• The Journal of Engineering Geology
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• v.22 no.3
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• pp.253-262
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• 2012

With the aim of remediating soils contaminated by heavy metals and oil, experimental research was conducted to evaluate the optimal design factors for remediation in terms of efficient soil washing methods and processes. The experiments employed absorptiometric analysis and gas chromatography methods to reduce the concentration of heavy metals such as cooper (Cu), lead (Pb), and zinc (Zn), and total petroleum hydrocarbons (TPH) in contaminated soils. The experimental processes consisted of deciding on the washing solution, washing time, and dilution ratio for contaminated soils. A dissolution analysis of heavy metals was then performed by the addition of surfactant, based on the results of the decision experiments, and the injection processes of microbes and hydrogen peroxide were selected. The experimental results revealed that reduction effects in contaminated soils under the experimental conditions were most efficient with hydrochloric acid 0.1 mole, washing time 1 hour, and dilution ratio 1:3, individually. Additional reduction effects for heavy metals and TPH were found with the addition of a washing solution of 1% of surfactant. The addition of microbes and hydrogen peroxide caused a reduction in TPH concentration.

• Journal of the Korean Wood Science and Technology
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• v.38 no.4
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• pp.316-322
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• 2010

The research attempted to develop a wood adhesive based on waste cooking oil, using ozonification technology for the chemical structure modification. The waste cooking oil (WCO) was reacted with $O_3$ for different times; 1 h, 2 h, and 3 h. The chemical structure modifications of the ozonized WCOs were examined by Fourier transform Infrared (FT-IR) spectrum. The FT-IR spectrum of WCO had an absorbance peak at 3,010 $cm^{-1}$ that was the characteristic peak of the unsaturated double bonds. As ozone treatment time increased, the peak of the double bond was disappeared and carboxyl peak appeared at 1,700 $cm^{-1}$. Especially, the double bond of 3 hrs-ozonized WCO was vanished almost. In results of the dry bonding strengths of the 3 hrs-ozonized WCO mixed with polymeric methylene diphenyl diisocyanate (pMDI) were the strengths of weight ratio of 3hrs-ozonized WCO : pMDI, 1 : 0.5, 8.08 kgf/$cm^2$, 1 : 0.75, 9.53 kgf/$cm^2$ 1 : 1, 44.16 kgf/$cm^2$, 1 : 2, 58.08 kgf/$cm^2$, 1 : 3, 61.41 kgf/$cm^2$, and 1 : 4, 46.95 kgf/$cm^2$. Therefore, it was found that the optimum equivalent ratio was formed at the ratio of 1 : 2 or 1 : 3. Under wetting the bonding strength of 1 : 3 ratio was appeared higher than that of 1 : 2 ratio, while the results obtained from hot-water and cyclic boiling shear test were similar.

• Geomechanics and Engineering
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• v.20 no.6
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• pp.537-546
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• 2020

Oil and natural gas reserves have been recognised abundantly in clayey rich rock formations in deep costal reservoirs. It is necessary to understand the sedimentary history of those reservoir rocks to well explore these natural resources. This work designs a group of laboratory experiments to mimic the physical process of the sedimentary clay-rich rock formation. It presents characterisation results of the physical properties of the artificial clayey rocks synthesized from illite clay, quartz sand and brine water by high-pressure consolidation tests. Special focus is given on the effects of illite clay content and high-stress consolidation on the physical properties. Multi-step loaded consolidation experiments were carried out with stress up to 35 MPa on mixtures constituting of the illite clay, quartz sand and brine water with five initial illite clay contents (w=85%, 70%, 55%, 40% and 25%). Compressibility and void ratio were characterised throughout the physical compaction process of the mixtures constituting of five illite clay contents and their water permeability was measured as well. Results show that the applied stress induces a great reduction of clayey rock void ratio. Illite clay contents has a significant influence on the compressibility, void ratio and the permeability of the physically synthesized clayey rocks. There is a critical illite clay content w=70% that induces the minimum void ratio in the physically synthesised clayey rocks. The SEM study indicates, in the high-pressure synthesised clayey rocks with high illite clay contents, the illite clay minerals are located in layers and serve as the material matrix, and the quartz minerals fill in the inter-mineral pores or are embedded in the illite clay matrix. The arrangements of the minerals in microscale originate the structural anisotropy of the high-pressure synthesised clayey rock. The test findings can give an intuitive physical understanding of the deep-buried clayey rock basins in energy reservoirs.

