• Bulletin of the Korean Chemical Society
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• 제26권8호
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• pp.1241-1245
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• 2005

Solvolyses of trifluoromethanesulfonyl chloride (TFMSC) in water and in aqueous binary mixtures of acetone, ethanol and methanol are investigated at 25, 35 and 45 ${^{\circ}C}$. The Grunwald-Winstein plot of first-order rate constants for the solvolytic reaction of TFMSC with YCl (based on 2-adamantyl chloride) shows marked dispersions into three separate curves for three aqueous mixtures. The extended Grunwald-Winstein plots for the solvolysis of TFMSC show better correlation. The large negative ${\Delta}S^{\neq}$ and relatively small positive ${\Delta}H^{\neq}$ reveals that the solvolytic reaction proceeds via a typical bimolecular reaction mechanism. The l and m values determined in various solvents are consistent with the proposed mechanism of the general base catalysis $S_AN/S_N2$reaction mechanism for TFMSC solvolyses based on mass law and stoichiometric solvation effect studies.

• 한국추진공학회지
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• 제13권4호
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• pp.36-44
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• 2009

광학 선형 패터네이터 및 광학 토모그래피 기법을 사용하여 높은 주위 기체 압력 조건에서 분무단면을 측정하였다. 레이저 직선광이 분무 영역을 지나도록 하여 발생하는 Mie 산란 신호 및 직선광의 투과율을 측정하였으며, 이로부터 Beer-Lambert 법칙 및 수학적 단면 재구성 기법을 이용하여 분무 단면의 감쇠 계수 분포를 재구성하였다. 높은 주위 기체 압력 조건에서 광학적으로 밀한 분무가 발생하며, 그 결과 산란 신호의 감쇠 효과가 크게 증가한다. 따라서 미 산란 신호를 이용하는 광학 선형 패터네이터의 경우 감쇠 효과를 완화하는 데 한계를 보인다. 광학 토모그래피의 경우 분무를 통과하는 레이저광의 투과율 정보만을 이용하여 성공적으로 분무 단면을 재구성하였다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2010년도 제35회 추계학술대회논문집
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• pp.311-316
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• 2010

The ignition and the burning characteristics of aluminum and magnesium particles ($30-110{\mu}m$ in diameter) isolated due to electrodynamic levitation were experimentally investigated. The burning time, the ignition delay time, the flame temperature, and the flame diameter were measured. The thermal radiation intensity was measured using the photomultiplier tube and the combustion history was monitored by high-speed cinematography. Two-wavelength pyrometry measured the temperature of the burning particles. The burning times of aluminum particles were measured approximately 5 to 8 times longer than those of magnesium particles. Exponents of $D^n$-law, for the burning rate of magnesium and aluminum particles of diameters less than $110{\mu}m$, are found to be 0.6 and 1.5, respectively. The instant of aluminum ignition is clearly distinguished with the ignition delay time little less than 10 ms, however the burning history of magnesium particle exhibits no distinct instant of the ignition. The ignition delay time of magnesium particle (less than $110{\mu}m$) were approximately shown in the range from 50 to 200 ns. The flame temperatures of single metal particles are lower than the boiling point of the oxide. The nondimensional flame diameters for magnesium are decreased with increasing of the diameter. The nondimensional flame diameters for aluminum are not changed significantly.

• Computers and Concrete
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• 제2권6호
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• pp.499-516
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• 2005

A composite model is used to represent the heterogeneity of plain concrete consisting of coarse aggregates, mortar matrix and the mortar-aggregate interface. The composite elements of plain concrete are modeled using triangular finite element units which have six interface nodes along the sides. Fracture is captured through a constitutive single branch softening-fracture law at the interface nodes, which bounds the elastic domain inside each triangular unit. The inelastic displacement at an interface node represents the crack opening or sliding displacement and is conjugate to the internodal force. The path-dependent softening behaviour is developed within a quasi-prescribed displacement control formulation. The crack profile is restricted to the interface boundaries of the defined mesh. No re-meshing is carried out. Solutions to the rate formulation are obtained using a mathematical programming procedure in the form of a linear complementary problem. An event by event solution strategy is adopted to eliminate solutions with simultaneous formation of softening zones in symmetric problems. The composite plain concrete model is compared to experimental results for the tensile crack growth in a Brazilian test and three-point bending tests on different sized specimens. The model is also used to simulate wedge-type shear-compression failure directly under the loading platen of a Brazilian test.

