• Fibers and Polymers
• /
• v.4 no.4
• /
• pp.156-160
• /
• 2003

Poly(ethylene 2,6-naphthalate) (PEN)/Poly(ethylene glycol) (PEG) copolymers were synthesized by two step reaction during the melt copolymerization process. The first step was the esterification reaction of dimethyl-2,6-naphthalenedicarbox-ylate (2,6-NDC) and ethylene glycol (EG). The second step was the condensation polymerization of bishydroxyethylnaphthalate (BHEN) and PEG. The copolymers contained 10 mol% of PEG units with different molecular weights. Structures and thermal properties of the copolymers were studied by using $^1{H-NMR}$, DSC, TGA, etc. Especially, while the intrinsic viscosities of PEN/PEG copolymers increased with increasing molecular weights of PEG, but the glass transition temperature, the cold crystallization temperature, and the weight loss temperature of the copolymers decreased with increasing molecular weights of PEG. Consequently, the hydrophilicities by means of contact angle measurement and moisture content of the copolymer films were found to be significantly improved with increasing molecular weights of PEG.

• Journal of the Korean Ceramic Society
• /
• v.28 no.1
• /
• pp.74-78
• /
• 1991

Willemite powders which have been prepared by solid state reaction were easy to intermixed impurities, and particle surfaces were demaged in the progress of crushing. The above defacts were easy to accompany non-crystallization for mechanochemical effects and luminescence efficiency was deteriorated. The goal of this study improve each of defacts, and synthesize high purity and fine Mn doped willemite powders by wet and hydrothermal methods without crushing progress. It has been experimentally verified that the single phase Zn1.98Mn0.02SiO4 willemite powders which prepared by hydrothermal synthes is at 220$^{\circ}C$ for 10 hours in 2N KOH solution. The products are like needle and composition is the same with starting composition.

• Journal of the Korean Ceramic Society
• /
• v.26 no.3
• /
• pp.371-380
• /
• 1989

The purpose of this experiment is to elucidate the reaction mechanism concerning to the formation of crystalline BaTiO3 synthesized by adding the pH control agent(KOH soln) in TiCl4 and BaCl2 solution (Wet direct synthetic method). In this expeirment, it is identified that the amorphous barium-titanate having Ba-O-Ti bonding is formed above pH5 due to the -OH- ion and Ti-gel is formed below pH5 due to the polymerization of metatitanic acid. The bonding of the amorphous Ba-O-Ti is identified by FT-IR spectrum and crystallization temperature is about 82$0^{\circ}C$. If the pH of the above system according to the -OH- ion concentration is above 13.8, the polymerized metatitanic acid will be depolymerized and produce [TiO3]2+ion and crystalline BaTiO3 is formed by reacting the produced [TiO3]-- ion with the active Ba++ ion.

• Applied Chemistry for Engineering
• /
• v.18 no.4
• /
• pp.344-349
• /
• 2007

NaY zeolites synthesized by microwave heating were compared with those obtained by conventional heating. When the same temperature increasing rates were adopted in both heating methods, the microwave heating shortened the induction period and enhanced the rate of crystallization of NaY zeolites compared with the conventional heating. Irrespective of microwave radiation, the fast temperature increasing rate also shortened the induction time and enhanced the crystallization of NaY zeolites. The crystal sizes of NaY zeolites were large under the fast temperature raise of the reaction mixture and became larger by microwave radiation. At the same time, the fast temperature increasing rate has reduced the energy consumption due to the fast completion of reaction during the synthesis of NaY zeolite. The energy consumption in the conventional ethylene glycol bath was lower than that in the microwave oven with the same temperature increasing rate in this study, which means that the energy efficiency is not always high in microwave heating. If the temperature increasing rate is carefully controlled, however, NaY zeolite can be produced with high energy efficiency in the microwave oven.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.12 no.4
• /
• pp.190-195
• /
• 2002

NaX zeolite crystals of a uniform particle size of 50 $\mu$m were grown by continuous crystallization method from seed crystals (10~20 $\mu$m) added into a 0.5~2.0 g mother liquor having a composition $3.5Na_2O : Al_2O_3: 2.1SiO_2: 1000H_2O$. In order to investigate the crystal growing by continuous method, the mother solution was supplied after 7 days, 5 days, 3 days and 1 day, respectively. The seeding resulted in an increase in the fraction of large crystals compared with unseeded batches and successfully led to an uniform NaX zeolite crystal. It was postulated that the seeding in the synthesis mixture leaded out increase of surface area for physical contact reaction and directed growth of seed crystal without the nucleation in the synthesis gel.