• Journal of Microbiology and Biotechnology
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• v.34 no.2
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• pp.330-339
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• 2024

Corn cobs were fermented with Aspergillus niger to produce soluble dietary fiber (SDF) of high quality and excellent food safety. In this work, the fermentation process was optimized by single-factor test and response surface methodology (RSM). The optimal fermentation conditions were determined to be a material-liquid ratio of 1:30, an inoculum concentration of 11%, a temperature of 32℃, a time of 6 days, and a shaking speed of 200 r/min. Under these conditions, the SDF yield of corn cob increased from 2.34% to 11.92%, and the ratio of soluble dietary fiber to total dietary fiber (SDF/TDF) reached 19.08%, meeting the requirements for high-quality dietary fiber (SDF/TDF of more than 10%). Scanning electron microscopy (SEM) and Fourier-transformed infrared spectroscopy (FT-IR) analysis revealed that the fermentation effectively degraded part of cellulose and hemicellulose, resulting in the formation of a loose and porous structure. After fermentation the water swelling capacity, water-holding capacity, and oil-holding capacity of the corn cob SDF were significantly improved and the adsorption capacity of glucose, cholesterol, and nitrite ions all increased by more than 20%. Moreover, the total phenolic content increased by 20.96%, which correlated with the higher antioxidant activity of SDF. Overall, the fermentation of corn cobs by A. niger increased the yield and enhanced the functional properties of dietary fiber (DF) as well.

• Economic and Environmental Geology
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• v.46 no.1
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• pp.51-61
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• 2013

Researches on the oil recovery enhancement using the nanotechnology has recently been studied in the United States. The previous researches has focused mainly on the flow characteristics of nanoparticles in porous media, and the stability of the nano-emulsion itself. However, the analysis did not deal with the size effects between a nano-emulsion and the pore size which has an important role when nano-emulsion flows in the porous media. In this research, nano-based emulsion was fabricated which is able to be applied for the enhanced oil recovery techniques and its characteristics was analyzed. In addition, in order to identify the characteristics of nano-emulsions flowing through the porous media, the size effect was analysed by filtering test. According to the results, when the emulsion was fabricated, SCA(Silane Coupling Agent) or PVA(Poly Vinyl Alcohol) are added to improve the stability of emulsion. As the ratio of the decane to water increased, the viscosity of emulsion and the droplet size also increased. For the filtering test at the atmospheric conditions, the droplet did not go through the filter; only the separated water from the emulsion was able to be filtered. This phenomenon occurred because the droplet was not able to overcome the capillary pressure. At the filtering test by suction pressure, most of the emulsion was filtered over the filter size of $60{\mu}m$. However, the ratio of filtration was rapidly degraded at less than $45{\mu}m$ filters. This is caused due to deformation and destruction of the droplet by strong shear stress when passing through the pore. The results from the study on the basic characteristic of nano-emulsion and filtering test will be expected to play as the important role for the fabrication of the stable nano-emulsion or the research on the recovery of residual oil in porous media.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.18 no.5
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• pp.1390-1411
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• 2024

Underwater Wireless Sensors Networks (UWSNs) are deployed in remotely monitored environment such as water level monitoring, ocean current identification, oil detection, habitat monitoring and numerous military applications. Providing scalable and efficient routing is very challenging in UWSNs due to the harsh underwater environment. The biggest difficulties are the nodes inherent movement due to water current, long delay in data transmission, low bandwidth of the acoustic signal, high error rate and energy scarcity in battery powered nodes. Many routing protocols have been proposed to solve the aforementioned problems. There are three broad categories of routing protocols namely depth based, energy based and vector-based routing. Vector Based Forwarding protocols perform routing through virtual pipeline by defining their radius which give proper direction to packets communication. We proposed a routing protocol termed as Path-Oriented Energy Scaled Expanded Vector Based Forwarding (PESEVBF). PESEVBF takes into account all parameters; holding time, the source nodes packets routing path and void holes creation on the second hop; PESEVBF not only considers the packet upward advancement but also focus on density of the forwarded nodes in terms of number of potential forwarding and suppressed nodes for path selection. Node selection in resultant holding time is based on minimum Path Factor (PF) value. Moreover, the suppressed node will be selected for packet forwarding to avoid the void holes occurrences on the second hop. Performance of PESEVBF is compared with other routing protocols using matrices such as energy consumption, packet delivery ratio, packets dropping ratio and duplicate packets creation indicating considerable performance improvement.

