• Title/Summary/Keyword: Rare Metal

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Recovery of Indium from Secondary Resources by Hydrometallurgical Method (2차(次) 자원(資源)으로부터 습식방법(濕式方法)에 의한 인듐의 회수(回收))

  • Wang, Lingyun;Lee, Manseung
    • Resources Recycling
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    • v.22 no.2
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    • pp.3-10
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    • 2013
  • Indium is one of the rare metals, and it has been used mainly for preparation of indium tin oxide (ITO). This review investigated the process parameters and the merits and demerits of several methods to recover indium from the leaching solution of secondary resources, such as solvent extraction, ion exchange, and precipitation. D2EHPA has been used mostly as a cationic extractant for indium extraction in moderate acid solutions, while amine extractants are used in strong hydrochloric acid solution. Since the loading capacity of resins for indium is generally small, ion exchange has some advantage over solvent extraction only when the concentration of indium is low.

Effects of Rare Earth Metal Addition on the Cavitation Erosion-Corrosion Resistance of Super Duplex Stainless Steels

  • 심성익;박용수;김순태;송치복
    • Transactions of Materials Processing
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    • v.8 no.3
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    • pp.301-301
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    • 1999
  • Austenitic stainless steels such as AISI 316L have been used in equipment in which fluid flows at high speeds which can induce cavitation erosion on metallic surfaces due to the collapse of cavities, where the collapse is caused by the sudden change of local pressure within the liquid. Usually AISI 316L is susceptible to cavitation erosion. This research focuses on developing a better material to replace the AISI 316L used in equipment with high speed fluid flow, such as impellers. The effects of Rare Earth Metal (REM) additions on the cavitation erosion-corrosion resistance of duplex stainless steels were studied using metallographic examination, the potentiodynamic anodic polarization test, the tensile test, the X-ray diffraction test and the ultrasonic cavitation erosion test. The experimental alloys were found to have superior mechanical properties due to interstitial solid solution strengthening, by adding high nitrogen (0,4%), as well as by the refinement of phases and grains induced by fine REM oxides and oxy-sulfides. Corrosion resistance decreases in a gentle gradient as the REM content increases. However, REM containing alloys show superior corrosion resistance compared with that of other commercial alloys (SAF 2507, AISI 316L). Owing to their excellent mechanical properties and corrosion resistance, the alloys containing REM have high cavitation erosion-corrosion resistance.

Distribution of Zirconium Between Salt And Bismuth During A Separation From Rare Earth Elements By A Reductive Extraction

  • S. W. Kwon;Lee, B. J.;B. G. Ahn;Kim, E. H.;J. H. Yoo
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.02a
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    • pp.165-169
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    • 2004
  • It was studied on the reductive extraction between the eutectic salt and Bi metal phases. The solutes were zirconium and the rare earth elements, where zirconium was used as the surrogate for the transuranic(TRU) elements. All the experiments were performed in a glove box filled with argon gas. Two types of experimental conditions were used -high and low initial solute concentrations in salt. Li-Bi alloy was used as a reducing agent to reduce the high chemical activity of Li. The reductive extraction characteristics were examined using ICP, XRD and EPMA analysis. Zirconium was successfully separated from the rare earth elements by the reductive extraction method. The LiF-NaF-KF system was favorable among the fluoride salt systems, whereas the LiCl-KCl system was favorable among the chloride salt systems. When the solute concentrations were high, intermetallic compounds were found near the salt-metal interface.

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Removal of Potassium from Molasses by Solvent Extraction and Ion Exchange

  • Wang, Lingyun;Nam, Sang-Ho;Lee, Manseung
    • Bulletin of the Korean Chemical Society
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    • v.35 no.9
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    • pp.2711-2716
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    • 2014
  • The high content of potassium in molasses limits its usage as a raw material for stock feed. Moreover, its high viscosity makes it difficult to develop an efficient removal process. In this study, ion exchange and solvent extraction experiments have been performed to investigate the removal of potassium from a mixture of molasses with water. Cationic exchange resins (AG50W-X8 and Diphonix) showed a high loading percentage of potassium but the occurrence of breakthrough in few bed volumes was a drawback to the industrial application. Among the cationic extractants (D2EHPA, PC 88A, Cyanex 272) tested in this study, saponified PC 88A was found to be the best extractant for the removal of potassium. Batch simulation studies on a three stage counter current extraction confirmed that 85% of potassium was removed from 50 wt % molasses solution in water by using saponifed PC 88A.

