• Title/Summary/Keyword: Rate Law

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Steady-State and Transient Response Analysis of DSSC Based on Electron Diffusion Coefficient and Chemical Capacitance

  • J. C. Gallegos;J. Manriquez;R. Rodriguez;S. Vargas;D. Rangel
    • Journal of Electrochemical Science and Technology
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    • v.15 no.2
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    • pp.276-290
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    • 2024
  • A study of the transition from transitory state to steady state in DSSCs based on natural dyes is presented; cochineal was used as dye and Li+, Na+, and K+ were the ions added to the electrolyte. The photocurrent profiles were obtained as a function of time. Several DSSCs were prepared with different cations and their role and the transitory-to-steady transition was determined. A novel hybrid charge carrier source model based on the Heaviside function H(t) and the Lambert-Beer law, was developed and applied to analysis of the transient response of the output photocurrent. Additionally, the maximum effective light absorption coefficient α and the electronic extraction rate κ for each ion were determined: ${\alpha}_{Li^+,Na^+,K^+}\,=\,(0.486,\,0.00085,\,0.1126)\,cm^{-1}$, and also the electronic extraction rate ${\kappa}^{Li^+,Na^+,K^+}_{ext.}\,=\,(1410,\,19.07,\,19.69)\,cm\,s^{-1}$. The impedance model using Fick's second law was developed for carrier recombination to characterize the photocurrent.

The Analysis of the National Examination for Dietitian's License by Educational System (영양사 국가시험 과목의 학제별 개설 운영 실태 및 영양사 국가시험과의 상관성 분석)

  • Park, Sanghyun;Jung, Hyeon-A;Paik, Jae-Eun;Joo, Nami
    • The Korean Journal of Food And Nutrition
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    • v.26 no.2
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    • pp.234-241
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    • 2013
  • The purpose of this research was to suggest a category and level of national examination for dietitian's license and provide basic data for the development of national examination question by analyzing the current states on the curriculum of national examination for the dietitian's license and correlation with the current states on curriculum and national examination for the dietitian's license. The higher the current states on curriculum, the lower absentee rate and failing rate of the national examination for the dietitian's license. The higher the current states on curriculum, the higher pass rate of the national examination for the dietitian's license. Also, the current states on curriculum were positive relationship with correct answer rates. The higher the educational system, the higher the current states on curriculum. The educational system was negative relationship with the current states on curriculum of 'public health', 'advanced nutrition', 'food science', 'principles of culinary', and 'food sanitary law (p<0.05)'. The correct answers rates of 'institutional foodservice' were significantly positive relationship with the current states on curriculum of 'institutional foodservice (p<0.01)', 'foodservice organization (p<0.01)', 'food sanitation (p<0.05)', and 'practice in foodservice institutions (p<0.01)'. The pass rate was significantly positive relationship with the correct answer rates of 'institutional foodservice (p<0.01)', 'physiology (p<0.01)', 'biochemistry (p<0.01)', 'food sanitary law (p<0.01)', 'food science and preparation (p<0.05)', 'nutrition education (p<0.01)', 'nutrition (p<0.01)', and 'total score (p<0.05)'.

Effect of Al Addition on the Reaction Behavior of Pure Cobalt with Molten Zinc (용융 아연과 WC-Co 코팅층 내 코발트의 반응거동에 미치는 아연욕 중의 Al 첨가 영향)

  • Seong, Byeong-Geun;Kim, Kyoo-Young;Kwon, Sung-Hee;Lee, Kee-Ahn
    • Journal of the Korean institute of surface engineering
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    • v.40 no.1
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    • pp.23-31
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    • 2007
  • The objective of this study is to investigate the effect of Al addition on the reaction behavior of cobalt with molten zinc. Pure cobalt specimen was immersion tested in the three kinds of molten zinc (pure, 0.12%Al added and 0.24%Al added) baths at $460^{\circ}C,\;490^{\circ}C\;and\;520^{\circ}C$. For the understanding of degradation processes, specimens were analyzed with scanning electron microscope (SEM) and energy dispersive spectrum (EDS), and electrochemical stripping method. When 0.12% and 0.24% Al was added in molten zinc baths, three intermetallic compounds layers of ${\gamma},\;{\gamma}_1,\;and\;{\gamma}_2$ were formed on the Co matrix and ${\beta}_1$ layer was not formed between the Co matrix and the ${\gamma}$ layer. Particles of CoAl intermetallic compound were formed at the interface between the ${\gamma}_2$ layer and zinc melt and they did not adhere to the Co-Zn intermetallic layer. Weight loss of the Co specimen increased as Al content in the molten zinc increased and the relationship of weight loss vs. immersion time followed parabolic rate law. Rate controlling process for the reaction rate of Co with Al added molten zinc was analyzed as the diffusion process of Al atom through a boundary layer between the ${\gamma}_2$ layer and the Al added zinc melt.

