• Journal of the Korean Applied Science and Technology
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• v.29 no.1
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• pp.19-32
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• 2012

Pharmaceutical use accounts for a great part of articles and papers on crosslinking of polymers. Crosslinking of polymers used for tissue engineering and drug delivery respects non-cytotoxicity and in situ gelling. The crosslinking of polymers is aimed not only at the improvement of modulus, chemical resistance, and thermal resistance, but also at endowing them with such functions as metal adsorption, antifouling, and ion exchange via crosslinked segments. Smart polymers responding to environmental change, and cosslinking mediated by light, enzyme, natural compound and in aqueous medium in consideration of environment are being studied. Developing new polymeric materials is essential along with the pharmaceutics aiming at the longevity of 120 years old. Functionalization and property adjustment of polymers through crosslinking will be done more delicately. Hydrogels will be focused on injectable and in situ gel forming. In the coating industry crosslinking system with low non-toxicity and low energy consumption will be developed in consideration of workers and environment.

• Journal of the Korea institute for structural maintenance and inspection
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• v.8 no.4
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• pp.87-96
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• 2004

As a special concrete, which is a mixture of soil, cement and water, has strength like regular concrete for pavement, soil cement has been used in various field such as pavement and soft soil improvement. The objective of this study was to investigate the characteristic of unconfined compressive strength and time dependent behavior of soil cement that is made from decomposed granite soil or coluvial and inorganic solidification liquid. The results showed that the unconfined compressive strength appears to increase as the amount of cement and curing time increase In addition, the strength seems to decrease with increase of the potion of fine particles(No 200 sieve). The result of XRD indicated that there is Vermiculite, the product of reaction, in the soil cement. The dynamic properties of material, such as shear complex compliance, shear complex modulus, and phase angle could be calculated from the hysteresis loop obtained from the Haversine Creep Tests. Finally, creep behavior was able to be predicted from these dynamic properties.

• Applied Chemistry for Engineering
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• v.19 no.4
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• pp.427-431
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• 2008

The rigid polyurethane foams (PUF) were prepared using polyols with 90, 110, 130, and 150 isocyanate index. The effect of sea water on the physical properties of PUF with the increase in isocyanate (NCO) index and ageing time was investigated. Tensile strengths and compressive strengths of the PUFs decreased up to 10% and 7% with an increase in ageing time, respectively. Cell morphology of the PUF under sea water was turned out to be the same as that in the ambient condition. It was observed that $T_g$ and tensile modulus of the PUF under sea water increased. The results showed an additional cross-link reaction of non-reacted MDI and the change of NCO peak as observed from FT-IR spectrum.

• Proceedings of the Korean Geotechical Society Conference
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• 2009.03a
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• pp.750-758
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• 2009

This study, as basic research which was intended to develope the surface reinforcement method using reinforcement material which is applicable to very soft ground in Korea, was aimed at proposing the design parameter for the surface ground improvement method. To that end, a wide width tensile test using geotextile, geogrid and steel bar (substitute for bamboo) and 25 kinds of the laboratory model tests with the end restraint conditions of the reinforcement that comprises the constrained and partially constrained (3 types) conditions were conducted. And the result indicated that the modulus of subgrade reaction or $N_c$ value (5.3) apparently overestimated the bearing capacity of very soft ground such as dredged ground. Moreover, as a result of model test by partially constraining the preload of 23.0kgf using geotextile, the effect of bearing capacity($q_1$) appeared to be the largest till the loading stress was $0.4tf/m^2$ due to cohesion, while it reached 75% of the maximum bearing force after $0.4tf/m^2$ due to increase in the effect of bearing capacity($q_2$) caused by the tensile force of the reinforcement. Such results tended to have appeared constantly or very similarly with each other, irrespective of the type of reinforcement (geogrid, steel bar) and constraint conditions.

• Korean Journal of Materials Research
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• v.30 no.1
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• pp.38-43
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• 2020

Sand casting 3D printing uses a binder jetting method to produce a mold having complicated shape by spraying a binder on sand coated with activator. Appropriate heat treatment process in sand mold fabrication can increase the degree of polymerization to improve flexural strength. However, long heat treatment of over 24 hours decreases flexural strength and reliability due to chemical bond decomposition through thermal degradation. The main role of the activator is to control the reaction rate between the polymer chains. As a result, when the activator composition is increased from 0.15 wt% to 0.25 wt%, the flexural strength is increased by 218 N/㎠. However, excess activator (0.40 wt%) has been shown to decrease reliability without increasing flexural strength. The main role of the binder is to control the flexural strength of the specimen. As the binder composition is increased from 2.00 wt% to 4.00 wt%, the flexural strength increases to about 255 N/㎠, indicating the maximum flexural strength increase. Finally, the reliability of the flexural strength of the fabricated specimens is evaluated by a Weibull plot. Weibull modulus calculations are used to evaluate the flexural strength reliability of the specimens, and maximum reliability value of 11.7 is obtained at 0.20 wt% activator composition. Therefore, it is confirmed that this composition has maximum flexural strength reliability.

