• Title/Summary/Keyword: Ratio of oil/water

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Multi-Component Relaxation Study of Human Brain Using Relaxographic Analysis (Relaxographic 분석법을 이용한 뇌의 다중 자기이완특성에 관한 연구)

  • Yongmin Chang;Bong Soo Han;Bong Seok Kang;Kyungnyeo Jeon;Kyungsoo Bae;Yong-Sun Kim;Duk-Sik Kang
    • Investigative Magnetic Resonance Imaging
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    • v.6 no.2
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    • pp.120-128
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    • 2002
  • Purpose : To demonstrate that the relaxographic method provides additional information such as the distribution of relaxation times and water content which are poentially applicable to clinical medicine. Materials and Methods : First, the computer simulation was performed with the generated relaxation data to verify the accuracy and reliabilility of the relaxographic method (CONTINI). Secondly, in or der to see how well the CONTIN quantifies and resolves the two different ${T_1}$ environments, we calculated the oil to water peak area ratios and identified peak positions of ${T_1}-distribution$ curve of the phantom solutions, which consist of four centrifugal tubes (10 ml) filled with the compounds of 0, 10, 20, 30% of corn oil and distilled water, using CONTIN. Finally, inversion recovery MR images for a volunteer are acquired for each TI ranged from 40 to 1160 msec with TR/TE=2200/20 msec. From the 3 different ROIs (GM, WM, CSF), CONTIN analysis was performed to obtain the ${T_1}$-distribution curves, which gave peak positions and peak area of each ROI location. Results : The simulation result shows that the errors of peak positions were less in the higher peak (centered ${T_1}=600$ msec) than in the lower peak (centered ${T_1}=150$ msec) for all SNR but the errors of peak areas were larger in the higher peak than in the lower peak. The CONTIN analysis of the measured relaxation data of phantoms revealed two peaks between 20 and 60 msec and between 500 and 700 msec. The analysis gives the peak area ratio as oil 10%: oil 20%: oil 30% = 1:1.3:1.9, which is different from the exact ratio, 1:2:3. For human brain, in ROI 3 (CSF), only one component of -distributions was observed whereas in ROI 1(GM) and in ROI 2 (WM) we observed two components of ${T_1}-distribution$. For the WM and CSF there was great agreement between the observed ${T_1}-relaxation$ times and the reported values. Conclusion : we demonstrated that the relaxographic method provided additional information such as the distribution of relaxation times and water content, which were not available in the routine relaxometry and ${T_1}/{T_2}$ mapping techniques. In addition, these additional information provided by relaxographic analysis may have clinical importance.

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Numerical Study on the Evaporation Characteristics of Biocrude-oil Produced by Fast Pyrolysis (급속열분해를 통하여 생산된 바이오오일 액적의 증발 특성에 관한 수치해석적 연구)

  • Choi, Sang Kyu;Choi, Yeon Seok;Kim, Seock Joon;Han, So Young
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.646-652
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    • 2016
  • Biomass is regarded as one of the promising energy sources to deal with the depletion of fossil fuels and the global warming issue. Biocrude-oil can be produced through the fast pyrolysis of biomass feedstocks such as wood, crops, agricultural and forestry residues. It has significantly higher viscosity than that of conventional petroleum fuel and contains solid residues, which can lower the spray and atomization characteristics when applied to the burner. In addition, biocrude-oil consists of hundreds of chemical species derived from cellulose, hemicellulose and lignin, and evaporation characteristics of the biocrude-oil droplet are distinct from the conventional fuels. In the present study, a numerical study was performed to investigate the evaporation characteristics of biocrude-oil droplet using a simplified composition of the model biocrude-oil which consists of acetic acid, levoglucosan, phenol, and water. The evaporation characteristics of droplets were compared at various surrounding air temperatures, initial droplet diameters, and ethanol mixing ratios. The evaporation time becomes shorter with increasing air temperature, and it is much sensitive to the air temperature particularly in low temperature ranges. It was also found that the biocrude-oil droplet evaporates faster in cases of the smaller initial droplet diameter and larger ethanol mixing ratio.

