• Title/Summary/Keyword: Rare Earth

Search Result 974, Processing Time 0.033 seconds

Growth of 1 inch $LuVO_4$ single crystals by the edge-defined film-fed-growth (EFG) technique

  • Kochurikhin, V.V.;Klassen, A.V.;Kvyat, E.V.;Ivanov, M.A.
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.15 no.6
    • /
    • pp.222-224
    • /
    • 2005
  • In suite of their superior optical and laser properties rare-earth orthovanadate single crystals have not been adopted yet into extensive industrial applications because of crystal growth difficulties. The edge-defined film-fed-growth (EFG) technique was applied successfully for the production of such crystals. At first time 1 inch $LuVO_4$ single crystals were grown by the EFG technique using newly developed die construction of high porous iridium with the application of automatic diameter control system.

Determination of Rare Earth Elements in USGS Geological Materials by ICP/AES (ICP/AES에 의한 지질시료 중의 희토류원소 분석)

  • 김정석;최광순;박용준;지광용
    • Journal of the Korean Chemical Society
    • /
    • v.39 no.2
    • /
    • pp.28-81
    • /
    • 1995
  • Inductively coupled plasma atomic emission spectrometry was used for the determination of all 14 rare earth elements (REE) in geological materials. Samples were decomposed by using acid digestion followed by alkaline fusion. Group separation of the REE was achieved by solvent extraction with TOPO (trioctylphosphine oxide) and back extraction into HCl. The results for standard rock sample, AGV-1, showed a good agreement with those obtained by US Geological Survey as well as reported values in other articles.

  • PDF

Infrared Transmitting Glass Ceramics for Passive and Active Applications

  • Zhang, Xianghua;Adam, J.L.
    • Ceramist
    • /
    • v.10 no.3
    • /
    • pp.48-54
    • /
    • 2007
  • Glass-ceramics transparent above $10\;{\mu}m$ in the infrared, have been synthesized. They are based on germanium and antimony sulphides or selenides associated to alkali halides. They are prepared by heating glass samples at temperatures above the glass transition, as a function of time. Ceramisation can be controlled, so that sub-100 nm crystals are generated in the glass matrix. Then, low light scattering is achieved and the transparency window of the original glass is maintained. When gallium sulphide is added, glass ceramics can be doped with rare-earth ions. Emissions from the $^4F_{3/2}$ and $^4I_{13/2}$ of $Nd^{3+}$ and $Er^{3+}$ ions, respectively, are more intense in glass-ceramics, as compared to their vitreous counterpart. Examination of band profiles and decaytimes show that rare-earth ions are embedded in both crystalline and glassy environments.

  • PDF

Decolorization of Dyeing Wastewater with Use of Chitosan Materials

  • Xin, Chen;Sun, Hui-Li;Pan, Jia-Hui
    • Ocean Science Journal
    • /
    • v.41 no.4
    • /
    • pp.221-226
    • /
    • 2006
  • More attention has been paid to the research on decolorization of dyeing wastewater nowadays. In this study, an investigation into the decolorization of dyeing wastewater was conducted using a combination of coagulant, carboxymethyl chitosan (NOCC) and coagulant aid, polyscrylamide (PAM). The factors influencing the decolorization efficiency, such as pH value, coagulant and the dosages of coagulant, were discussed. The results showed that using PAM as coagulant aid could reach a high decolorization efficiency compared with using NOCC alone. The optimal conditions were pH 2.3, 480 mg/L for NOCC, and 4-8 mg/L for PAM. Under the optimum conditions, the rate of decolorization could achieve 99%, and the removal of chemical oxygen demand (COD) could achieve 90%. In addition, the membrane processes with chitosan/rare-earth-metals could enhance the decolorization rate of Direct Black FF to 94.7%, and Indanthren Red F3B to 98.2%, respectively.

Luminescence properties of Er/PbS encapsulated by phenyl modified silica via Sol-Gel Process (Phenyl modified silica에 졸-겔 캡슐화 된 Er/PbS의 발광 특성)

  • Ham, Gyeong-Guk;Ahn, Bok-Yeop;Seok, Sang-Il
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2003.11a
    • /
    • pp.146-146
    • /
    • 2003
  • If rare earth ions could be activated by electrical means after introducing into an appropriate semiconductor host, it might be possible to achieve the electrically-driven optical amplifier. Futhermore, some groups report that rare earth doped semiconductor nanoparticls show the sensitized emission. In this study, we try to prepare the Er/PbS nanoparticles encaupsulated by phenyl modified silica shell via sol-gel process. Er/PbS nanoparticles were characterized by UV-vis absorption, XRD, FT-IR and TEM etc. Finally we will present the luminescence properties of Er doped PbS nanoencapsulation.

  • PDF

Catalytic Activity of Commercial Metal Catalysts on the Combustion of Low-concentration Methane (저농도 메탄 연소에서 상용 금속촉매의 활성)

  • Lee Kyong-Hwan;Park Jae-Hyun;Song Kwang-Sup
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.21 no.6
    • /
    • pp.625-630
    • /
    • 2005
  • This study was focused on the catalytic activity for the combustion of low-concentration methane using various commerical catalysts (six transition metal catalysts in Russia and one rare earth metal (Honeycomb) catalyst in Korea). Catalytic activity was strongly influenced by the type and loading content of metal supported in catalyst. Catalytic performance showed the highest activity in Honeycomb catalyst including rare earth metal, which was the most expensive catalyst, while the next was the catalyst supported Cu with high content (AOK-78-52) and also that supported Cr and Co (AOK-78-56). However, both AOK-78-52 and AOK-78-56 catalysts that were very cheap had lower activation energy than Honeycomb catalyst. In the economical field, both AOK-78-52 and AOK-78-56 catalysts with transition metals showed a good alternative catalyst on the combustion of methane.

