• 제목/요약/키워드: Rate Law

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금속티타늄분말의 질화반응과 산화반응에 관한 연구 (A Study on Nitridation and Oxidation Reaction of Titanium Powder)

  • 이영기;손용운;조영수;김용석;김석윤
    • 열처리공학회지
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    • 제8권2호
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    • pp.137-148
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    • 1995
  • The nitridation kinetics of titanium powder were studied by isothermal and non-isothermal (dynamic) methods in high purity nitrogen under I atm pressure. For the comparison with nitridation, the oxidation kinetics of titanium powder were also studied in dry oxygen at I atm pressure. An automatic recording electrobalance was used to measure the weight gain as a function of time and temperature. For the reaction with nitrogen, the nitride was formed at over $700^{\circ}C$. The reaction with nitrogen followed the parabolic rate law, and the activation energy was calculated to be 31 kcal/mol in the isothermal method (above $900^{\circ}C$). The non-stoichiometric TiNx has been synthesized by the nitridation at a proper temperature and time, followed by the homogenizing treatment above $1100^{\circ}C$. In comparison with the stoichiometric $TiN_{1.0}$ and the non-stoichiometric TiNx ($TiN_{0.5}$ and $TiN_{0.65}$), the hot oxidation characteristics of the former is superior to that of the latter. However, both non-stoichiometric nitrides make little difference in the hot oxidation characteristics.

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펙틴의 곁사슬에 의한 유변학적 성질에 대한 모델 (Modeling of Rheological Properties of Pectins by Side Branches)

  • 신해헌;황재관
    • 한국식품과학회지
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    • 제34권4호
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    • pp.583-589
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    • 2002
  • 펙틴에서 곁사슬의 정도가 다르게 제조된 사과펙틴과 토마토펙틴을 이용하여, 낮은 층밀림속도에서부터 높은 층밀림속도까지 적용이 가능한 유변학적 모델을 구하고자 하였다. 지수법칙모델, Cross 모델, Carreau 모델을 실험값에 비교하여 본 결과, Carreau 모델이 가장 적합하였다. 모델식에서 얻어진 층밀림속도 0에서의 점도$({\eta}_0)$는 곁사슬의 정도가 큰 사과펙틴의 경우에는 곁사슬이 많은 sample II가 적은 sample I보다 크게 나은 반면에 곁사슬이 적은 토마토 펙틴은 큰 차이를 보이지 않았으며, 그 값은 사과펙틴보다 크게 나타났다. 모델식의 계수를 펙틴농도에 대한 지수함수로 표현하여 펙틴에서 곁사슬의 영향을 살펴보았다. 즉, 곁사슬이 많은 사과펙틴은 토마토펙틴에 비해 유변학적 성질이 큰 차이를 보이고 있으며 모델로 설명할 수 있다.

R-410A 임계영역 운전조건에서 오리피스의 성능특성에 관한 연구 (Performance of Short Tube Orifices Using R-410A Near the Critical Region)

  • 최종민;김용찬
    • 설비공학논문집
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    • 제17권12호
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    • pp.1106-1112
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    • 2005
  • An experimental investigation was performed to develop an empirical correlation of R-410A flowing through short tube orifices working near the critical region. Tests were executed by varying upstream pressure from 2,619 kPa to 4,551 kPa, and upstream subcooling from 2.8 and $11.1^{\circ}C$. The experimental data were represented as a function of major operating parameters and short tube diameter. As compared to mass flow trends at normal upstream pressures, flow dependency on upstream subcooling became more significant at high upstream pressures due to a higher density change. Based on the database obtained from this study and literature, an empirical correlation was developed from a power law form of dimensionless parameters generated by the Buckingham Pi theorem. The correlation yielded good agreement with the data. Approximately $92\%$ of the data were correlated within a relative deviation of $5\%$.

