• Title/Summary/Keyword: Rare Earth

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Cryptic variation, molecular data, and the challenge of conserving plant diversity in oceanic archipelagos: the critical role of plant systematics

  • Crawford, Daniel J.;Stuessy, Tod F.
    • Korean Journal of Plant Taxonomy
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    • v.46 no.2
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    • pp.129-148
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    • 2016
  • Plant species on oceanic islands comprise nearly 25% of described vascular plants on only 5% of the Earth's land surface yet are among the most rare and endangered plants. Conservation of plant biodiversity on islands poses particular challenges because many species occur in a few and/or small populations, and their habitats on islands are often disturbed by the activity of humans or by natural processes such as landslides and volcanoes. In addition to described species, evidence is accumulating that there are likely significant numbers of "cryptic" species in oceanic archipelagos. Plant systematists, in collaboration with others in the botanical disciplines, are critical to the discovery of the subtle diversity in oceanic island floras. Molecular data will play an ever increasing role in revealing variation in island lineages. However, the input from plant systematists and other organismal biologists will continue to be important in calling attention to morphological and ecological variation in natural populations and in the discovery of "new" populations that can inform sampling for molecular analyses. Conversely, organismal biologists can provide basic information necessary for understanding the biology of the molecular variants, including diagnostic morphological characters, reproductive biology, habitat, etc. Such basic information is important when describing new species and arguing for their protection. Hybridization presents one of the most challenging problems in the conservation of insular plant diversity, with the process having the potential to decrease diversity in several ways including the merging of species into hybrid swarms or conversely hybridization may generate stable novel recombinants that merit recognition as new species. These processes are often operative in recent radiations in which intrinsic barriers to gene flow have not evolved. The knowledge and continued monitoring of plant populations in the dynamic landscapes on oceanic islands are critical to the preservation of their plant diversity.

The Relative and Absolute Speed of Radiographic Screen-Film Systems (증감지(增感紙)-필름계(系)의 상대감도(相對感度)와 절대감도(絶對感度)에 관한 실험(實驗))

  • Huh, Joon;Lee, In-Ja
    • Journal of radiological science and technology
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    • v.16 no.1
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    • pp.67-80
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    • 1993
  • Recently, a large number of new screen-film systems have become available for use in diagnostic radiology. These new screens are made of materials generally known as rare-earth phosphors which have high x-ray absorption and high x-ray to light conversion efficiency compared to calcium tungstate phosphors. The major advantage of these new systesms is reduction of patient exposure due to their high speed or high sensitivity. However, a system with excessively high speed can result in a significant degradation of radiographic image quality. Therefore, th speed is important parameters for users of these system. Our aim of in this was to determine accurately and precisely the absolute speed and relative speeds of both new and conventional screen-film system. We determined the absolute speed in condition of BRH phantom beam qulity and the relative speed were measured by a split-screen technique in condition of BRH and ANSI phantom beam qulity. The absolute and the relative speed were determined for 8 kinds of screen-4 kinds of film in regular system and 7 kinds of screen-7 kinds of film in ortho system. In this study we could know the New Rx, T-MAT G has the highest film speed, also know Green system's stndard deviation of relative speed larger than blue system. It was realized that there were no relationship between the absolute speed and the blue system. It was realized that there were no relationship between the absolute speed and the relative speed in ortho or regular system.

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Study on the Synthesis of HoN Nanoparticles and Magnetocaloric Effect as Magnetic Refrigerant for Hydrogen Re-Liquefaction (수소재액화를 위한 자기냉매용 HoN 나노분말 합성 및 자기열량효과 연구)

  • Kim, Dongsoo;Ahn, Jongbin;Jang, Sehoon;Chung, Kookchae;Kim, Jongwoo;Choi, Chuljin
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.6
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    • pp.594-601
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    • 2014
  • Rare-earth (RE) nitrides can be used as magnetocaloric materials in low temperature. They exhibit ferromagnetism and have Curie temperature in the region from 6 to 70 K. In this study, Holmium nitride (HoN) nano particles were prepared through plasma arc discharge technique and their magnetocaloric properties were studied. Nitrogen gas ($N_2$) was employed as an active element for arc discharge between two electrodes maintained at a constant current. Also, it played an important role not only as a reducing agent but also as an inevitable source of excited nitrogen molecules and nitrogen ions for the formation of HoN phase. Partial pressure of $N_2$ was systematically varied from 0 to 28,000 Pa in order to obtain single phase of HoN with minimal impurities. Magnetic entropy change (${\Delta}S_m$) was calculated with data set measured by PPMS (Physical Property Measurement System). The as-synthesized HoN particles have shown a magnetic entropy change ${\Delta}S_m$) of 27.5 J/kgK in applied field of 50,000 Oe at 14.2 K thereby demonstrating its ability to be applied as an effective magnetic refrigerant towards the re-liquefaction of hydrogen.