Preparation of $SiO_2-TiO_2$ Porous Composite Pigments Using a Pickering Emulsion Method as Template (피커링 에멀젼을 형판으로 하는 $SiO_2-TiO_2$ 다공성 분체의 제조)

  • Lee, Sang-Gil;Kim, Young-Ho;Hong, Jun-Ki;Pyo, Hyeong-Bae;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.3
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    • pp.377-392
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    • 2012
  • It has been known that small solid particles act as a stabilizer in pickering emulsion system. In this study, we successfully prepared stable pickering emulsion in n-hexylalcohol and water system with $TiO_2$ whose surface was treated by alkylsilane. The optimum condition to prepare pickering emulsion stabilized by $TiO_2$ particles was determined by amount of $TiO_2$ particles and ratio of water and oil phase. The type of pickering emulsion was dependent on wettability of particles for water and n-hexylalcohol. When the amount of $TiO_2$ particles increased up to 5.00 wt%, the stability of pickering emulsion was showed to be improved. The most stable pickering emulsion was prepared in the case of W/O type which has the ratio of oil and water phase (3 : 7). We tried to prepare porous $SiO_2-TiO_2$ composite pigments using a pickering emulsion as template at the optimal condition. Porous pigments were synthesized with Ludox HS-30 as an inorganic material by sol-gel process. The characteristics and shape of porous pigments were measured by optical microscope, SEM, BET, XRD and EDS.

Effects of Fatty Acids and Vitamin E Supplementation on Behavioral Development of the Second Generation Rat

  • Hwang, Hye-Jin;Um, Young-Sook;Chung, Eun-Jung;Kim, Soo-Yeon;Park, Jung-Hwa;Lee, Yang-Cha-Kim
    • Preventive Nutrition and Food Science
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    • v.7 no.3
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    • pp.265-272
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    • 2002
  • In this study, we examined the effects of dietary fatty acids on the fatty acid composition of phospholipid fractions in regions of the brain and on behavioral development in rats. The Sprague Dawley rats were fed the experimental diets 3~4 wks prior to the conception. Experimental diets consisted of 10% fat(wt/wt) which were from either safflower oil (SO, poor in $\omega$3 fatty acids), mixed oil MO, P/M/S ratio : 1:1.4:1, $\omega$6/$\omega$3 ratio = 6.3), or mixed oil supplemented with vitamin E (+500 mg/kg diet). At 3 and 9 weeks of age, frontal cortex (FC), corpus striatum (CS), hippocampus (H), and cerebellum (CB) were dissected from the whole brain. The fatty acid content was determined in the different phospholipid fractions: phosphatidylcholine (PC), phosphatidyl-serine (PS), and phosphatidylethanolamine (PE) in the rat brain regions. In the visual discrimination test, the order of the cumulative errors made in Y-water maze test were SO > MO > ME. This suggested that the balanced diet supplemented with vitamin I had the most beneficial effect on learning ability. The overall characteristics of correlation between fatty acids and behavior development were that the frequency of cumulative errors were negatively correlated significantly with monounsaturated fatty acids (MUFAs), ie., 18:1 $\omega$9 and 22:1 $\omega$9. Docosa-hexaenoic acid (22:6 $\omega$3) of PS in frontal cortex (FC) was negatively correlated with the number of errors made in the Y-water maze test.22:5 $\omega$6 PS in hippocampus (H), PC and PE in corpus striatum (CS), PC in cerebellum (CB) were positively correlated with cumulative errors. And these errors were negatively correlated with 20:4 $\omega$ 6 of PE in corpus striatum (CS) and PC in cerebellum (CB). Especially, O1eic acid (18:1 u 9) in all phospholipid fractions (PC, PS, PE) of hippocampus was negatively correlated with the number of errors. These findings demonstrate that the MUFAs were might be essential for proper brain development, especially in hippocampus which is generally thought to be the regions of memory and learning.

In-situ Rock Stress Measurement at the Water Tunnel Sites in the OO Oil Storage Facility with Hydraulic Fracturing Method (수압파쇄법을 이용한 OO 원유비축시설 내 수벽 터널에서의 초기응력 측정)

  • Bae, Seong-Ho;Kim, Jae-Min;Kim, Jang-Soon;Lee, Young-Ho
    • Tunnel and Underground Space
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    • v.18 no.1
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    • pp.80-89
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    • 2008
  • The influence of in-situ rock stress on the stability of an underground rock structure increases as the construction depth become deeper and the scale of a rock structure become larger. In general, hydraulic fracturing stress measurement has been performed in the surface boreholes of the target area at the design stage of an underground structure. However, for some areas where the high horizontal stresses were observed or where the overstressed conditions caused by topographical and geological factors are expected, it is desirable to conduct additional in-situ stress measurement in the underground construction site to obtain more detailed stress information for ensuring the stability of a rock structure and the propriety of current design. The study area was a construction site for the additional underground oil storage facility located in the south-east part of OO city, Jeollanam-do. Previous detailed site investigation prior to the design of underground structures revealed that the excessive horizontal stress field with the horizontal stress ratio(K) greater than 3.0 was observed in the construction area. In this study, a total of 13 hydraulic fracturing stress measurements was conducted in two boreholes drill from the two water tunnel sites in the study area. The investigation zone was from 180 m to 300 m in depth from the surface and all of the fracture tracing works were carried out by acoustic televiewer scanning. For some testing intervals at more than 200 m ind depth from surface, the high horizontal stress components the horizontal stress ratio(K) greater than 2.50 were observed. And the overall investigation results showed a good agreement with the previously performed test.