Sulfurization of Rare-Earth Oxides Using $H_2S$ and $SC_2$

  • Sato, Nobuaki;Sato, Soichi
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 2004.02a
    • /
    • pp.60-63
    • /
    • 2004
  • Sulfurization of rare-earth oxides R203 (R=Nd, Eu) using sulfurizing reagents, such as $H_2S$ and $SC_2$was examined for the sulfide magnetic separation of spent fuel. $EU_2O_3$was found to react with H$_3$S gas forming the mixture of $EU_2O_2S$ and EuS at 500 oC, while EuS was formed by $SC_2$ at 800 oC. In the case of the mixture of $R_2O_3$and $UO_2$, EuS and $ND_3S_4$ were formed as well as $EU_2O_2S$ and $Nd_2O_2S$ at 500oC in $H_2S$, though $UO_2$ remained unreacted.

  • PDF

Electrical Property of $BaTiO_3$ Ceramics(II) ($BaTiO_3$ 세라믹의 전기적성질(II))

  • 윤기현;송효일;윤상옥;이형복
    • Journal of the Korean Ceramic Society
    • /
    • v.18 no.2
    • /
    • pp.75-78
    • /
    • 1981
  • The electrical conductivity of $(M_2O_3)_x (BaTiO_3)_{1-x}$ has been measured over the temperature range of 30 to 27$0^{\circ}C$. The substitution of rare earth oxide such as $La_2O_3$, $Nd_2O_3$, or $Dy_2O_3$ can be represented by $M_2O_3$. The additional mole fraction of the rare earth oxide is ranged over 0.0015 to 0.0030. The electrical conductivity exhibits an anomalous decrease near the tetragonal to cubic transition about 12$0^{\circ}C$. The decrease in the electrical conductivity is observed at the higher impurity concentrations owing to space charge layer. The increase in the electrical conductivity is observed as the impurity ion is varied from $La^{+3}$$Nd^{+3}$ to $Dy^{+3}$, due to overlap of 4f electrons of the inner shell.

  • PDF

Mechanical Properties of Hot-Pressed SiC with Rare-Earth Oxide (희토류 산화물을 첨가한 일축가압소결 탄화규소의 기계적 특성)

  • 최철호;이충선;박광자;조덕호;김영욱
    • Journal of the Korean Ceramic Society
    • /
    • v.37 no.2
    • /
    • pp.158-163
    • /
    • 2000
  • Six different SiC ceramics with SiO2-Re2O3 (Re=Yb, Er, Y, Dy, Gd, Sm) as sintering additives have been fabricated by hot-pressing the SiC-Re2Si2O7 compositions at 1850$^{\circ}C$ for 2 hr under a pressure of 25 MPa. The room temperature strneth and the fracture toughness of the hot-pressed ceramics were characterized and compared with those of the ceramics sintered with YAG (Y3Al5O12). Five SiC ceramics (Re=Yb, Er, Y, Dy, Gd) investigated herein showed sintered densities higher than 94% of theoretical. Tthe SiC-Re2Si2O7 compositions showed lower strength and comparable toughness to those from SiC-YAG composition, owing to the chemical reaction between SiO2 and SiC during sintering. SiC ceramics fabricated from a SiC-Y2Si2O7 composition showed the best mechanical properties of 490 MPa and 4.8 MPa$.$m1/2 among the compositions investigated herein.

  • PDF

Comparison of Vehicle Efficiency Applying Rare Earth Free Concentrated-Flux Synchronous Motor and Rare Earth Interior Permanent Magnet Synchronous Motor According to Driving Cycle (전기자동차 구동용 비희토류 자속집중형 전동기와 희토류 전동기의 주행사이클에 따른 차량 효율 비교)

  • Cha, Kyoung-Soo;Kim, Dong-Min;Lim, Myung-Seop;Hong, Jung-Pyo
    • Proceedings of the KIEE Conference
    • /
    • 2015.07a
    • /
    • pp.858-859
    • /
    • 2015
  • 현재 전기자동차 구동전동기는 일반적으로 희토류 영구자석을 사용한 동기전동기를 사용하고 있다. 하지만 희토류는 수급불안정성이 높아 자동차 업계는 희토류 전동기를 대체할 수 있는 방안을 찾고 있으며 그 방안 중 하나가 비희토류 자속집중형 전동기이다. 비희토류 영구자석의 수를 늘려서 희토류 전동기와 동일한 크기에 유사한 출력을 만족하게 설계했다. 마지막으로 전기자동차 구동용 비희토류 자속집중형 전동기의 특성 및 크기를 희토류 전동기와 비교하고 두 전동기를 탑재한 차량을 Advisor(Advanced Vehicle Simulator)를 사용해 주행사이클에 대한 차량효율을 비교할 것이다.

  • PDF