• Applied Chemistry for Engineering
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• v.9 no.7
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• pp.1043-1046
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• 1998

Aluminium based inorganic flocculants are extensively used in this country in the removal of fine particles present in the raw water for the production of drinking water. These inorganic flocculants, however, have potential hazard of high residual aluminium ions in the treated waters, which is known to be one of the reasons of alzheimer's disease. Inorganic flocculants alone are sometimes incapable of treating water when there are excessive turbidity in the raw water sources due to flooding. A polyamine type polymeric flocculant has long been used to treat raw water in the drinking water production in the European countries and United State of America. The optimum reaction conditions such as mole ratio of epichlorohydrin(EPI) to dimethylamine(DMA), reaction temperature and time for each stage for the pilot scale preparation of polyamine from EPI-DMA was studied in this work. The variation of intrinsic viscosity and flocculating efficiency in the water treatment of the synthesized polyamines were evaluated. The residual materials after polymerization reaction were analyzed by gas chromatography to study the effect of variation of reaction conditions.

• Membrane Journal
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• v.19 no.2
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• pp.165-171
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• 2009

This study was for the evaluation of adaptability of the fiber filter as the pre-treatment of the RO membrane through SDI (Silt Density Index) measurement. The turbidity of raw waters were $0.76{\sim}1.6$ NTU for the effluent of sewer treatment plants (STP) and $2.2{\sim}3.3$ NTU for sea waters and 100 NTU for the surface water. The turbidity of the $2^{nd}$ filtrate of the serially connected two fiber filters was $0.07{\sim}0.25$ NTU and $SDI_{15}$ was $1.4{\sim}2.8$ when the 17% PAC was dosed $10{\sim}30ppm$. Results of the turbidity and $SDI_{15}$ of the $2^{nd}$ filtrate of the fiber filter which were compared with them of the lab scale MF/UF disc filter for the same STP's effluents showed that filtrate quality were enhanced with a little on the order of two stage fiber filter>MF>UF, the difference in $SDI_{15}$ was only $0.7{\sim}1.0$. So, the filtrate of the serially connected two stage fiber filter could satisfy $SDI_{15}$ 5.0 safely which was normally required for the feed water by the RO membrane supplier and it means the serially connected two stage fiber filter could be applied as the pre-treatment process of the RO membrane.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.2
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• pp.120-131
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• 2011

A pilot-scale experiment of floodplain filtration with a filtration depth of 3.6m was performed employing flood/rest type raw-water supply system in an effort to find ways to improve river water quality by additional treatments of discharged effluent from sewage treatment plant. Soil samples were taken from 3 sites including Gumi, Daegu and Gimhae along the Nakdong river. Reductions of infiltration rates following increases in operating time was investigated in each soil sample, along with the analysis of removal efficiencies of various pollutants according to different depths and infiltration rates. The results show incremental development of clogging on the soil surface with increases in operation time, and illustrate exponential decrease in the infiltration rate. The time required for the removal of the clog from the soil surface was longer than 2 weeks for all soil samples analyzed. The stable infiltration rates for soils were 5 m/day for Gumi and for Daegu and Gimhae was 1 m/day. In unsaturated soils dissolved oxygen levels increased following the increase of filtration depth, suggesting that alternating application of flood and rest for raw-water supply effectively keeps the soil environment aerobic. For all soils, the nature of pollutant removal depending on the depth of filtration remained the same regardless of the infiltration rate. Most of the BOD and turbidity were removed within 1.2 m, about 30% of COD was removed within 3.6m and was expected to be removed further with increases in filtration depth. Nitrification occurred near the surface of all soils; however there was no significant removal of nitrogen in the filtration depths tested in this study. Although removal rate of phosphorus was low for Gumi's soil, it was high enough for other soils, suggesting that the method developed in this study could significantly improve river water quality.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.3
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• pp.276-285
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• 2006

When polluted stream water was treated with biological aerated filter(BAF) in pilot plant, all operation with 90, 60, 45 and 30 min of EBCT at fixed $0.1m^3air/m^2min$ of aeration showed 80% or higher treatment efficiency of particle materials(SS, turbidity and Chl.-a) and 85% or higher efficiency of ammonia nitrogen removal. It was thought that, in case of BOD, biological stability may sufficiently be assured with BAF because grade III or IV inflow water was changed to grade I for outflow water. In case of $COD_{Mn}$, about 60% of removal efficiency was found. When the mechanism of the result was investigated, about 30% of COD materials was produced by algae clogged in the reactor. There was almost no biological decomposition because specific substrate utilization rate of algogenic organic materials were $0.0245mg{\cdot}COD_{Mn}/mg{\cdot}VSS{\cdot}day$, thus partial backwashing(washing the media in 1 m upper of the reactor once a day) was required. It is thought that elevation of removal rate about 10% of $COD_{Mn}$ and 5.5% of $BOD_5$ could be obtained with partial backwashing resulting in assurance of biologically more stable raw water and that saving backwashing water may be significant.

