• Title/Summary/Keyword: Rate Law

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Kinetic Study of Proton Exchange between Al($H_2O$)$_6^{3+}$ Ion and Bulk Water Molecules (Ⅰ) (Al($H_2O$)$_6^{3+}$ 이온과 물 용매 분자 사이에서의 수소 이온 교환의 반응속도론적 연구 (Ⅰ))

  • Moon-Hwan Cho;Jin-Ho Kim;Chang-Ju Yoon
    • Journal of the Korean Chemical Society
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    • v.32 no.5
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    • pp.436-442
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    • 1988
  • The $^1H-nmr$ lineshapes of $H_2O$ in the solution containing $Al^{3+}$ ion have been measured as a function of temperature and $H^+$-ion concentration. Above [$H^+$] = 0.06, the lineshape were analyzed by the uncoupled two-site exchange model. From the proton exchange rate between hexaaquaaluminium ion and bulk water as a function of H-ion concentration. These kinetic data could be fitted to a following linear rate law; that is; 1/${\tau}$ = k$_1$/12 + $k_2$[$H^+$]/6. The following proton exchange parameters were obtained; $k_1^{298}$ = 38.5s$^{-1}$ ${\{Delta}H_1^{\neq}$ = $42.9kJ mole^{-1}$ ${\{Delta}S_1^{\neq}$ = -48.6J $mole^{-1}K^{-1}$ $k_2^{298}$ = $172s^{-1}mole^{-1}$ ${\{Delta}H_2^{\neq}$ = 27.8kJ $mole^{-1}$ ${\{Delta}S_2^{\neq}$ = -90.3J $mole^{-1}K^{-1}$ These activation parameters are indicating an associative interchange, Ia, mechanism for the acid-hydrolysis of hexaaquaaluminium ion and the proton exchange between the hydration spheres of $Al^{3+}$ and $H^+$.

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Revenue and Expenditure by Alternative Integration Proposals of the Medical Insurance Society for Self-Employed (지역의료보험조합의 통합대안별 재정수지 비교)

  • Park, Jae-Yong;Beh, Sung-Kweun;Kam, Sin
    • Health Policy and Management
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    • v.5 no.1
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    • pp.80-105
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    • 1995
  • Assuming that we introduced integration of medical insurance society for self-employed, this study was conducted to examine effects and results after the integration and to research more effective method for integration. To assess effects and results of the finacial status of 266 insurance societies after intergration, the data were obtained from "The Medical Insurance Program for Self-Employeds Statistical Yearbook in 1992". The major finding are as follows : 1. Three alternative integration proposals were made. First alternative proposal was consisted of 232 medical insurance societies, second was 187, and third was 115. 2. As the results of average number of the insured per insurance societies of medical insurance program for self-employed every alternative proposal, first was 88, 119 persons, second was 108, 576, and third was 178, 967 from 76, 576 persons of present socienties. 3. It was true that the more average size of societies increased, the more average administration expenditure per 1, 000 insured reduced. 4. The average size of societies grew bigger, the rate of general expenditure to general revenue more improved. Also, the rate of benefits to contributions was changed for better. But if not to have had correct analysis and precise preparation for integration, effects and results of integration were always not optiized. 5. According to results of simple regression formulas, it was proved that the more the average size of societies was increased, the more result was advantaged. 6. The law of majority and the economy of scale were applied in this study, and it was necessary to analyze and assess effectiveness and efficiency of integration. Therefore, when the integration of medical insurance societies for self-employeds will be performed, it must be taken into consideration. Among three alternative proposals, third was showed more effective alternative than anothe, second was presented more ineffective result than present system. To achieve more effective and efficient integration of regional medical insurance societies throughout the result of the regression formula on present cost curve, it is necessary to operate well-integrated societies and to know appropriative countermeasures of present situation of each societies. Also, for integrating regional medical insurance societies, it is necessary to continue more deep research through practical model activity and to investigate the effective size and managed method of the societies.societies.