Effect of surface bolt on the collapse mechanism of a shallow rectangular cavity

  • Huang, Fu;Zhao, Lian-heng;Zhang, Sheng
    • Geomechanics and Engineering
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    • 제13권3호
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    • pp.505-515
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    • 2017
  • Based on the collapse characteristics of a shallow rectangular cavity, a three-dimensional failure mechanism which can be used to study the collapsing region of the rock mass above a shallow cavity roof is constructed. Considering the effects of surcharge pressure and surface bolt on the collapsing block, the external rate of works produced by surcharge pressure and surface bolt are included in the energy dissipation calculation. Using variational approach, an analytic expression of surface equation for the collapsing block, which can be used to study the collapsing region of the rock mass above a shallow cavity roof, is derived in the framework of upper bound theorem. Based on the analytic expression of surface equation, the shape of the collapsing block for shallow cavity is drawn. Moreover, the changing law of the collapsing region for different parameters indicates that the collapsing region of rock mass decreases with the increase of the density of surface bolt. This conclusion can provide reference for practicing geotechnical engineers to achieve an optimal design of supporting structure for a shallow cavity.

Performing angiographic intervention with a femoral entry shield: Element analysis microscopy and hand dose reduction for interventional radiologist

  • Law, Martin;Ng, Dickon H.L.;Yoon, Do-Kun;Djeng, Shih-Kien
    • Nuclear Engineering and Technology
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    • 제53권4호
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    • pp.1318-1322
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    • 2021
  • To unveil and delineate the elements applicable to the radiation protection of a femoral entry shield, calculate its mass attenuation coefficient, and demonstrate its dose reduction efficacy for interventional radiologist performing transarterial embolization (TAE) of ruptured hepatocellular carcinoma (rHCC). The lead equivalency of the shield was firstly validated. Electron microscopy was used to confirm the femoral entry shield being lead-free and to analyze the elemental content, with which the mass attenuation coefficient of the shield was calculated. An adult phantom, irradiated at the upper abdomen to simulate the TAE of rHCC, was used together with a dosimeter attached to the palm of a hand phantom. The dose rates at the hand phantom were measured, with the rHCC clinical protocol, without and with the femoral entry shield placed over the right femoral access site of the adult phantom. Without using the shield, the average hand dose rate was measured to be 0.325 µSv/sec. While using the shield, it was determined to be 0.110 µSv/sec. There was significant 66% dose reduction to the hand dose of IRs performing angiographic intervention with the femoral entry shield.

Temperature dependent buckling analysis of graded porous plate reinforced with graphene platelets

  • Wei, Guohui;Tahouneh, Vahid
    • Steel and Composite Structures
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    • 제39권3호
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    • pp.275-290
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    • 2021
  • The main purpose of this research work is to investigate the critical buckling load of functionally graded (FG) porous plates with graphene platelets (GPLs) reinforcement using generalized differential quadrature (GDQ) method at thermal condition. It is supposed that the GPL nanofillers and the porosity coefficient vary continuously along the plate thickness direction. Generally, the thermal distribution is considered to be nonlinear and the temperature changing continuously through the thickness of the nanocomposite plates according to the power-law distribution. To model closed cell FG porous material reinforced with GPLs, Halpin-Tsai micromechanical modeling in conjunction with Gaussian-Random field scheme are used, through which mechanical properties of the structures can be extracted. Based on the third order shear deformation theory (TSDT) and the Hamilton's principle, the equations of motion are established and solved for various boundary conditions (B.Cs). The fast rate of convergence and accuracy of the method are investigated through the different solved examples and validity of the present study is evaluated by comparing its numerical results with those available in the literature. A special attention is drawn to the role of GPLs weight fraction, GPLs patterns through the thickness, porosity coefficient and distribution of porosity on critical buckling load. Results reveal that the importance of thermal condition on of the critical load of FGP-GPL reinforced nanocomposite plates.

화재사례분석을 통한 화재피해자 지원체계 구축방안 (Strategy about Support System for Victims of Fire Cases through the Analysis of A Fire Cases)

  • 차종호
    • 산업경영시스템학회지
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    • 제41권4호
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    • pp.196-202
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    • 2018
  • There have been more than 40,000 cases of fires in Korea in the last three years. However, as 'Accidental Fire Liability Act' was judged to be non-conform to the Constitution in 2007, the damages by light mistakes should be compensated. Accordingly, disputes such as compensation claims, litigations and indemnification cases of the victims of fire increased. However, it is so difficult for victims of fire cases to take proper action. So, this study is to help victims of fire cases in the disputes and compensation claims of the victims, and to find actual and practical support system based on the analysis of compensation status. To help victims of fire cases, we need to survey about victims of fire cases with multiple victims. That survey is analyzed to find support plan for victims. Furthermore, to find support plan the current law is needed to be analyzed and reviewed to revision. It is also tried to identify problems in the operation of the Center for victims of Fire currently operated by fire stations and to find countermeasures. In addition, the status of subscription and problem of fire insurance for the compensation for the victims and the method to increase fire insurance subscription rate will be studied.

