999

In the flip chip interconnection using solder bump, the Under Bump Metallurgy (UBM) is required to perform multiple functions in its conversion of an aluminum bond pad to a solderable surface. In this study, various UBM systems such as $Al 1\mu\textrm{m} / Ti 0.2\mu\textrm{m} / Cu 5\mu\textrm{m}, Al 1\mu\textrm{m} / Ti 0.2\mu\textrm{m} / Cu 1\mu\textrm{m}, al 1\mu\textrm{m}/Ni 0.2\mu\textrm{m} / Cu 1\mu\textrm{m} and Al 1\mu\textrm{m}/Pd 0.2\mu\textrm{m} / Cu 1\mu\textrm{m}$ for flip chip interconnection using the low melting point eutectic 63Sn-37Pb solder were investigated and compared to their metallurgical properties. $100\mu\textrm{m}$ size bumps were prepared for using an electroplating process. The effects of the number of reflows and aging time on the growth of intermetallic compounds(IMC) were investigated. $Cu_6Sn_5$ and $Cu_3Sn$ IMC were abserved after aging treatment in the UBM system with thick coper $(Al 1\mu\textrm{m}/Ti 0.2\mu\textrm{m}/Cu 5\mu\textrm{m})$. However only the $Cu_6Sn_5$ was detected in the UBM system with $1\mu\textrm{m}$ thick copper even after 2 reflow and 7 day aging at $150^{\circ}C$. Complete Cu consumption by Cu-Sn IMC growth gives rise to a direct contact between solder inner layer such as Ti, Ni and Pd, and hence to possibly cause reactions between two of them. In this study, however, only for the Pd case, IMC of PdSn. was observed by Cu consumption. UBM interfacial reactions with s이der affected the adhesion strength ot s이der balls after s이der reflow and annealing treatment.

• Applied Chemistry for Engineering
• /
• v.16 no.6
• /
• pp.772-777
• /
• 2005

Porous hydrated lime and limestone filters were prepared by foaming and gelcasting method, and their physical properties were evaluated. Through these analyses, it has been found that with the increased porosity and pore size of the filters, majority of pores in the filters were inter-connected by windows. Also, $SO_2$ removal efficiency for the filters was investigated. As the porosity and the reaction temperature increased, $SO_2$ removal efficiency also increased. Especially, unlike the variation of entrance concentration, the entrance flow rate had great influence on the removal efficiency. In case of the filters with an equal porosity, the hydrated lime filter had superior removal efficiency compared to the limestone filter. From these results, it was shown that the high conversion ratio to CaO from the hydrated lime filter was a result of facilitated formation of $CaSO_4$ by $SO_2$.

• Applied Chemistry for Engineering
• /
• v.23 no.6
• /
• pp.534-538
• /
• 2012

$Na^+$-beta-alumina solid electrolyte was synthesized by solid state reaction using $Li_2O$ and MgO as a phase stabilizer, and the effect of stabilizers on the phase formation and sintering density was investigated. In order to determine the phase fraction according to the synthesizing temperature, the molar ratio of [$Na_2O$] : [$Al_2O_3$] was fixed at 1 : 5, and calcination was conducted at temperatures between $1200{\sim}1500^{\circ}C$ for 2 h. In the $Li_2O$-$Na_2O$-$Al_2O_3$ ternary system, ${\beta}^{{\prime}{\prime}}$-alumina phase fraction considerably increased by the secondary phase transition at $1500^{\circ}C$, whereas it maintained similarly in the MgO-$Na_2O$-$Al_2O_3$ system. Additionally, the disc-type specimens of $Na^+$-beta-alumina were sintered at the temperature between $1550{\sim}1650^{\circ}C$ for 30 min, and relative sintering densities, phase changes, and microstructures were analyzed. In case of $Li_2O$-stabilized $Na^+$-beta-alumina, ${\beta}^{{\prime}{\prime}}$-phase fraction and relative density of specimen sintered at $1600^{\circ}C$ were 94.7% and 98%, respectively. Relative density of MgO-stabilized $Na^+$-beta-alumina increased with a rise in sintering temperature.