The Drying Characteristics of Apples at Various Drying Conditions (사과의 건조조건(乾燥條件)에 따른 건조특성(乾燥特性))

  • Jung, Shin-Kyo;Choi, Yong-Hee;Shon, Tae-Hwa;Choi, Jong-Uck
    • Korean Journal of Food Science and Technology
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    • v.18 no.1
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    • pp.61-65
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    • 1986
  • This study was performed to examine the drying characteristics of apples at various drying conditions. Air velocity has no effect on the drying rate except the constant rate period. In this experiment the diffusion coefficients of moisture in the apple tissue were in the range of $1.1470-2.2148{\times}10cm^2/sec$. As a result of balance of heat and mass transfer during the falling rate period. an empirical equation based on Fick's law was obtained as follows; $log{\Delta}t\;=\;log\;t_o\;-\;D{\frac{{\pi}^2{\theta}}{4d.}}$ This equation can be used to calculate the temperature of apples during the falling rate period, provided the diffusion coefficients of apple are known. The experimental values of the internal moisture distribution during apple dehydration were nearly in accord with the theoretical values.

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A Study on the DCT Image Coding Considering Weber's law (웨버의 법칙을 고려한 DCT 영상 부호화에 관한 연구)

  • 이은국;김장복
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.18 no.5
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    • pp.663-674
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    • 1993
  • In this paper, a DCT image coding algorithm using the human visual property is proposed. Human visual is relatively sensitive to noise in the darker region, insensitive to noise in the brighter region. This property was proved by Weber's law through psycovisual experiment. Weber's law states that the just noticeable difference (j.n.d.) is proportional to intensity. Therefore, the implication of this observation for image processing is that reducing noise in the darker region is more important than reducing noise in the brighter region. In this proposed coding scheme AC coefficients in the darker region are more finely quantized than those in the brighter region. Results showed that, at low bit rate, the subjective quality of reconstructed images by proposed coding scheme is improved than that of coding scheme without considering human visual property.

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A Computational Work of Critical Nozzle Flow for High-Pressure Hydrogen Gas Mass Flow Measurement (고압수소 유량계측용 임계노즐 유동의 수치해석적 연구)

  • Lee, Jun-Hee;Kim, Heuy-Dong;Park, Kyung-Am
    • 유체기계공업학회:학술대회논문집
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    • 2006.08a
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    • pp.227-230
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    • 2006
  • The method of mass flow rate measurement using a critical nozzle is well established in the flow satisfying ideal gas law. However, in the case of measuring high-pressure gas flow, the current method shows invalid discharge coefficient because the flow does not follow ideal gas law. Therefore an appropriate equation of state considering real gas effects should be applied into the method. The present computational study has been performed to give an understanding of the physics of a critical nozzle flow for high-pressure hydrogen gas and find a way for the exact mass flow prediction. The two-dimensional, axisymmetric, compressible Navier-Stokes equations are computed using a fully implicit finite volume method. The real gas effects are considered in the calculation of discharge coefficient as well as in the computation. The computational results are compared with the previous experimental data and predict well the measured mass flow rates. It has been found that the discharge coefficient for high-pressure hydrogen gas can be corrected properly adopting the real gas effects.