• Membrane and Water Treatment
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• v.6 no.1
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• pp.77-94
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• 2015

Ultrafiltration membranes have several advantages over conventional drinking-water treatment. However, this technology presents major limitations, such as irreversible fouling and low removal of natural organic matter. Fouling depends heavily on the raw-water quality as well as on the operating conditions of the process, including flux, permeate recovery, pre-treatment, chemical cleaning, and backwashing. Starting with the premise that the optimisation of operating variables can improve membrane performance, different experiments were conducted in a pilot plant located in Granada (Spain). Several combinations of permeate and backwashing flow rates, backwashing frequencies, and aeration flow rates were tested for low-quality water coming from Genil River with the following results: the effluent quality did not depend on the combination of operating conditions chosen; and the membrane was effective for the removal of microorganisms, turbidity and suspended solids but the yields for the removal of dissolved organic carbon were extremely low. In addition, the threshold transmembrane pressure (-0.7 bar) was reached within a few hours and it was difficult to recover due to the low efficiency of the chemical cleanings. Moreover, greater transmembrane pressure due to fouling also increased the energy consumption, and it was not possible to lower it without compromising the permeate recovery. Finally, the intensification of aeration contributed positively to lengthening the operation times but again raised energy consumption. In light of these findings, the feasibility of ultrafiltration as a single treatment is questioned for low-quality influents.

• Journal of Korean Society of Water and Wastewater
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• v.31 no.6
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• pp.501-510
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• 2017

In this study, it is estimated that ceramic membrane process which can operate stably in harsh conditions replacing existing organic membrane connected with coagulation, sedimentation etc.. Jar-test was conducted by using artificial raw water containing kaolin and humic acid. It was observed that coagulant (A-PAC, 10.6%) 4mg/l is the optimal dose. As a results of evaluation of membrane single filtration process (A), coagulation-membrane filtration process (B) and coagulation-sedimentation-membrane filtration process (C), TMP variation is stable regardless of in Flux $2m^3/m^2{\cdot}day$. But in Flux $5m^3/m^2{\cdot}day$, it show change of 1-89.3 kpa by process. TMP of process (B) and (C) is increased 11.8, 0.6 kpa each. But, the (A) showed the greatest change of TMP. When evaluate (A) and (C) in Flux $10m^3/m^2{\cdot}day$, TMP of (A) stopped operation being exceeded 120 kpa in 20 minutes. On the other hand, TMP of (C) is increased only 3 kpa in 120 minutes. Through this, membrane filtration process can be operated stably by using the linkage between the pretreatment process and the ceramic membrane filtration process. Turbidity of treated water remained under 0.1 NTU regardless of flux condition and DOC and $UV_{254}$ showed a removal rate of 65-85%, 95% more each at process connected with pretreatment. Physical cleaning was carried out using water and air of 500kpa to show the recovery of pollutants formed on membrane surface by filtration. In (A) process, TMP has increased rapidly and decreased the recovery by physical cleaning as the flux rises. This means that contamination on membrane surface is irreversible fouling difficult to recover by using physical cleaning. Process (B) and (C) are observed high recovery rate of 60% more in high flux and especially recovery rate of process (B) is the highest at 95.8%. This can be judged that the coagulation flocs in the raw water formed cake layer with irreversible fouling and are favorable to physical cleaning. As a result of estimation, observe that ceramic membrane filtration connected with pretreatment improves efficiency of filtration and recovery rate of physical cleaning. And ceramic membrane which is possible to operate in the higher flux than organic membrane can be reduce the area of water purification facilities and secure a stable quantity of water by connecting the ceramic membrane with pretreatment process.