• Journal of the Mineralogical Society of Korea
• /
• v.32 no.3
• /
• pp.213-222
• /
• 2019

Birnessite (birnessite, $7{\AA}$ manganate, ${\delta}-MnO_2$) is a major mineral comprising manganese nodule. Various synthetic methods have been studied and evaluated because it can be used as an ion exchange agent and a battery recharging material. However, it is difficult to obtain a single birnessite phase because it does not have a stoichiometric chemical composition. Feitknechtite (${\beta}-MnOOH$) is formed as an intermediate product during birnessite synthesis and in this study, the transition of this phase to birnessite was compared by using XRD and SEM. Two different methods, Feng et al. (2004) and Luo et al. (1998), based on redox reaction were used. It was possible to obtain the impurity-free birnessite for the sample aged 60 days at $27^{\circ}C$ by Feng et al. (2004) method and 3 days at $60^{\circ}C$ by Luo et al. (1998) method. The phase transition rate of the feitknechtite phase was slower in the case of $Mg^{2+}$ doped birnessite which was synthesized by Luo et al. (1998) method, and almost single phase almost single phase birnessite was identified at high temperature. Crystal surface and morphology also confirmed the difference between the samples synthesized by two methods.

• Cross-Cultural Studies
• /
• v.45
• /
• pp.245-268
• /
• 2016

Tokyo! is a 2008 French / Japanese / South Korean / German anthology film containing "Interior Design" by Michel Gondry, "Merde" by Leos Carax, and "Shaking Tokyo" by Joon-ho Bong, all of which were filmed in Tokyo. This cinematic triptych of three Tokyo-set stories is concerned with how the experience of self-alienation is related to urban life, that is, how to survive in a city as a self. The problem of life is the struggle for self-preservation. In Tokyo! the three film directors have shown that urban life is both self-deconstructing and self-preserving. In this paper, our purpose is to examine different modes of urban life by using two concepts reformulated by the French philosopher Jacques Derrida: the urban ipseity and auto-immunity. According to Derrida, ipseity is a system subjected to a circular structure. Such a system cannot avoid the general logic of auto-immunity; i.e., the structure of ipseity functions as both self-deconstructing and self-preserving. The three episodes contained in Tokyo! testify, each in its own way, to the function of that logic. In bringing to light the three modes of self: appropriation, dis-appropriation, and in-appropriation, we claim that the modality of urban life is confronted with the autoimmune reaction.

• Korean Chemical Engineering Research
• /
• v.57 no.4
• /
• pp.475-483
• /
• 2019

Special chemical warfare agents are lethal gases that attack the human respiratory system. One of such gases are blood agents that react with the irons present in the electron transfer system of the human body. This reaction stops internal respiration and eventually causes death. The molecular sizes of these agents are smaller than the pores of an activated carbon, making chemical adsorption the only alternative method for removing them. In this study, we carried out a Computational Fluid Dynamics simulation by passing a blood agent: cyanogen chloride gas through an SG-1 gas mask canister developed by SG Safety Corporation. The adsorption bed consisted of a Silver-Zinc-Molybdenum-Triethylenediamine activated carbon impregnated with copper, silver, zinc and molybdenum ions. The kinetic analysis of the chemical adsorption was performed in accordance with the test procedure for the gas mask canister and was validated by the kinetic data obtained from experimental results. We predicted the dynamic behaviors of the main variables such as the pressure drop inside the canister and the amount of gas adsorbed by chemisorption. By using a granular packed bed instead of the Ergun equation that is used to model porous materials in Computational Fluid Dynamics, applicable results of the activated carbon were obtained. Dynamic simulations and flow analyses of the chemical adsorption with varying gas flow rates were also executed.

• The Journal of the Korea Contents Association
• /
• v.19 no.3
• /
• pp.365-374
• /
• 2019

Unlike benign tumors, malignant tumors are capable of metastasis, easy to relapse, poor survival, and low quality of life. In Korea, here is a tendency to treat the tumors collectively according to the General Principles of Cancer Chemotherapy(GPCC) of the Health Insurance Review & Assessment Service (HIRA). But recently, companion diagnostics(CDx) is recommended rather than unilateral medication because biomarker-based molecular diagnostics is possible to predict the drug response of patients before drug treatment. Not only domestic but also overseas Food and Drug Administratio (FDA) recommends the development of the CDx system at the stage of drug development to ensure the responsiveness and safety of medicines. In this study, I focused on the necessity of CDx development direction as well as CDx development status through literature review. Furthermore I also discussed CDx types according to the molecular diagnostic technology such as immunohistochemistry (IHC), polymerase chain reaction (PCR), in situ hybridization (ISH), and next-generation sequencing (NGS) not only in the approved CDx but also in the developing one by US FDA. And I suggested the technology issue of CDx development process such as a selection of molecular diagnostics at the time of release, a clear understanding of the CDx mechanism, and a convergence of drug with CDx development. The necessity of social insurance system also was proposed for CDx development.