• Structural Engineering and Mechanics
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• 제19권6호
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• pp.639-652
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• 2005

In this paper, a full-scale K-joint specimen was tested to failure under cyclic combined axial and in-plane bending loads. In the fatigue test, the crack developments were monitored step by step using the alternating current potential drop (ACPD) technique. Using Paris' law, stress intensity factor, which is a fracture parameter to be frequently used by many designers to predict the integrity and residual life of tubular joints, can be obtained from experimental test results of the crack growth rate. Furthermore, a scheme of automatic mesh generation for a cracked K-joint is introduced, and numerical analysis of stress intensity factor for the K-joint specimen has then been carried out. In the finite element analysis, J-integral method is used to estimate the stress intensity factors along the crack front. The numerical stress intensity factor results have been validated through comparing them with the experimental results. The comparison shows that the proposed numerical model can produce reasonably accurate stress intensity factor values. The effects of different crack shapes on the stress intensity factors have also been investigated, and it has been found that semi-ellipse is suitable and accurate to be adopted in numerical analysis for the stress intensity factor. Therefore, the proposed model in this paper is reliable to be used for estimating the stress intensity factor values of cracked tubular K-joints for design purposes.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.13-18
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• 2004

The objective of this study is to investigate fracture toughness and fatigue crack propagation behavior in the Reduced Activation Ferritic Steel (RAFs) JLF-I. The fracture toughness tests were performed with various size(plane size and thickness) and various side groove of specimens. The fatigue crack propagation behavior of the JLF-I steel was investigated by the constant-amplitude loading test for the stress ratios R=O.I, 0.3 and 0.5 respectively. The effects of stress ratios and specimen size on the fatigue crack growth behaviors for JLF-I steel were discussed within the Paris law. The test results showed the standard CT specimen with the side groove of 40 % represented a valid fracture toughness. The fracture resistance curve increased with increasing plane size and decreased with increasing thickness. However, the fracture resistance curve of half size specimen was similar to that of the standard specimen. The fatigue crack propagation rate of a half size specimen was similar to that of a full size specimen at the stress ratios of 0.1, 0.3 and 0.5 respectively. The fatigue crack propagation behavior of this material were evaluated by using a half size specimen.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.400-405
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• 2004

In this study, the optimal welding condition of the input power was selected experimentally through the ERW simulator, which is equal to welding status of ERW part in pipe. This condition is the input power 250kW in the heat treatment of the $900^{\circ}C$ normalizing derived from the nondestructive technique and impact energy. In order to evaluate the variation of the fatigue life in the pipe, fatigue surface crack growth test of base and optimal welded metal were performed statistically. As stress intensity factor range (${\Delta}K_s$) increases, the fatigue crack propagation rate (da/aN) of the base metal is faster than that of the welded joint. The variation of the fatigue life in the ERW pipe was estimated statistically using Monte-Carlo simulation with the standard deviation of material constants (C and m) of the paris law in the specimen.

• 한국추진공학회지
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• 제19권2호
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• pp.29-37
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• 2015

본 연구는 케로신 연료를 사용하는 액체로켓엔진에서 발생할 수 있는 연소불안정으로 인하여 파괴될 수 있는 연소기의 손상을 수치적으로 모사하는 해석 모델의 기초연구이다. 연소불안정으로부터 야기 될 수 있는 케로신의 데토네이션은 1단계 아레니우스 식의 화학 반응식을 이용하였고, 구조체는 Johnson-Cook 강성모델을 활용하여 데토네이션으로 인한 금속관의 소성 변형을 모델링하였다. 금속관의 소성 변형에 의해 변화하는 유동장과 구조체의 스트레스를 노즐 형상과 관의 두께변화에 따라 해석하였다.

• 한국태양에너지학회 논문집
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• 제31권6호
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• pp.49-56
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• 2011

In this study a novel cogeneration system driven by low-temperature sources at a temperature level below $190^{\circ}C$ is investigated by first and second laws of thermodynamics. The system consists of Organic Rankine Cycle(ORC) and an additional heat generation as a parallel circuit. Seven working fluids of R143a, R22, R134a, R152a, $iC_4H_{10}$(isobutane), $C_4H_{10}$(butane), and R123a are considered in this work. Maximum mass flow rate of a working fluid relative to that of the source fluid and optimum turbine inlet pressure are considered to extract maximum power from the source. Results show that due to a combined heat and power generation, both the efficiencies by first and second laws can be significantly increased in comparison to a power generation, however, the second law efficiency is more resonable in the investigation of cogeneration systems. Results also show that the working fluid for the maximum system efficiency depends on the source temperature.

• 한국직업건강간호학회지
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• 제14권1호
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• pp.44-55
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• 2005

Purpose: The purpose of this study was to describe the current status of work-related back pain among nurses in the U.S. Method: Literature review and website searching were conducted. Key words as 'nurse and back pain (or back injury)' were used in searching the Medline, NIOSHTIC-2and reference list of selected studies. Total studies were selected of which subjects were nurses working in the U.S., and published since 1970. Results: Though there was variation in the measurement among studies, the prevalence rate of back pain among nurses in the U.S. could be estimated about 50%. Risk factors were confirmed as the frequency of patient lifting, ward, nursing shortage, overtime, work shift, stress on physical demand, but age and work experiences showed the inconsistent relation. It has been well known that educational approach is not enough to prevent back pain. Intervention studies to apply the ergonomic approach using mechanical devices reported the effects, but the devices were less diverse than European countries or Canada. The study for lifting team was rare. Federal government developed only the guideline for nursing home that had no legal obligation. As a professional nursing organization, ANA has been trying to educate and advocate for "No lift policy" since 2003. Meanwhile, two trade unions of nurses made efforts to establish the law strengthening the responsibility of health care facilities. Conclusion: The research and policy development will be needed to prepare to rapid increase of back pain among Korean nurses.