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A Study on the Behaviour of Fish Schools in the Process of Catch of the Purse Seine Fishing Method (선망어법의 어획과정에 있어서 어군행동에 관한 연구)

  • Park, Jeong-Sik;Kim, Seok-Jong;Kim, Sam-Gon
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.33 no.3
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    • pp.173-182
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    • 1997
  • This study is a basic research in purse seine fishery : on the behaviour of fish schools of tilapia Tilapia mossambica in the process of catch of the purse seine fishing method. The experiment was carried out for the mackerel purse seine which using of power block by fishing fleet system in the near sea of Cheju Island and as a forecast in the near future on the purse seine fishing, using of triplex net winch by one boat system in the near sea of Norway. These model purse seines were made of the scale of 1/180 of its full scale. The model purse seine test on the escaping behaviour of fish school by gap, area reducing of gap and tension of purse line was carried out in the stagnant water of experimental water tank. Designing and testing for the model purse seines were based on the Tauti's law. The results obtained were as follows : 1. When the time for the completing of pursing was 20 minutes, average swimming speed of fish school through a gap was 9.71cm/sec for powerblock seine and 9.97cm/sec for triplex seine. 2. In the case of pursing time in actual value was 20minutes, at 50 percent of the pursing, swimming behaviour of fish school in purse seine was 10% to I section, 80% to II section, 10% to III sectional direction for powerblock seine and a similar tendency for triplex seine. 3. In the case of pursing time in actual value was 20 minutes, at the time of 10 minutes have proceeded since then, area reducing rate of gap of the seine in projected front view was 63.5% for powerblock seine and 67.5% for triplex seine. 4. In the case of pursing time in actual value was 20 minutes, escaping rate of fish school by gap in projected front view was 70% for powerblock seine and 30% for triplex seine. Maximum tension of purse line was about 8.1 tons for powerblock seine and about 8.3 tons for triplex seine.

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Applicability of Washing Techniques Coupled with High-Pressure Air Jet for Petroleum-contaminated Soils (고압공기분사를 이용한 유류오염토양 세척기법의 적용성 연구)

  • Choi, Sang-Il;Kim, Kang-Hong
    • Journal of Soil and Groundwater Environment
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    • v.11 no.6
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    • pp.61-68
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    • 2006
  • Soil washing techniques coupled with high pressure air jet were applied for diesel-contaminated soils sampled by an underground oil reservoir of which the initial total petroleum hydrocarbon (TPH) ($2,828{\pm}206\;mg/kg$) exceeded 5 times of current standard level (500 mg/kg) regulated by the Soil-Environment Conservation Law. Through several tests, we found that the position of impeller has a critical impact for washing efficiencies. The highest washing efficiency was obtained at an oblique angle (30 degree) for the impeller and optimized mixing speed (300 rpm) that could have high shearing forces. Considered economical and feasible aspects, the optimum mixing time was 10 min. Rate constants of TPH removal derived from the first-order equation were not linearly increased as mixing speed increased, indicating that mechanical mixing has some limits to enhance the washing efficiencies. Application of high-pressure air jet in washing process increased the washing efficiency. This increase might be caused by the fact that the surface of micro-air bubbles strongly attached hydrophobic matters of soil particles. As the pressure of air jet increased, the separation efficiencies of TPH-contaminated soil particles increased. In the combined process of high-pressure air jet and mixing by impeller, the optimum mixing speed and air flow-rate were determined to be 60 rpm and $2\;kg/cm^2$, respectively. Consequently, the washing technique coupled with high-pressure air jet could be considered as a feasible application for remediating petroleum-contaminated soils.

Determinants of Success in Ex-parte and Inter-parte Patent Litigation (발명의 특허성 및 특허의 유효성 분쟁결과에 영향을 미치는 요인분석)

  • Choo, Ki-Neung;Oh, Jun-Byoung
    • Journal of Technology Innovation
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    • v.20 no.3
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    • pp.57-91
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    • 2012
  • This paper investigates determinants of litigation success in the two distinctive types of patent litigations, ex-parte and inter-parte cases, which are brought in the process where a filed application becomes a valid patent right. We regress winning rates of patent applicants on the characteristics of firms, trials, patent lawyer, and patent itself, using a probit model with sample selections. The paper finds that the relative suit rate of a firm, time to be sued, changes of patent agents by applicants, and multiple agents among explanatory variables affect ex-parte reexamination and in-parte post-grant patent trials differently in the point of average marginal effects. These variables lower the probability of applicant's victory in the ex-parte cases, while they raise the probability in the inter-parte trials. However, the experience that agents represent applicants is a winning rate-increasing factor both in inter-parte and ex-parte reexamination, unexpectedly. This result cannot be applied to the entire domain of the variable, since sample selection effects are reflected in the result. The number of claim increases the winning probability of the applicant in the both types of patent litigations. This study has some limitations because it ignores the information on the legal person to which a patent agent belongs, and confined agent's experience to patent filing. We leave it future studies to investigate the effects of lawsuit experience of patent agent, and those of characteristics of the law firm to which individual patent lawyer is affiliated.