• Elastomers and Composites
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• v.33 no.3
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• pp.185-192
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• 1998

This study was investigated on the physical properties of synthetic rubber compounds containing silica and silane copuled silica. Surface area and pore volume of silane copuled silica appeared to be low compared with those of pure silica because silane coupling agent blocks the pore of silica surface during silanization reaction. Silica with large surface area and high structure showed the short scorch time$(t_5)$ and rapid cure rate. The silane coupled silica showed the shorter scorch time and more rapid cure rate than pure silica because of the of effect of sulfur in the silane coupling agent(Si 69), The high value of $N_2SA$ minus CTAB com-pared with surface area and structure of silica showed the high 300% modulus. Also, the surface area and structure of silica did not affected the amount of PICO loss that indicate the abrasion resistance but affected the amount of cut and chip loss.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.765-768
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• 2008

Silica fume is a very important gradient in UHPC(Ultra High Performance Concrete) and its amount is normally over 25% of cement(wt.%). But we surely need to comprehend the influence of the amount of silica fume on the UHPC. In this paper, it was investigated how the amount of silica fume influence on the properties such as fluidity, compressive strength, elastic modulus, and flexural strength. Furthermore, it was examined the internal micro structure on UHPC through the test of SEM and MIP. In results, If we properly use silica fume in UHPC, fluidity and strength of UHPC was increased. It can be ascertained through the test of MIP that silica fume effectively increased density of UHPC by posolanic reaction and acting as filler. Especially, In case of Cement to silica fume ratio$0.1{\sim}0.25%$, we can be concluded that UHPC has similar to mechanical property.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.441-444
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• 2008

Ultra high performance concrete (UHPC) in this study is composed of sand, cement, silica fume, siliceous powder, superplasticizer and steel fiber. UHPC is composed of fine mineral particles below 0.5mm in diameter. In general, siliceous powder improves the mechanical properties of concrete by physical and chemical effect. Physical effect is related with filling interior voids which weaken the mechanical properties and chemical effect with reaction of $SiO_2$ with cement hydrates in a condition of high temperature and pressure. We evaluated the effect of siliceous powder's particle size on the mechanical properties of ultra high performance concrete in air pressure and $90^{\circ}C$ steam curing condition. siliceous powder's particle size in this study is in the range of $2{\mu}m$ to $26{\mu}m$. Fluidity in a fresh concrete, compressive strength, ultimate strain, elastic modulus and flexural strength in a hardened concrete was evaluated. We could find out that the smaller siliceous powder's particle size is, the better the fluidity and strength properties.

• Journal of the Korean Geotechnical Society
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• v.15 no.3
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• pp.151-160
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• 1999

The settlement limit concept is generally adopted as design criteria of rock-socketed pile foundations, therefore, the load-displacement$(\sigma-\sigma)$ behavior of the rock-socketed piles should be well understood at the design stage, which, however, is hard to achieve due to its complexity. To help this out, field pile load tests are executed on cast-in-situ concrete piles, first, to figure out the $\sigma$-$\delta$ behavior of rock-socketed piles. Next, the $\sigma-\sigma$ relations of the piles are simulated numerically using commercial package program(ELAC) varying a couple of input data which are sensitive in shaping the $\sigma$-$\delta$ curves. Finally, the relation between the best input data for the numerical simulations and the geotechnical field data are cultivated to generalize the numerical simulation procedures, which enables geotechnical engineers to predict the $\sigma$-$\delta$ behavior at the design stage, if appropriate geotechnical field data are provided.

• Elastomers and Composites
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• v.44 no.1
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• pp.63-68
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• 2009

Recently, much attention has focused on the permanent deformation of roads in hot summer and cracks in cold winter, which are detrimental to safe driving. This leads to necessity of modification of asphalt to resist those deformation. In this study, a type of modified asphalt was prepared by addition of a photoinitiator which is activated by ultraviolet lay. The mechanical and rheololgical properties of photoinitiator-modified asphalt were examined using UTM and rheometer. Results showed that the modified asphalt was effected by ultraviolet and thus tensile strength and storage modulus increased, due to molecular attraction, with initiator content and irradiation dose. Thermal analysis showed less weight loss upon photoinitiator-modification and this indicated that the molecular attraction is the result of cross linking reaction between asphalt molecules induced by photoinitiator. According to long term ultraviolet curing test, properties of the photoinitiator-modified asphalt did not decrease or even increase for 20 years. This indicates that useful life of the asphalt could be extended by addition of photoinitiator.