• Title/Summary/Keyword: Rare Earth

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Study of Material Characteristics by a Componential Analysis on the Whiteware from the Kiln of Chiljeon-ri, Bangsan-myeon, Yanggu-gun (양구 방산 칠전리 출토 백자의 성분분석을 통한 원료특성 연구)

  • Ahn, Songyee;Hwang, Hyunsung
    • Journal of Conservation Science
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    • v.29 no.3
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    • pp.261-277
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    • 2013
  • This study aims to research the relationship between whitewares and their rare materials from the site of Yanggu and Bunwon through the componential characteristic of the excavated whitewares from the 1st and the 2nd kilns of Chiljeon-ri in Bangsan-myeon, Yanggu-gun. As a result, the sherds were devided according to the chemical compositions of the body and the glaze via their respective production era. However, it considered that the whitewares from Chiljeon-ri had been manufactured with geochemically similar materials and the production process, such as refining and combining materials, had been different. It assumed that the firing temperatures of the whitewares from Chiljeon-ri were around $1,100-1,200^{\circ}C$ and substantially lower than for general whitewares. In the componential analysis, there were disparate properties in the cobalt pigment, which contained trace elements and rare earth elements. A review of the literature revealed a correlation between the whitewares from the late Chosun kiln site in Bunwon-ri and the raw materials from Yanggu-gun, but this was there were various techniques for refining and combining materials in Bunwon-ri.

Studies on the New Analytical Methods for Separation and Recovery of Rare Earth Metals (I) : Adsorption Characteristics of U(VI) Ion by New Synthetic Resins with Macrocyclic Compounds (희토류금속 분리 및 회수를 위한 분석화학적 연구 (제1보) : 우라늄(VI)의 분리회수를 위한 선택이온교환수지 합성과 우라늄(VI) 금속이온의 흡착특성)

  • Jung Oh Jin;Hak Jin Jung;Joon Tea Kim
    • Journal of the Korean Chemical Society
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    • v.32 no.4
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    • pp.358-370
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    • 1988
  • Several new ion exchange resins have been synthesized from chloromethyl styrene-1,4-divinylbenzene(DVB) with 1%, 2%, 4%, and 10%-crosslinking and macrocyclic ligands of cryptand type by interpolymerization method. The adsorption characteristics and the pH, time, solvents and concentration dependence of the adsorption of metal ions by this resin were studied. The correlation between the separation characteristics of uranium, rare earths and transition metal on the resins and the stability constants of complexes with macrocyclic ligands have been examined. The resins were very stable in both acidic and basic media and have good resistance to heat at $280^{\circ}C$. The $UO_2^{+2}$ aqueous solution are not adsorbed on the resins below pH 3.0, but the power of adsorption of $UO_2^{2+}$ increased rapidly above pH 4.0. The optimum equilibrium time for adsorption of metallic ions was twenty minutes and adsorptive power decreased in proportion to crosslinking size of the resins and order of dielectric constants of solvents used and the selective sequence for metal cations is in the order of $UO_2^{2+},\;Cu^{2+}\;and\;Nd^{3+}$.

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GG Tauri A: gas properties and dynamics from the cavity to the outer disk

  • Nguyen, Thi Phuong;Dutrey, Anne;Pham, Ngoc Diep;Chapillon, Edwige;Guilloteau, Stephane;Lee, Chang Won;Di Folco, Emmanuel;Majumdar, Liton;Bary, Jeff;Beck, Tracy L.;Coutens, Audrey;Denis-Alpizar, Otoniel;Melisse, Jean-Paul;Pietu, Vincent;Stoecklin, Thierry;Tang, Yei-Wen
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.38.2-39
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    • 2021
  • I will presents the analysis of the gas properties of the protoplanetary disk surrounding the young low-mass (about 1.2Msun) triple star, GG Tau A. This work makes use of ALMA observations of rotational lines of CO (12CO, 13CO and C18O) together NOEMA observations of a few dozens of other molecules. While the CO emission gives information on the molecular layer close to the disk atmosphere, its less abundant isotopologues 13CO and C18O bring information much deeper in the molecular layer. I will present the analysis of the morphology and kinematics of the gas disk using the CO isotopologues. A radiative transfer model of the ring in CO isotopologues will also be presented. The subtraction of this model from the original data reveals the weak emission of the molecular gas lying inside the cavity. Thus, I am able to evaluate the properties of the gas inside the cavity, such as the gas dynamics, excitation conditions, and the amount of mass in the cavity. High angular resolution observations of CO reveals sprials induced by embedded planet(s) located near the 3:2:1 mean-motion resonance that help to explain the special morphology of the circumbinary disk. I also discuss some chemical properties of the GG Tau A disk. I report the first detection of H2S and C2S in a protoplanetary disk. The molecule abundance relative to 13CO of about twenties other molecules will also be given. In GG Tau A, the detections of rare molecules such as H2S and C2S have been probably possible because the disk is more massive (a factor about 3-5) than other disks where the molecules was searched. Such a large disk mass makes the system suitable to detect rare molecules and to study cold-chemistry in protoplanetary disks.