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A Study on the Evaluation of Potential Hydro-electric Power in North Korea (북한의 수력발전가능량 산정 및 평가에 대한 연구)

  • Park, Miri;Ahn, Jaehyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.38 no.1
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    • pp.41-49
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    • 2018
  • This study is to analyze and evaluate water resource development potential in North Korea. The study was conducted to analyze selected potential hydropower as an indicator to evaluate water resource development potential. Potential hydropower means theoretical value about the potential capacity of river. It is used to evaluate the amount of development through the hydropower generation. For calculating potential hydropower, monthly average and annual average of rainfall for each river basin were calculated by using the data of 27 rainfall stations in North Korea. As a result of the calculation of theoretical potential hydropower by rainfall in the seven major basins in North Korea, the Aprok River basin was analyzed to be the largest with $7,562.2{\times}10^3kW$. The efficiency and utilization rate of theoretical potential hydraulic power in South Korea and North Korea was 42.3% and 36.2%, respectively. The Daedong River basin's potential hydropower utilization rate is 12.3%, which is the lowest in North Korea. In the case of Daedong River basin, more than 40% of the total population is inhabited, so demand for water and electricity is expected to be the largest. Therefore, the Daedong River basin is considered as a priority area for water resource development. The results of this study are expected to be used as basic data for future water resource development projects and research activities in North Korea.

Catching efficiency of biodegradable trammel net for swimming crab (Portunus trituberculatus) in the Yeonpyeong fishing ground of Korea (연평어장에서 생분해성 꽃게 삼중자망의 어획성능)

  • Kim, In-Ok;Lee, Gun-Ho;Cho, Sam-Kwang;Cha, Bong-Jin;Sohn, Byung-Kyu
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.48 no.4
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    • pp.322-336
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    • 2012
  • To study the catching efficiency of biodegradable trammel net for swimming crab (Portunus trituberculatus), three types (biodegradable, monofilament and multifilament) of trammel nets were used in the field test, and the tests were carried out 16 times with two different mesh sizes (105mm and 160mm) in the Yeonpyeong fishing ground of Korea, 2009~2011. The catching efficiency of three type nets was analyzed by catch in number, catch in weight and average weight per individual of small and large size swimming crab by net types and mesh sizes. Statistical T-test was also carried out to verify the efficiency between the three types of nets. The results are as follows. The catch in number of swimming crab was 24,667 and formed about 81.0% of total catch. Of all swimming crab catch, small swimming crabs with less than 64mm in carapace length which is a prohibited landing size by law formed 48.1%, larger swimming crabs with more than 64mm in carapace length which is a landing size formed 51.9%. In 105mm mesh size trammel net test, the catch share in number of small size swimming crab by biodegradable trammel net was 47.5% in comparison with multifilament trammel net and 74.2% in comparison with monofilament trammel net, so biodegradable trammel net has more protective effects on small size swimming crab than other types of trammel nets. The protective effects for small size swimming crab by biodegradable trammel net was 25.8~52.5% in comparison with other types of trammel nets. The catch share in weight of large size swimming crab by biodegradable trammel net was 98.3% in comparison with multifilament trammel net and 92.3% in comparison with monofilament trammel net, so biodegradable trammel net has a similar catch efficiency to multifilament trammel net. The results of 160mm mesh size trammel net test have shown similar results of 105mm mesh size trammel net test. This study shows that biodegradable trammel net is a more useful fishing gear than multifilament and monofilament trammel net because biodegradable trammel net has lower catch rate than other types of nets in small size swimming crab and similar catch rate than multifilament trammel net which is a well used net by fishermen.