Spectrophotometric Determination of Lanthanide Ions by Flow Injection Analysis (Flow Injection Analysis에 의한 란탄족 이온들의 흡광광도 정량)

  • Kang, Sam-Woo;Cho, Kwang-Hee
    • Analytical Science and Technology
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    • v.9 no.3
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    • pp.244-252
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    • 1996
  • Spectrophotometric properties of lanthanide complexes with methylthymol blue(MTB) and cetyltrimethylammonium bromide(CTAB) were studied and also lanthanide(III) ions were determined by flow injection analysis on the base of the above results. The absorption maxima of lanthanide(III)-MTB complexes in the presence of CTAB are 635nm with molar absorptivity of $4.51{\sim}6.11{\times}10^4Lmol^{-1}cm^{-l}$ at pH 5.8. The mole ratio of lanthanide(III) complexes with MTB is 1:2 in the presence of CTAB. The calibration curves of lanthanide(III) ions obey the Beer's law in the range of 0.1 to 0.4ppm under the optimum condition. The samples throughput was ca. $60hr^{-1}$. The interfering effect of some cations and anions was investigated. The ligand anions such as tartrate and citrate, many transition and rare earth elements interfered severely and must be removed before the determination of lanthanide(III) ions.

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Leaching Kinetics of Yttrium Extraction from Coal Fly Ash using Sulfuric Acid

  • Kim, Jae-kwan;Park, Seok-un;Hong, Jun-seok;Shin, Dong-ik;Jeong, Jae-hyeok
    • KEPCO Journal on Electric Power and Energy
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    • v.3 no.1
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    • pp.29-34
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    • 2017
  • Leaching kinetics for extracting yttrium from the coal fly ash was investigated in the presence of sulfuric acid during extraction. The leaching kinetics of yttrium were conducted at reactant densities of 5~1,000 g coal fly ash per L of $1.0{\sim}10.0N\;H_2SO_4$, agitation speed of 250 rpm and temperature ranging from 30 to $90^{\circ}C$. As a result, the leaching kinetic model was determined in a two-step model based on the shrinking core model with spherical particles. The first step was proceeded by chemical reaction at ash surface, and the second step was proceeded by ash layer diffusion because the leaching conversion of yttrium by the first chemical reaction increases with increased the time irrelevant to the temperature whereas it increases with increased the leaching temperature. The activation energy of the first chemical leaching step was determined to be $1.163kJmol^{-1}$. After the first chemical reaction, the activation energy of ash layer diffusion leaching was derived to be $41.540kJmol^{-1}$. The optimum conditions for leaching the yttrium metal of 60 % were found to be the slurry density of 250 g fly ash per L of $H_2SO_4$, solvent concentration of $2.0N\;H_2SO_4$, second step leaching of temperatures of $30^{\circ}C$ for 3 hours and then $90^{\circ}C$ for 3 hours at agitation rate of 250 rpm.

Development of a Cost-Effective Process for the Fabrication of Single Grain $YBa_2Cu_3O_{7-y}$ Bulk Superconductors (단결정 $YBa_2Cu_3O_{7-y}$ 벌크 초전도체 제조를 위한 경제적 공정의 개발)

  • Park, Soon-Dong;Kim, Kwang-Mo;Jun, Byung-Hyuk;Han, Young-Hee;Kim, Chan-Joong
    • Progress in Superconductivity
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    • v.13 no.2
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    • pp.133-138
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    • 2011
  • To reduce the processing cost of the single grain REBCO (RE: Rare-earth elements) bulk superconductors, a cost-effective process should be developed. One possible way of developing the cost-effective process is the use of low-cost precursor powders. In this study, the single grain YBCO superconductors were fabricated using a home made powder. $YBa_2Cu_3O_{7-y}$ (Y123) powders were synthesized at $850-900^{\circ}C$ in air by the powder calcination method with repeated crushing and heat treatment steps. The processing parameters for the fabrication of single grain Y123 bulk superconductors, $T_{max}$ (maximum temperature), $T_p$ (peritectic temperature) and a cooling rate through $T_p$ were optimized. To enhance the flux pinning capacity of the single grain Y123 samples, $Y_2BaCuO_5$ (Y211) particles were dispersed in the Y123 matrix by adding $Y_2O_3$ powder to the calcined Y123 powder. Applying the optimized processing condition, the single grain Y123 superconductors with $T_c=91\;K$ and $J_c=1.5{\times}10^4\;A/cm^2$ at 2 T were successfully fabricated using a home made powder. The levitation forces and trapped magnetic field at 77 K measured using a Nd-B-Fe permanent magnet of 5300 G were 47 N and 3000 G, respectively, which are comparable to those obtained for the samples fabricated using a commercial grade Y123 powders.