• Journal of Environmental Science International
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• v.8 no.3
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• pp.363-369
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• 1999

This study aimed to elucidate the relationship between theoretical parameters affecting the coagulation process and the real coagulation phenomenon applied to the dye wastewater. Emphasis was placed on the effective removal of the suspend particulates. Parameters studied in this study are pH, coagulant concentration and surface potential. Optimal dosages of coagulants by the measurement of the zeta potential at lower then $25^{\circ}C$ are 5\times$10^P-3}$ M of $FeCl_3 and 1.4\times10^{-6}M of Fe_2(SO_4)_3$. The results were well agreeded with the separate Jar-test results. Emphasis was also placed on the relationship between water quality and the content of SS. It was found that the COD and DOC were reduced to 65% and 85%, respectively. The turbidity at the above condition was reduced from 300 NTU to 0~1 NTU. Efforts were made to clarify the behavior of the suspend solid as affecting the water quality. 12,000~13,000 particles/10mL in $1~50\mu$m size range particulates in the raw wastewater were reduced to 300 particle/10mL in the same range after treatment. This research has proposed the methodology to find out the optimal condition of coagulation for small scale wastewater treatment plant or chemical coagulation process.

• Journal of Korean Society of Water and Wastewater
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• v.24 no.4
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• pp.463-474
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• 2010

In this study, chemical coagulation conditions for treating combined sewer overflow(CSO) occurred during rainy season were evaluated by jar tests with aluminum sulfate[$Al_2(SO_4)_3{\cdot}17H_2O$] and ferric chloride[$FeCl_3{\cdot}6H_2O$]. The raw domestic sewage sampled from the primary sedimentation tank at a local sewage treatment plant was filtered through $150{\mu}m$ sieve before using. Point of zero charge(PZC) for various dose of aluminum sulfate occurred at pH 5.8-6.5, while for ferric chloride occurred at pH 5.3-6.0 in term of streaming current(SC) values. Charge neutralization ability of aluminum sulfate was bigger than that of ferric chloride. Optimum pH and dose of aluminum sulfate and ferric chloride were 6.2, 0.438mM and 5.8, 0.925mM, respectively. Removal efficiencies of TCOD, turbidity, SS and TP were 75, 97, 95, 96% with aluminum sulfate and 74, 96, 98, 99% with ferric chloride at their optimum coagulation conditions. More efficient removal of SS, TP and small particles was possible with ferric chloride at optimum coagulation conditions. Both SC values and COD removal started to increase where soluble phosphorus was completely removed.

• Environmental Engineering Research
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• v.22 no.2
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• pp.203-209
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• 2017

Innovations in the biofiltration process can provide effective solutions to overcome crucial water pollution problems. The elimination of pollutants is a result of the combined effects of biological oxidation, adsorption and filtration processes. This research aims to evaluate the performance of quartz sand biofiltration for removing total suspended solids, turbidity, color, organic matter, and ammonium from polluted river water and develop an empirical model for designing quartz sand biofilters for the treatment of polluted river water. Experiments were conducted using two biofilter units filled with quartz sand as filter media. A set of experiments were performed to evaluate the effect of hydraulic retention time on biofilter performance in removing water contaminants. The kinetics of organic matter removal were also determined to describe the performance of the biofilter. The results show that biofiltration can significantly remove river water pollutants. Removal efficiency depends on the applied hydraulic retention time. At a hydraulic retention time of two hours, removal efficiencies of total organics, ammonium and total suspended solids were up to 78%, 82%, and 91%, respectively. A model for designing quartz sand biofiltration has been developed from the experimental data.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.12
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• pp.883-888
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• 2013

Coagulation and sedimentation tests were conducted with clay and three different coagulants of soil origin (AC-A, AC-B, AC-C) to determine optimal coagulant types and doses to remove algae in stagnant water bodies such as reservoirs. Raw water had an algal density of 2,950 cells/mL and was dominated by Cyanobacteria. Removal rates of algal density by clay (50 mg/L) were 49% and 85% after 10 and 30 minutes sedimentation, respectively. Other natural coagulants achieved 80-90% removal in 10 minutes and 89-94% removal in 30 minutes of sedimentation after adding 20 mg/L each. AC-A was the optimal coagulant from this study considering algal removal rates and other water quality parameters such as turbidity and pH. For the same removal rates of algae, raw waters with higher algal densities required higher coagulant doses although no strong corelation was observed. The coagulants of soil origin did not impact orgnic contents and pH of raw water, but remove phosphate up to 70%.