Occurrence and Petrogenesis of Phoscorite-Carbonatite Complexes in the Kola Alkaline Province, Arctic

  • Lee, Mi-Jung;Lee, Jong-Ik;Kim, Yea-Dong
    • Ocean and Polar Research
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    • v.25 no.1
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    • pp.119-128
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    • 2003
  • Although phoscorites and carbonatites form only a minor proportion of the earth's crustal rocks, these unusual rocks and their intimate relation are of both academic and economic importance. Rare metal (Nb, Zr, Ta) and REEs mineralizations are in close relation with the differentiation of these phoscorite-carbonatite complexes (PCCs). Recent integrated petrological and geochemical data on PCCs in the Kola Alkaline Province, Arctic, indicate that phoscorites and associated carbonatites are differentiated from common 'carbonated silicate patental magma'. Various hypotheses for the genesis of phoscorite-carbonatite complexes have been proposed during the last half-century. A simple magmatic fractionation scheme can not explain the chemical and mineralogical characteristics of phoscorite and conjugate carbonatite. Instead, the hypotheses involving liquid immiscibility and coeval accumulation processes are favored to explain the mineralogical and geochemical characteristics of phoscorite and carbonatite association.

Optical, Mechanical and Tribological Properties of $Y_2O_3$ $Er_2O_3$ and $Nd_2O_3$ Doped Polycrystalline Silicon Nitride Ceramics

  • Joshi, Bhupendra;Lee, Su-Wan
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.51.1-51.1
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    • 2010
  • $Y_2O_3$ $Er_2O_3$ and $Nd_2O_3$ doped polycrystalline silicon nitride were prepared by hot pressed sintering at $1850^{\circ}C$ and their optical transmittance were investigated in visible and in infrared region. Mechanical and tribological properties were also investigated. Grain growth in silicon nitride was reduced with addition of $Y_2O_3$ and $Nd_2O_3$. 1 wt.% of each rare earth metal were sintered with 3 wt.% MgO, 9wt.% AlN and 87 wt.% of ${\alpha}-Si_3N_4$. Adding these rare earth metal oxides shows good mechanical properties as high strength and toughness and also shows low friction coefficient.

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Development of Dark Field image Processing Technique for the Investigation of Nanostructures

  • Jeon, Jongchul;Kim, Kyou-Hyun
    • Journal of Powder Materials
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    • v.24 no.4
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    • pp.285-291
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    • 2017
  • We propose a custom analysis technique for the dark field (DF) image based on transmission electron microscopy (TEM). The custom analysis technique is developed based on the $DigitalMicrograph^{(R)}$ (DM) script language embedded in the Gatan digital microscopy software, which is used as the operational software for most TEM instruments. The developed software automatically scans an electron beam across a TEM sample and records a series of electron diffraction patterns. The recorded electron diffraction patterns provide DF and ADF images based on digital image processing. An experimental electron diffraction pattern is recorded from a IrMn polycrystal consisting of fine nanograins in order to test the proposed software. We demonstrate that the developed image processing technique well resolves nanograins of ~ 5 nm in diameter.

Novel Properties of Boron Added Amorphous Rare Earth-transition Metal Alloys for Giant Magnetostrictive and Magneto-optical Recording Materials

  • Jai-Young Kim
    • Journal of Magnetics
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    • v.3 no.3
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    • pp.78-81
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    • 1998
  • Large magneto crystalline anisotropy energy and demagnetization energy of rare earth-transition metal (RF-TM) alloys play roles of bottlenecks towards their commercial applications for giant magnetostrictive and blue wavelength magneto optical recording materials, respectively. To solve the above problems, boron is added into amorphous RE-TM alloys to produce its electron transferring. The boron added amorphous RE-TM alloys show novel magnetic and magneto-optical properties as follows; 1) an amorphous $(Sm_{33}Fe_{76})$97B3 alloy obtains the magnetostriction of$ -550{times}10^{-6}$ at 400 Oe compared with saturation magnetostriction of$ -60{\times}10^{-6}$ in conventional Ni based alloys, 2) an amorphous$ (Nd_{33}Fe_{67})_{95}B_5$ alloy increases effective magnetic anisotropy to$ -0.5{\times}10^{-6} ergs/cm^3 from -3.5{\times}10^6 ergs/cm^3$ without boron, which correspond to the polar Kerr rotation angles of 0.52$^{\circ}$and 0.33$^{\circ}$, respectively. These results attribute to selective 2p-3d electron orbits exchange coupling (SEC).

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