Fe-REE Mineralization of the Hongcheon-Jaeun District (홍천-자은지역 철-희토류광상의 광화작용)

  • 김상중;이현구;윤경무;박중권
    • Economic and Environmental Geology
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    • v.34 no.4
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    • pp.319-328
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    • 2001
  • The Fe-REE deposit of the Hongcheon-Jaeun district occurs in Precambrian gneiss, and is classified into two ore bodies: the Jaeun ore body (northern ore body) and the Hongcheon ore body (southern ore body). Ecomonically important minerals consist of magnetite, monazite, strontianite and barite. Based on mineral assemblages and textures, the mineralization can be classified into two stages (Na-carbonatite stage and Fe-carbonatite stage). Main REE minerals were precipitated during the Fe-carbonatite stage. Some evidences of the carbonatite origin include: 1) strontianite-monazite exolution texture, 2) strontianite-barite exolution texture, 3) the occurrence of acmite of igneous origin at the area with abundant rare earth minerals, 4) the occurrence of the mineral assemblage consisting of carbonate minerals + magnetite + REE minerals. Therefore, we suggest that Fe-REE mineralization in the study area was related to carbonatite of igneous origin.

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Phase Evolution and Thermal Conductivities of (La1-xGdx)2Zr2O7 Oxides for Thermal Barrier Coatings (열차폐코팅용 (La1-xGdx)2Zr2O7 산화물의 상형성과 열전도도)

  • Kwon, Chang-Sup;Lee, Sung-Min;Oh, Yoon-Suk;Kim, Hyung-Tae;Jang, Byung-Koog;Kim, Seong Won
    • Journal of Powder Materials
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    • v.19 no.6
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    • pp.429-434
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    • 2012
  • With increase in operating temperature of gas turbine for higher efficiency, it is necessary to find new materials of TBC for replacement of YSZ. Among candidate materials for future TBCs, zirconate-based oxides with pyrochlore and fluorite are prevailing ones. In this study, phase structure and thermal conductivities of $(La_{1-x}Gd_x)_2Zr_2O_7$ oxide system are investigated. $(La_{1-x}Gd_x)_2Zr_2O_7$ system are comprised by selecting $La^{3+}/Gd^{3+}$ as A-site ions and $Zr^{4+}$ as B-site ion in $A_2B_2O_7$ pyrochlore structures. With powder mixture from each oxide, $(La_{1-x}Gd_x)_2Zr_2O_7$ oxides are fabricated via solid-state reaction at $1600^{\circ}C$. Either pyrochlore or fluorite or mixture of both appears after heat treatment. For the developed phases along $(La_{1-x}Gd_x)_2Zr_2O_7$ compositions, thermal conductivities are examined, with which the potential of $(La_{1-x}Gd_x)_2Zr_2O_7$ compositions for TBC application is also discussed.

Electrorefining Characteristics of Uranium by Using a Graphite Cathode (흑연 전극을 이용한 우라늄 전해정련 특성)

  • Kang, Young-Ho;Lee, Jong-Hyeon;Hwang, Sung-Chan;Shim, Joon-Bo;Kim, Eung-Ho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.1
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    • pp.1-7
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    • 2007
  • Electrorefining experiments were successfully carried out in LiCl-KCl eutectic molten salt with a graphite cathode. It was found that the formation of Uranium-Graphite intercalation compound(U-GIC) helped the self-scraping mechanism of the uranium dendrite and the efficiency of the electrorefiner increased due to an elimination of the stripping step. The contaminations of the uranium deposit by rare earth elements was negligible while about 300 ppm of carbon was observed. The carbon contamination is believed to be eliminated by further purification by yttrium reaction. The morphology characteristics of the recovered U deposit was compared to that of steel cathode. These are only qualitative preliminary experimental results, but we believe that further research on this type of activity change the direction of the electrorefining research on spent nuclear fuel.

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A Scientific Study on the Characteristics of Ridge-end Tiles from the Temple Sites in the Period of the Sabi Baekje (사비백제시기 사찰지 출토 치미 특성에 대한 과학적 연구)

  • Lee, Minhee;Hwang, Hyunsung;Shin, Yeonhong
    • Journal of Conservation Science
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    • v.35 no.5
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    • pp.430-439
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    • 2019
  • This study investigates the characteristics of ridge-end tiles excavated from temple sites in Sabi Baekje. Analyses were carried out to evaluate the chemical and mineralogical compositions of the excavated samples. All the samples except one from the Gunsu-ri temple exhibit a similar element distribution pattern in rare earth element contents. However, major and trace element contents differ because the mixing method used in each sample depends on the type of ridge-end tile. The mineral components of the tiles were grouped into three types, irrespective of the excavated areas. Group 2 and 3 were probably developed in high-temperature fires in comparison with Group 1; this is verified by the Fe2O3 content of more than 5 wt% in these samples. In conclusion, the raw materials utilized in each ridge-end tile are prone to have changed according to the time of use of the tile, regardless of the excavated site.