Synthesis of $LiMn_2O_4$ Cathode Materials by Emulsion Method and Its Electrochemical Properties

  • Youn Kyu Choi;Bok Hee Kim
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.250-254
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    • 1999
  • Synthesis of the spinel $LiMn_2O_4$ by emulsion method was investigated. $LiOH.H_2O \;and \;Mn(NO_3)_2.6H_2O$ were used as starting materials to prepare mixed aqueous solution (0.5 mol/$\ell$ for the $LiMn_2O_4$). Kerosene, paraffin oil and span 80 were used for organic phase. The aqueous solutioin and organic phase were mixed in the ratio of 2:1 and emulsified at the speed of 4000 rpm for 5 min. The prepared emulsions were dropped into the petroleum heated at $170^{\circ}C$ to evaporate water in the silicon oil bath, dried at $120^{\circ}C$ in the oven the remove petroleum and calcined at temperature ranges from 600 to $900^{\circ}C$ for 48 hrs. The characteristics of powders were investigated by XRD, SEM, BET and electrochemical properties of synthesized cathode materials were measured with Galvanostatic system. $Li_{1.05}Mn_2O_4$ calcined at $800^{\circ}C$ for 48 hrs showed initial discharge capacity of 125.9mAH/g.

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A Study on The Reduction of Fuel Oil Consumption for Fishing Boat Engine (어선기관의 연료유 절감에 관한 연구)

  • 이창호
    • Journal of Advanced Marine Engineering and Technology
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    • v.5 no.1
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    • pp.12-19
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    • 1981
  • As the fuel oil cost covers from 45% to 60% of the total expenditure for fishing boat operation, the energy saving is now an urgent problem to be taken a countermeasure for engineers, manufacturers or specialists engaging in this field. Undertaking a second-hand engine of the trainging ship, the author made several reconstructions to restore its performances. By inserting foot linears of connecting rods the compression ratio was increased and by adjusting both the fuel injection timing and the cooling water outlet temperature, its thermal efficiency was improved. The results of the experimental operation were summarized as follows. 1. By raising the piston top position 0.75mm more than the value of the operating manual, the compression pressure increased 1.3 kg/$cm^2$ and the maximum pressure did 3.4 kg/$cm^2$ at 75% load. 2. At 75% load, the difference of the maximum pressure between each cylinder was decreased from 2.4 kg/$cm^2$ to 1.8 kg/$cm^2$. 3. The fuel consumption was decreased about 8 g/ps.h at 75% load, and about 5.3 g/ps.h at 85% load. 4. The brake thermal efficiency was improved about 1.5% at 75% load and 0.9% at 85% load.

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A Study on The Effect of Dampening Conductivity in the Offset Printing Printability (오프셋인쇄 축임물의 전도도가 인쇄적성에 미치는 영향에 관한 연구)

  • Park, Chan-Woo;Lee, Jae-Soo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.25 no.1
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    • pp.43-52
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    • 2007
  • Offset printing is one of the well known printing technique of lithographic process and consists of image area and 'non-image area on a flat image carrier. The surface tension of dampening water can be controlled by adding IPA after mixing of raw water and etching solution. The etching solution contains a surfactant for reducing surface energy, a clean agent for non-imaging area, wetting agent for protecting non-imaging area from oil components like ink and also an emulsifying agent for controlling emulsification. In this study, the present situation of dampening water maintenance has examined by collecting dampening water using at domestic companies. The pH related to dampening water, conductivity, contact angle, emulsification curve are measured to define the current situation of dampening water control of each companies and to analyze the relationship among measured properties. In the study most of companies among 16 printing companies tested controlling dampening water through pH value. However, the quality of printing has varied depending upon conductivity, contact angle, IPA content, and emulsification value. The control of dampening water should be carry at the state of the standard when adding proper ratio of etching solution. It would be more effective when pH or conductivity control carries out in parallel with controlling dampening water. Therefore the concept that pH5.5 is correct is based concept. Based on these initial tests it is defined that the standardization of dampening water control is required.