원통형 펌프 흡입정 벽면에서 발생하는 수중 보텍스 제어 (Control of Subsurface Vortex on Cylindrical Sump Wall)

  • 박영규;전준호;이연원
    • 한국가시화정보학회지
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    • 제17권2호
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    • pp.73-82
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    • 2019
  • The subsurface vortex - which occurs inside the cylindrical sump - was visualized through Computational Fluid Dynamics (CFD) and experiment. The analysis of subsurface vortex inside the cylindrical sump was already carried out using CFD techniques by the first author. To understand the subsurface vortex more clearly, an experimental analysis was carried out with a 1/5th scale model; and the flow rate was calculated according to the similarity law. The experimental results of vortex visualization matches well with the CFD results. The surface roughness model and Anti Vortex Device (AVD) model have been investigated to control the subsurface vortex. For the case of average surface roughness of 1mm and 5mm, the subsurface vortex appears and the vorticity is higher when compared to that of a smooth surface condition. However, for the AVD model, the subsurface vortex is completely removed and the internal flow is stabilized.

Determinants of Sukuk Market Development: Macroeconomic Stability and Institutional Approach

  • BASYARIAH, Nuhbatul;KUSUMA, Hadri;QIZAM, Ibnu
    • The Journal of Asian Finance, Economics and Business
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    • 제8권2호
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    • pp.201-211
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    • 2021
  • This study aims to analyze the determinants of macroeconomic and institutional stability on the development of the global sukuk market by controlling the effects of population. This study uses panel data namely GDP per-capita, exchange rate, and inflation as the proxies for macroeconomic stability sourced from the World Development Index, and six dimensions of Worldwide Governance Indicators (WGI) as institutional proxies sourced from WGI-World Bank. To make robust the relationship between macroeconomics and institutional on the global sukuk market, the population (POP) variable was included as a control variable. The development of sukuk uses a proxy for sukuk issuance in the International Islamic Financial Market, for the annual period from 2002-2017. The data was analyzed using the General Method of Moment, and the results show that by controlling the population effects that proved to be significant, GDP per-capita and the rule of law have a significant impact on the development of sukuk, especially when incorporating population effects as control variables, whereby further ascertaining the effect of each macroeconomic-stability variable and institutional stability on sukuk development, especially inflation, found not to affect sukuk development. These results also confirm the previous findings, whereby inflation remains controllable at a certain level for economic development.

각속도 제한을 고려한 인공위성의 슬라이딩 모드 자세제어 (Sliding Mode Attitude Control of Spacecraft Considering Angular Rate Constraints)

  • 김민영;장석호;이현재
    • 한국항공우주학회지
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    • 제49권2호
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    • pp.129-138
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    • 2021
  • 최근 다양한 지상 및 우주 임무 수행을 위한 위성 개발이 활발히 진행되고 있음에 따라 위성의 고정밀·고기동성을 고려한 위성 자세제어 또한 요구되는 추세이다. 임무 수행 최적화를 위하여 고기동성의 제어 모멘트 자이로(Control Moment Gyros, CMG)를 위성에 장착하여 반작용 휠(Reaction Wheel, RW)과 같은 기존의 구동기에서 비롯되는 기동 제약을 완화시킬 수 있다. 또한, 구동기 자체의 제약 특성으로 인하여 위성의 각속도 제한이 발생하게 된다. 본 논문에서는 이를 고려한 CSCMG(Constant Speed CMG)장착 위성의 자세제어를 위하여 슬라이딩 모드 기반 제어기를 설계하였고, 리아푸노프 안정성을 확인하였으며 마지막으로 수치 시뮬레이션을 통하여 제어기 성능 분석을 진행하였다.