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Engineering Geological Implications of Fault Zone in Deep Drill Cores: Microtextural Characterization of Pseudotachylite and Seismic Activity (시추코어 단층대에서의 지질공학적 의미: 슈도타킬라이트의 미세조직의 특징과 지진활동)

  • Choo, Chang-Oh;Jeong, Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.27 no.4
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    • pp.489-500
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    • 2017
  • It is not rare that pseudotachylite, dark colored rock with glassy texture, is recognizable in deep core samples drilled up to 900 m from the surface. Pseudotachylite with widths varying few to 20 cm is sharply contacted or interlayered with the host rocks composed of Jurassic granite and Precambrian amphibolite gneiss, showing moderately ductile deformation or slight folding. Pseudotachylite occurring at varying depths in the deep drill core are slightly different in texture and thickness. There is evidence of fault gouge at shallower depths, although brittle deformation is pervasive in most drill cores and pseudotachylite is identified at random depth intervals. Under scanning electron microscope (SEM), it is evident that the surface of pseudotachylite is characterized by a smooth, glassy matrix even at micrometer scale and there is little residual fragments in the glass matrix except microcrystals of quartz with embayed shape. Such textural evidence strongly supports the idea that the pseudotachylite was generated through the friction melting related to strong seismic events. Based on X-ray diffraction (XRD) quantitative analysis, it consists of primary minerals such as quartz, feldspars, biotite, amphibole and secondary minerals including clay minerals, calcite and glassy materials. Such mineralogical features of fractured materials including pseudotachylite indicate that the fractured zone might form at low temperatures possibly below $300^{\circ}C$, which implies that the seismic activity related to the formation of pseudotachylite took place at shallow depths, possibly at most 10 km. Identification and characterization of pseudotachylite provide insight into a better understanding of the paleoseismic activity of deep grounds and fundamental information on the stability of candidate disposal sites for high-level radioactive waste.

Geology and Constituent Rocks, and Radioactive Values of the Eoraesan Area, Chungju, Korea (충주 어래산지역의 지질 및 구성암류와 방사능 값)

  • Kang, Ji-Hoon;Lee, Deok-Seon;Koh, Sang-Mo
    • The Journal of the Petrological Society of Korea
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    • v.27 no.2
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    • pp.85-96
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    • 2018
  • The Neoproterozoic Gyemyeongsan Formation and the Mesozoic igneous rocks are distributed in the Eoraesan area, Chungju which is located in the northwestern part of Ogcheon metamorphic zone, Korea, and the rare earth element (REE) mineralized zone has been reported in the Gyemyeongsan Formation. We drew up the detailed geological map by the lithofacies classification, and measured the radioactivity values of the constituent rocks to understand the distribution and characteristics of the source rocks of REE ore body in this paper. It indicates that the Neoproterozoic Gyemyeongsan Formation is mainly composed of metapelitic rock, granitic gneiss, iron-bearing quartzite, metaplutonic acidic rock (banded type, fine-grained type, basic-bearing type, coarse-grained type), metavolcanic acidic rock, and the Mesozoic igneous rocks, which intruded it, are divided into pegmatite, biotite granite, gabbro, diorite, basic dyke. The constituent rocks of Gyemyeongsan Formation show a zonal distribution of mainly ENE trend, and the distribution of basic-bearing type of metaplutonic acidic rock (MPAR-B) is very similar to that of the previous researcher's REE ore body. The Mesozoic biotite granite is regionally distributed unlike the result of previous research. The radioactive value of MPAR-B, which has a range of 852~1217 cps (average 1039 cps), shows a maximum value among the constituent rocks. The maximum-density distribution of radioactive value also agrees with the distribution of MPAR-B. It suggests that the MPAR-B could be a source rock of the REE ore body.