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Effects of Dietary $\omega3$ and $\omega6$ Fatty Acids on the Fatty Acid Composition of RBC and Brain Synaptosomal, Microsomal and mitochondrial Phospholipids and on Behavioral Development of Rats (식이 $\omega3$$\omega6$계 지방산 조성이 제 2세대 쥐의 RBC과 뇌조직 Synaptosome, Microsome 및 Mitochondria의 인지질 및 행동발달에 미치는 영향)

  • 엄영숙
    • Journal of Nutrition and Health
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    • v.29 no.8
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    • pp.849-860
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    • 1996
  • The supply of different fatty acids during the development period has significant effects. This study examined the effects of dietary $\omega$3 and $\omega$6 fatty acid compositions on phospholipids (PLs) of RBC and rat brain subcellular fractions (synaptosome, microsome, mitochondria), and on learning ability of the 2nd generation rat. Rats were fed experimental diets 3-4 wks prior to the conception. Early in the lactation period, the feeding mothers were exchanged. Diets consisted of 10% fat(by weight), which was either safflower oil('S') poor in $\omega$3 fatty acids or computer-searched mixed oil('M') with P/M/S ratio, 1/1.4/1 and $\omega$6/$\omega$3 ratio, 6.1/1. The 'S' and 'M' rats were subdivided further into SS, SM, MS & MM rats according to their lactation stauts. At 3 (weaning) & 9 wks of age, the percentage of total $\omega$3 fatty acids to their lactation status. At 3 (weaning) & 9 wks of age, the percentage of total $\omega$3 fatty acids and the ratios of $\omega$3/$\omega$6 fatty acids in PLs of RBC and brain subcellular fractions in SM and MM groups fed milk from the mixed oil-fed mothers for 2 wks tended to be higher than those in SS and MS groups respectively. In contrast, the concentrations of $\omega$6 fatty acids, especially 22:5$\omega$6 in all fractions, were significantly lower in the SM & MM groups compared to those of the SS & MS groups respectively. In contrast, the concentration of $\omega$6 fatty acids, especially 22:5$\omega$6 in all fractions, were significantly lower in the SM & MM groups compared to those of the SS & MS groups, The values for the DHA$\omega$3/22:5$\omega$6 ratios after the lactation period were markedly higher in the groups (SM & MM) which were reared by mixed oil(MO) fed mothers. In carring out Y-water maze at 9th wk of age, the SM(4.2$\pm$0.5) & MM (5.3$\pm$0.5) groups made significantly less errors compared to the SS(6.2$\pm$0.6, p<0.05 compared with SM) & MM (7.2$\pm$0.5, p<0.05 compared with MM) groups which were lactated by the safflower oilfed mothers. Therefore, by feeding a balanced fatty acid diet from the lactation period up to 9 wks of age as compared with the groups fed $\omega$3 fatty acid-deficient diet regardless of mother's diet given before parturition. The levels of DHA(synaptosome) and 22:5$\omega$3 (mitochondria) were positively correlated not only with these values in RBC but also with visual discriminating ability. The levels of DHA and 22:5$\omega$3 in RBC can, therfore, reflect visual discriminatng ability in the rat.

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Enzymatic reaction model for the production of symmetrical lipid molecules using the response surface methodology

  • Hong, Joon-Sun;Shin, Jung-Ah;Lee, Ki-Teak
    • Korean Journal of Agricultural Science
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    • v.45 no.2
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    • pp.265-282
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    • 2018
  • The purpose of this research was to produce symmetric (Saturated-Unsaturated-Saturated, SUS) triacylglycerol (TAG) using palm stearin fraction oil (PSFO) and high oleic sunflower oil (HOSO) as substrates to replace cocoa butter. PSFO was blended with HOSO (1 : 2 weight ratio), and $lipozyme^{(R)}$ TLIM (20 weight % of the substrate) was added. Interesterification was carried out in a shaking water bath at $55^{\circ}C$ at 220 rpm for 6 hours. The response surface methodology (RSM) through the central composite face design was employed to observe the optimized SUS-TAG. The independent factors were the reaction temperature ($X_1$: 65, 75 and $85^{\circ}C$), reaction time ($X_2$: 1, 3 and 5 hours) and ratio of TLIM ($X_3$: 10, 15 and 20 weight %). The dependent variables were $Y_1$ = Saturated-Unsaturated-Unsaturated (SUU, area %), $Y_2=SUS$ (area %), $Y_3$ = Saturated-Saturated-Unsaturated (SSU, area %), $Y_4$ = Unsaturated-Unsaturated-Unsaturated (UUU, area %), and $Y_5=sn-2$ unsaturated fatty acid (area %). The optimal conditions from the central composite face design minimized acyl migration while maximizing the presence of unsaturated fatty acid at the sn-2 position (73.43 area %). The optimal conditions were $X_1=65^{\circ}C$, $X_2=1hour$, and $X_3=20weight%$. As a result of the response surface analysis, the lack of fits was found as $Y_1=0.622$, $Y_2=0.438$, $Y_3=0.264$, $Y_4=0.526$, and $Y_5=0.215$, and their $R^2$ were 0.897, 0.944, 0.826, 0.857, and 0.867, respectively.