Effects of Gas Injection on the Recovery of Copper Powder from Industrial Waste Water in Fluidized - Bed Electrolytic Reactors (유동층 전극반응기에서 기체의 유입이 산업폐수로부터 동입자의 회수에 미치는 영향)

  • Song, Pyung-Seob;Son, Sung-Mo;Kang, Yong;Kim, Seung-Jai;Kim, Sang Done
    • Applied Chemistry for Engineering
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    • v.16 no.4
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    • pp.485-490
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    • 2005
  • Effects of gas injectino on the copper recovery form industrial waste water in a fluidized-bed electrolytic reactor were investigated. Effects of gas injection on the individual phase holdup and efficiency of copper recovery for given operating variables such as liquid and gas velocity (0.1~0.4 cm/s), current density ($2.0{\sim}3.5A/dm^2$) and amount of fluidized solid particles (1.0~4.0 wt%) were examined. The solid particle, whose diameter and swelling density were 0.5 mm and $1100kg/m^3$, respectively, was made of polystylene and divinyl benzene. It was found that the holdup of gas and solid phases increased, but that of the liquid phase decreased with increasing velocity of gas injected into the reactor. With increasing gas and/or liquid velocity and increasing amount of fluidized particles is not needed, the rate of copper recovery increased to a maximum value of and subsequently decreased. The recovery rate of copper increased almost linearly with increasing current density in accordance with Faraday's law.

가중 쳐프 신호를 사용한 초음파 고조파 영상 기법

  • 김동열;이종철;권성재;송태경
    • Journal of Biomedical Engineering Research
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    • v.23 no.1
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    • pp.61-72
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    • 2002
  • In this parer, a new harmonic imaging technique is Proposed and evaluated experimentally. In the Proposed method. a weighted chirp signal with a hanning window is transmitted. The RF samples obtained on each array element are individually compressed by correlating with the reference signal defined as the 2nd harmonic component($2f_0$) of a transmitted chirp signal generated in a square-law system. The correlator output will then consist of the compressed version of the $2f_0$ component generated in tissue and the crosscorrelation sequence of the fundamental($f_0$) and 2f$_{0}$components. The Proposed method uses the compressed $2f_0$ component to form an image. for which the crosscorrelation term should be suppressed below at least -50dB. The Proposed method has two process, 2f$_{0}$-correlation and $2f_0$-correlation(PI) . $2f_0$-correlation can successfully eliminate the $f_0$ component with a single transmit-receive events and therefore is more efficient than the conventional Pulse inversion method in terms of the frame rate. 2i)-correlation(Pl) Performs pulse compression after applying pulse inversion method for the 2nd harmonic image with high resolution and SNR. Another advantage of the proposed method is that the SNR of 2nd harmonic imaging can be improved without limitation by increasing the duration of the chirp signal. The proposed method was verified through both the computer simulations and actual experiments .ts .

Examination on Numerical Simulation Using Reduced-scale Model of Theater Fire: Influences of Fire Curtain and Stage Natural Vent (공연장 화재 축소모형을 이용한 전산시뮬레이션 검토: 방화막 및 무대부 자연배출구 영향)

  • Yang, Ji Hyun;Baek, Seon A;Lee, Chi Young;Kim, Duncan
    • Fire Science and Engineering
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    • v.33 no.5
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    • pp.37-47
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    • 2019
  • In the present study, the influences of the fire curtain and natural vent in a theater fire were investigated through the numerical simulation of a reduced-scale model of a theater fire using the Fire Dynamics Simulator (FDS). Based on a previous experimental study using the reduced-scale model, the 1/14 reduced-scale model and its conditions were constructed according to the law of similarity with a real-scale theater. Through a series of numerical simulations, the smoke movements were visualized, and the temperatures in the stage and auditorium, mass flow rate of the outflow through natural vent, and time at which smoke started moving toward the auditorium were measured and analyzed. The general trends on the effects of the fire curtain and natural vent during the theater fire predicted by the present numerical simulation were similar to the previous experimental results. For quantitative comparison of the present numerical simulation and previous experimental results, the mean percentage errors of temperatures in the stage and auditorium, and the mass flow rate of outflow through the natural vent were calculated. The present numerical simulation results showed good agreement with previous experimental results with reasonable accuracy.