Design and Development of a Granite Information System Prototype (화강암정보시스템의 설계 및 구축)

  • Hwang, Jae-Hong;Chi, Kwang-Hoon;Cheong, Won-Seok;Hong, Yong-Kuk;Ryu, Keun-Ho
    • Economic and Environmental Geology
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    • v.40 no.2 s.183
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    • pp.251-262
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    • 2007
  • The purpose of this research is to develop a Geological Information System(GIS) in order to store, manage and display geochemical data observed from references of recently domestic granite. There is still no use in geochemical and mineralogical information such as REE(rare earth element), trace elements, mode data(modals or mineral composition) and major elements. Therefore, we need to construct the standardized database system for the analytical data of granites through the verification of its data in South Korea. To construct the information system for geochemical and mineralogical information of granites in South Korea. Firstly, we collected the existing research data related digital map data. Secondly, we extract granite polygons to digital geological map and convert the polygon to points in South Korea. Thirdly, we considered both database schema and symbols of REE elements, trace elements, modal data and major mineral. Fourthly, we carried out all sorts of process to build granite database for GIS statistic analysis and visualization.

Development of Geochemical Tracers to Identify a Specific Source Region of Mineral Dust in China and Preliminary Test of Their Applicability (중국 기원 광물성 먼지 입자의 지화학 추적자 개발 및 기초 적용연구)

  • Lee, Sojung;Hyeong, Kiseong;Kim, Wonnyon;Kim, Tae-Hoon
    • Ocean and Polar Research
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    • v.41 no.3
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    • pp.169-181
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    • 2019
  • The purpose of this study is to develop geochemical tracers to identify a specific source desert of mineral dust in China using the published data. In addition, we tested the applicability of these tracers to wet-deposits and soil samples collected in Jeju, Korea. Because of similarity in trace elemental compositions of mineral dust from the major arid regions in China, such as Taklimakan, West Ordos (Badain Jaran), East Ordos (Mu Us and Hobq), East Northern China (Horqin), West Northern China (Gurbantunggut), and Chinese Loess Plateau, there has been limited to the use of geochemical data for source identification. Here we propose the four (4) plots using combination of seven (7) geochemical variables as a source indicator to distinguish one from other source regions in China: $\frac{Y}{Tb_N}$ vs. $\frac{Th}{{\Sigma}REE_N}$, $\(\frac{La}{Gd}\)_N$ vs. $\frac{Y}{{\Sigma}REE_N}$, $\frac{Th}{Tb_N}$ vs. $\frac{Y}{Nd_N}$, and $\frac{Th}{Tb_N}$ vs. $\(\frac{Ce}{Ce}\)_N^*$, where $_N$ and $\(\frac{Ce}{Ce}\)_N^*$ stand for values normalized to Post-Archean Average Shale composition and Ce anomaly, respectively. Mineral dusts from aforementioned six major deserts are distinguished one from the others by the combined use of these variables. Jeju rock and soil samples form a separate domain from Chinese mineral dusts in all four plots. In contrast, most of Jeju dust samples were comparable with the West Ordos desert (Badain Jaran) domain, indicative of strong influence of Badain Jaran dust in Jeju in spring season when the mineral dust was collected. A weak positive Ce anomaly in Jeju samples implies minimal local contribution. Our study suggests that the combination of $\frac{Y}{Tb_N}$ vs. $\frac{Th}{{\Sigma}REE_N}$, $\(\frac{La}{Gd}\)_N$ vs. $\frac{Y}{{\Sigma}REE_N}$, $\frac{Th}{Tb_N}$ vs. $\frac{Y}{Nd_N}$, and $\frac{Th}{Tb_N}$ vs. $\(\frac{Ce}{Ce}\)_N^*$ can be used to identify a specific source region of mineral dust in China as well as Jeju mineral particles.

A Study on the Luminescence Properties of Eu3+ Ions Doped Vanadate (Eu3+ 이온이 첨가된 바나듐산염의 형광특성 연구)

  • Kang, Yeonhee;Yoon, Changyong
    • Journal of the Korean Society of Radiology
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    • v.13 no.3
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    • pp.445-451
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    • 2019
  • The fluorescence intensity and fluorescence lifetime of $Ba_2GdV_3O_{11}$, a vanadate compound based on $Ba^{2+}$ ion, were investigated by adding $Eu^{3+}$ as a rare earth ion which is an alkaline earth metal, which is distributed around active ions and has a large influence on fluorescent properties when used as a host in a phosphor. $Ba_2GdV_3O_{11}:Eu^{3+}$ phosphor was synthesized by solid state method and the crystallinity of the phosphor was confirmed by X - ray diffraction analysis. The fluorescence properties of the $Ba_2GdV_3O_{11}:Eu^{3+}$ phosphor were measured using optical and laser. The energy transfer and diffusion of the $Ba_2GdV_3O_{11}:Eu^{3+}$ phosphor are highly dependent on the concentration of $Eu^{3+}$. When the concentration of $Eu^{3+}$ is low, it shows strong fluorescence to the CT band. However, as the concentration of $Eu^{3+}$ increases, the fluorescence due to 4f - 4f transition is strong. The concentration of $Eu^{3+}$ ion increased and the energy between ions was diffused, and the lifetime of fluorescence decreased. Energy transfer occurs between two $Eu^{3+}$ ions at low $Eu^{3+}$ concentration and energy diffusion occurs at high $Eu^{3+}$ concentration.