• Korean Chemical Engineering Research
• /
• v.51 no.6
• /
• pp.760-765
• /
• 2013

Lysozyme crystallization was performed by using flow-focusing chip in droplet-based microfluidic system. Water-in-oil droplets were formed in the system and collected on petri-dish and cross type mold. Liquid-liquid reaction of lysozyme and sodium chloride occurred in the droplet and crystals were observed through microscope. Solution pH was varied as 4.8 and 7.2. Crystals of polyhedron and plate-like shape were obtained at pH 4.8, while needle structure crystals formed at pH 7.2. Lysozyme in single droplet for two pHs were crystallized with constant or decreased droplet size. However, crystals at pH 4.8 were only obtained in the droplet of which size was increased by the interaction between droplets. Droplet volume did not change at pH 7.2 and crystals formed in both droplets.

• The Korean Journal of Ceramics
• /
• v.2 no.1
• /
• pp.33-38
• /
• 1996

In thick film resistors, the characteristics of the frit and the reaction between glass frit and conductor material play an important role for their electrical properties. In this study, various glass frits in the system of $60RO{\cdot}20SiO_2$ $15B_2O_3{\cdot}5Al_2O_3$(RO=PbO, ZnO, CdO; mole%) were mixed with $RuO_2$ and coated on 96% alumina substrate. Only the glass frit containing PbO was reacted with $RuO_2$in$RuO_{2+}$-thick film resistor and produced the new crystalline phase of $Pb_2Ru_2O_{65}$. Their electrical resistivities strongly depend on the amount of $Pb_2Ru_2O_{65}$ crystalline phase obtained, which varied with firing temperature. The sheet resistivities of these resistors were varied from $10^3\; to\; 10^6\;{\Omega}/{\Box}$ depending on heat treatment, and the absolute value of TCR was decreased as the heat treatment temperature increaed. However, $RuO_2$ did not reacted with the glass frits containing ZnO nor CdO, and the resulting showed very high sheet resistivities.

• Journal of Korea Foundry Society
• /
• v.15 no.6
• /
• pp.566-573
• /
• 1995

In this study, the microstructural characteristics such as primary silicon, eutectic silicon, $SiC_p$ dispersion behavior, compound amount and Si solubility in $Al/SiC_p$ composite fabricated by the squeeze casting under various conditions were investigated systematically. As applied pressure(MPa) increases, cooling rate and compound amount are increased. In gravity casting, the cooling rate of hypereutectic composite is slower than of hypoeutectic composite by exothermic reaction of primary Si crystallization. But the cooling rate of hypereutectic composite is faster than that of hypoeutectic composite fabricated by same applied pressure, because amount of primary Si crystallization in hypereutectic composite was decreased, on the contrary, primary ${\alpha}-Al$ in hypoeutetic composite was increased due to increase of Si solubility in matrix by applied pressure. The crystalized primary silicon in hypereutectic composite fabricated by squeeze casting become more fine than that in non-pressure casting This is because mush zone became narrow due to increase of Si content of eutectic composition by pressure and time for growth of primary silicon got shorter according to applied pressure. It is turned out that eutectic temperature and liquidus are decreased by the increasing of squeeze pressure in all the composite due to thermal unstability of matrix owing to increasing of Si solubility in matrix by the increasing of applied pressure, as indicated in thermal anaiysis(DSC) results.

• Applied Chemistry for Engineering
• /
• v.25 no.6
• /
• pp.586-591
• /
• 2014

In this study, the diarylide compound pigment of high hiding power and vivid color was synthesized successfully by controlling several factors such as pH, coupler solution temperature, kind and addition amount of dispersion precursor, and crystallization temperature in the process of coupling synthesis. The properties of samples were measured by the means of FT-IR, UV-Vis spectroscopy, PSA, zeta potential, and turbiscan. It was found that the highly dispersive sample could be prepared by introducing the dispersive precursor.

• Journal of Microbiology and Biotechnology
• /
• v.17 no.2
• /
• pp.369-372
• /
• 2007

O-Methyltransferases (OMTs), one of the ubiquitous enzymes in plants, bacteria, and humans, catalyze a methyl-transfer reaction using S-adenosylmethionine and a wide range of phenolics as a methyl donor and acceptor, respectively. Substrates for most bacterial OMTs have largely remained elusive, but recent investigation using BcOMT2, an OMT from Bacillus cereus, suggested that ortho-dihydroxyflavonoids could serve as substrates. To elucidate the functional and structural features of BcOMT2, we expressed, and purified BcOMT2, and crystallized an apoenzyme and its ternary complex in the presence of a flavonoid and S-adenosylhomocysteine. Each crystal diffracted to $1.8{\AA}$ with its space group of C2 and $P2_{1}2_{1}2_{1}$, respectively. Structural analysis of apo-BcOMT2 and its ternary complex will provide the structural basis of methyl transfer onto (iso)flavonoids in a regiospecific manner.