• Journal of Conservation Science
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• v.31 no.4
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• pp.457-476
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• 2015

This study is expected to present instructions and analysis of Modern Dancheong pigments by its physical characteristics. Search pigments currently used and experiments proper mixing ratio of Jangdanyuksaek(Incarnadine). Samples are made by based on presented a mixture ratio which is less exfoliation, cracks and color change. And put into accelerated weathering test and ultraviolet ray degradation test. As a result in case of Jidang($TiO_2$) Rutile type is superior in discoloration and durability. Rutile type makes color difference remarkably because of oil absorption difference while mixing with Jangdan. Water paints which are used as a alternative present yellowness which means water paints lack in durability. whiting should be taken carefully as it has high brightness after degradation.

• Korean Journal of Food Science and Technology
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• v.35 no.3
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• pp.423-428
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• 2003

Stabilities of W/O emulsions containing eugenolchitosan (EuCs) prepared from chitosan and eugenol were compared to determine the optimal conditions for the ratio of water (core phase) to corn oil (continuous phase), the concentration of EuCs, storage temperature, and the extent of homo-mixing. The optimal ratio of water to corn oil was 2:3 (w/w). The effects of EuC concentrations, and singular vs. binary system of emulsifiers on the storage stability of the emulsion were investigated with EuCs and polyoxyethylene sorbitan monolaurate. The emulsion was stable, showing more than 95% emulsion stability index (ESI) value, when the concentration of EuCs was more than 0.18% (w/v). ESI value of binary emulsifier system was almost equal to that of singular emulsifier system at the concentration of 0.18% (w/v). At this singular emulsifier system, the W/O emulsion formed by EuCs had ESI value of 100%. The optimal concentration of EuCs was determined as 0.18% (w/v). The highest stability of the emulsion was obtained from the homo-mixing at 11,000 rpm for 10 sec and the storage temperature ranging $25{\sim}65^{\circ}C$. EuCs produced from this study was mutagenecity-negative on Ames test and contained no heavy metal ions.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.39 no.9
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• pp.909-916
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• 2015

In this study, to investigate the effect of spray behavior characteristics, we induce the mixing ratio of emulsified fuel using impinging spray. We formulate the emulsified fuel by mixing diesel and hydrogen peroxide($H_2O_2$). We set the temperature of the heating plate to $150^{\circ}C$, $200^{\circ}C$, and $250^{\circ}C$, and set the injection pressures to 400, 600, 800, and 1000bar. The surfactants for the emulsified fuel mixture, which were mixed span80 and tween80 was mixed as 9:1, were fixed to 3% of the total volume of the emulsified fuel. We set the mixing ratio of $H_2O_2$ in the emulsified fuel as emulsified fuel(EF)0, EF2, EF12, and EF22. Further, we visualize the evaporation impinging spray using the Schlieren method. Based on the results of this study, we found that a higher temperature and injection pressure of the heating plate impingement led to the active diffusion of the fuel vapor, which promoted emulsified fuel evaporation. When the emulsified fuel is utilized in an actual engine, because of the temperature-drop effect of the combustion chamber, which is due to the evaporation of $H_2O_2$ in fuel and faster mixture formation is expected to decrease the engine emissions.

• Economic and Environmental Geology
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• v.47 no.6
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• pp.625-633
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• 2014

The Aquistore project is the world's first commercial capture, transportation, utilization and storage project of post-combustion $CO_2$ from a coal-fired thermo electric power plant, and the proposed storage is a saline aquifer at a depth of about 3,500 m. Deep saline aquifer, compared to hydrocarbon reservoir, provides the great volumetric potential for storage of $CO_2$ anywhere in the world, therefore the research results from the project may be exported globally to other sites. Geological $CO_2$ storage characterization for saline aquifer instead of hydrocarbon reservoir needs to estimate the geophysical properties of subsurface geology. This study calculated the geophysical property of water-saturated formation by applying amplitude variation analysis developed from oil and gas exploration. We correlated horizon tops at the well logs to seismic traveltime of 1,815 and 1,857 ms as Winnipeg and Deadwood formations. Gradient analysis from seismic traces showed correlation coefficient of 45 - 81 % on amplitude variation with respect to incident angle. Crossplot of intercept and gradient shows the inverse proportional trend which represents typical water saturated sediments. Product attribute of intercept and gradient described the base of wet sediment. Poisson's ratio change attribute increased at the top of target area satisfying with wet sediment and decreased at the top of basement in a dry rock bed.