Rendezvous Mission to Apophis: IV. Investigation of the internal structure - A lesson from an analogical asteroid Itokawa

  • Jin, Sunho;Kim, Yaeji;Jo, Hangbin;Yang, Hongu;Kwon, Yuna G.;Ishiguro, Masateru;Jeong, Minsup;Moon, Hong-Kyu;Choi, Young-Jun;Kim, Myung-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.58.1-59
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    • 2021
  • Exploration of asteroids' internal structure is essential for understanding their evolutional history. It also provides a fundamental information about the history of coalescence and collision of the solar system. Among several models of the internal structures, the rubble-pile model, confirmed by the near-Earth asteroid (25143) Itokawa by Hayabusa mission [1], is now widely regarded as the most common to asteroids with size ranging from 200 m to 10 km [2]. On the contrary, monolithic and core-mantle structures are also possible for small asteroids [3]. It is, however, still challenging to look through the interior of a target object using remote-sensing devices. In this presentation, we introduce our ongoing research conducted at Seoul National and propose an idea to infer the internal structure of Apophis using available instruments. Itokawa's research provides an important benchmark for Apophis exploration because both asteroids have similar size and composition [4][5]. We have conducted research on Itokawa's evolution in terms of collision and space weathering. Space weathering is the surface alteration process caused by solar wind implantation and micrometeorite bombardment [6]. Meanwhile, resurfacing via a collision acts as a counter-process of space weathering by exposing fresh materials under the matured layer and lower the overall degree of space weathering. Therefore, the balance of these two processes determine the space weathering degrees of the asteroid. We focus on the impact evidence on the boulder surface and found that space weathering progresses in only 100-10,000 years and modifies the surface optical properties (Jin & Ishiguro, KAS 2020 Fall Meeting). It is important to note that the timescale is significantly shorter than the Itokawa's age, suggesting that the asteroid can be totally processed by space weathering. Accordingly, our result triggers a further discussion about why Itokawa indicates a moderately fresh spectrum (Sq-type denotes less matured than S-type). For example, Itokawa's smooth terrains show a weaker degree of space weathering than other S-type asteroids [7]. We conjecture that the global seismic shaking caused by collisions with >1 mm-sized interplanetary dust particles induces granular convection, which hinders the progression of space weathering [8]. Note that the efficiency of seismic wave propagation is strongly dependent on the internal structure of the asteroid. Finally, we consider possible approaches to investigate Apophis's internal structure. The first idea is studying the space weathering age, as conducted for Itokawa. If Apophis indicates a younger age, the internal structure would have more voids [9]. In addition, the 2029 close encounter with Earth provides a rare natural opportunity to witness the contrast between before and after the event. If the asteroid exhibits a slight change in shape and space weathering degree, one can determine the physical structure of the internal materials (e.g., rubble-pile monolithic, thick or thin regolith layer, the cohesion of the materials). We will also consider a possible science using a seismometer.

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Students' Characteristics of the Reflective Inquiry Dispositions According to the Modes of Interaction of Small Group in High School Earth Science Inquiry Class (고등학교 지구과학 탐구활동에서 소그룹의 상호작용 양식에 따른 학생들의 반성적 탐구의 특성)

  • Park, Mi-Ra;Jeong, Jin-Woo;Cheong, Cheol
    • Journal of The Korean Association For Science Education
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    • v.26 no.7
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    • pp.843-855
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    • 2006
  • The purpose of this study was to understand the substance of the reflective inquiry of students and obtain educational suggestion to the inquiry class for the promotion of the reflective inquiry, by checking out which characteristics the reflective inquiry showed according to the modes of interaction of small group in highschool earth science inquiry class. The result of study is shown as follows. At the stage of developmentand conclusion, the reflective inquiry relating the task context to data context was often appeared on the group of the modes of comfort interaction, but it was very rare on the group of modes of confrontation interaction. And the reflective inquiry scale value of the latter was two times lower than the former, The comfort group showed much more reflective inquiry statements quantitatively and performed much more meaningful reflective inquiry relating the task context to the data context. The heterogeneous group in the inquiry ability and the cognitive style showed confrontation interaction modes in the affective domain, having the most negative influence on the reflective inquiry. The homogeneous group both in the cognitive style and the inquiry ability showed the comfort interaction mode, having positive int1uence on the reflective inquiry.