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The Performance Analysis of Otto Cycle Engine by Thermodynamic Second Law (오토 사이클 기관의 열역학 제 2법칙적 성능 해석)

  • 김성수;노승탁
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.6
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    • pp.94-102
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    • 2001
  • The thermodynamic second law analysis, which means available energy or exergy analysis, for the indicated performance of Otto cycle engine has been carried out. Each operating process of the engine is simplified and modeled into the thermodynamic cycle. The calculation of the lost work and exergy through each process has been done with the thermodynamic relations and experimental data. The experimental data were measured from the test of single cylinder Otto cycle engine which operated at 2500 rpm, WOT(Wide Open Throttle) and MBT(Minimum advanced spark timing for Best Torque) condition with different fuels: gasoline, methanol and mixture of butane-methanol called M90. Experimental data such as cylinder pressure, air and fuel flow rate, exhaust gas temperature, inlet gas temperature and etc. were used for the analysis. The proposed model and procedure of the analysis are verified through the comparison of the work done in the study with experimental results. The calculated results show that the greatest lost work is generated during combustion process. And the lost work during expansion, exhaust, compression and induction process follows in order.

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Study on Design of Air-water Two-phase Flow Centrifugal Pump Based on Similarity Law

  • Matsushita, Naoki;Furukawa, Akinori;Watanabe, Satoshi;Okuma, Kusuo
    • International Journal of Fluid Machinery and Systems
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    • v.2 no.2
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    • pp.127-135
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    • 2009
  • A conventional centrifugal pump causes a drastic deterioration of air-water two-phase flow performances even at an air-water two-phase flow condition of inlet void fraction less than 10% in the range of relatively low water flow rate. Then we have developed a two-phase flow centrifugal pump which consists of a tandem arrangement of double rotating cascades and blades of outer cascade have higher outlet angle more than $90^{\circ}$. In design of the two-phase flow pump for various sized and operating conditions, similarity relations of geometric dimensions to hydraulic performances is very useful. The similarity relations of rotational speed, impeller diameter and blade height are investigated for the developed impeller in the present paper. As the results, the similarity law of rotational speed and impeller diameter is clarified experimentally even in two-phase flow condition. In addition, influences of blade height on air-water two-phase flow performances indicate a little difference from the similarity relations.

Performance Characteristics of Combined Heat and Power Generation with Series Circuit Using Organic Rankine Cycle (유기랭킨사이클을 이용한 직렬 열병합 사이클의 성능 특성)

  • Kim, Kyoung-Hoon;Jung, Young-Guan
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.5
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    • pp.699-705
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    • 2011
  • A combined heat and power cogeneration system driven by low-temperature sources is investigated by the first and second laws of thermodynamics. The system consists of Organic Rankine Cycle (ORC) and an additional process heater as a series circuit. Seven working fluids of R152a, propane, isobutane, butane, R11, R123, isopentane and n-pentane are considered in this work. Maximum mass flow rate of a working fluid relative to that of the source fluid is considered to extract maximum power from the source. Results indicate that the second-law efficiency can be significantly increased due to the combined heat and power generation. Furthermore, higher source temperature and lower turbine inlet pressure lead to lower second-law efficiency of ORC system but higher that of combined system. Results also show that the optimum working fluid varies with the source temperature.

A Study on the Design and Validation of Automatic Pitch Rocker System for Altitude, Speed and Deep Stall Recovery (항공기의 고도, 속도 및 깊은 실속의 회복을 위한 자동회복장치 설계 및 검증에 관한 연구)

  • Kim, Chong-Sup
    • Journal of Institute of Control, Robotics and Systems
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    • v.15 no.2
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    • pp.240-248
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    • 2009
  • Modem version of supersonic jet fighter aircraft must have been guaranteed appropriate controllability and stability in HAoA(High Angle of Attack). The HAoA flight control law have two parts, one is control law of departure prevention and the other is control law of departure recovery support. The control laws of departure prevention for advanced jet trainer consist of HAoA limiter, roll command limiter and rudder fader. The control laws of departure recovery support are consist of yaw-rate limiter and MPO(Manual Pitch Override) mode. The guideline of pitch rocking using MPO mode is simple, but operating skill of pitch rocking is very difficult by the pilot with inexperience of departure situation. Therefore, automatic deep stall recovery system is necessary. The system called the "Automatic Pitch Rocker System" or APRS, provided a pilot initiated automatic maneuver capable of an aircraft recoveries in situations of deep stall, speed and altitude. This paper addresses the design and validation for APRS to recovery of an deep stall without manual pitch rocking by the pilot. Also, this system is designed to recovery of speed, attitude and altitude after deep stall recovery using ATCS (Automatic Thrust Control System) and autopilot. Finally, this system is verified by real-time pilot evaluation using HQS (Handling Quality Simulator).