• Korean Journal of Child Education & Care
• /
• v.18 no.4
• /
• pp.65-89
• /
• 2018

Objective: The purpose of this study is to analyze the science concepts and teaching and learning methods presented in the science education-related activities of the Nuri Curriculum teacher guidebooks for ages 3-5. Methods: The research data included 772 activities related to science education in the teachers' guidebook. The analysis of science concepts was based on physical science (force and motion, physical structure, electricity and magnetism, light and shadow, sound properties), chemistry (material properties, material reaction), life science (organizational structure, growth and change, heredity and evolution, animal plant and human relationships), earth science (earth system interaction, earth system structure, and universe), engineering (designed world, engineering design, engineering, technology and society) and ecology (environment preservation). Teaching and learning methods were analyzed according to the types of small and large group activities and of free play activities. Results: Science concepts were mainly presented in the fields of engineering, chemistry, and life science commonly among children aged 3-5, whereas the concepts of physical science were lowly presented in all ages. Science concepts appeared mainly in the daily subjects of 'animal plant and nature', 'life tools', 'environment and life', and 'spring, summer, autumn and winter'. As the teaching and learning method, free paly activities (science area, free outdoor selection activity, math and manipulative activity) were mostly used for the ages of 3 and 4, and small and large group activities (cooking, story sharing, music activity) were for the age of 5. Conclusion/Implications: It is necessary to select the level of science area and concept that can be taught according to the age of children and the timing of the teaching.

• Journal of Korean Society of Coastal and Ocean Engineers
• /
• v.31 no.2
• /
• pp.73-87
• /
• 2019

Ocean waves are the driving force for the sediment transport and the beach process. However, wave actions are nonlinear and non-stationary, and the response of the beach is inconsistent in terms of reaction rate and magnitude. Therefore, the beach process is difficult to predict accurately. The purpose of this study is to identify the correlations between the shoreline change and ocean waves observed in the east coast of Korea. The relation of the beach width obtained from video monitoring at five sandy beaches and the wave data obtained from nearby wave monitoring at three points was analyzed. Although the correlations estimated over the whole data sets was not significant, the correlations estimated based on the seasonal period or wave conditions provided more noteworthy information. When the non-exceedance probability of the wave height was greater than 0.99, the wave period and beach width showed strong negative correlations. In case the non-exceedance probability of the wave period was greater than 0.99, the wave height and beach width showed strong negative correlations as well. Furthermore, the erosion rate of the beach width increased when the primary wave direction was close to normal to the coastline. Little significant seasonal or monthly change was found between the beach width and the wave, but it was greatly affected by intensive events such as typhoons. Thus, it is necessary to analyze in detail the wave height or period level explaining the change of beach width for more relevant and practical information.

• Korean Chemical Engineering Research
• /
• v.59 no.4
• /
• pp.514-520
• /
• 2021

A drug delivery system (DDS) based on nanoparticles has been used as a mediator to improve the efficacy of a drug by controlling the amount of drug released and delivering it to a target place. Chitosan, which is non-toxic and biodegradable, has good biocompatibility and excellent adsorption, so it can be used as a drug delivery vehicle. Valine, the essential amino acids, helps muscle growth and tissue recovery, and along with other amino acids. It lowers blood sugar levels and increases growth hormone production. In this study, Valine was adsorbed on magnetic chitosan which is capable of drug absorption, and Fe₃O₄-Valine CNPs was prepared through cross-linking with TPP (Tripolyphosphate). And then absorption and release trends of valine were investigated with the Fe₃O₄-Valine CNPs. Fe₃O₄, which has relatively high stability, is used to make the drug carrier magnetic so that the drug can be delivered to a target place. At optimal conditions, the absorption and release tendency of Fe₃O₄-Valine CNP was confirmed by analyzing by UV-Vis through the Ninhydrin test which is the color reaction of amino acids and by measuring the size of the particles, it was confirmed that it is suitable as a drug carrier.