• 제목/요약/키워드: Rapid Solidification Process

검색결과 79건 처리시간 0.024초

급속응고법으로 제작한 Zr기 수소저장합금의 전극특성 (The Electrode Characteristics of the Zr-based Hydrogen Absorbing Alloy Fabricated by the Rapid Solidification Process)

  • 한동수;정원섭;김인곤
    • 한국재료학회지
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    • 제9권4호
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    • pp.386-391
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    • 1999
  • The charge-discharge, the high-rate dischargeability, and the self discharge characteristics of the electrodes composed of rapidly solidified ZrV\ulcornerMn\ulcornerMo\ulcornerNi\ulcorneralloy, which has the form of partial substitution of Mn, Mo, Ni for V in $ZrV_2$ were studied. The alloys were prepared using Arc & RSP(Rapid Solidification Process) at the rotating roller speed of 2000 and 5000 rpm. Some of them were received heat treatment at$ 560 ^{\circ}C$ for 1 hour after the solidification to investigate the effect of the heat treatment. It was fond that cycle life was significantly improved by RSP, whereas discharge capacity, activation rte and high rate dischargeability were decreased compared with the conventional arc melting method. The capacity loss seems to be due to the loss of the crystallinity and the increase of the cycle life ascribed to the presence of the amporphous phase as well as the refined grain size of less than 0.2$\mu\textrm{m}$. Heat treatment of the alloy cooled at 2000 rpm improved the cycle life. In case of the alloys cooled at 5000 rpm, both the discharge capacity and the activation rate were significantly improved by the heat treatment.

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급속응고 및 Stone Mill 공정에 의해 제조된 하이브리드 Al2O3-TiC/Al 복합재료의 미세조직 (Microstructure of the Hybrid Al2O3-TiC/Al Composite by Rapid Solidification and Stone Mill Process.)

  • 김택수;이병택;조성석;천병선
    • 한국분말재료학회지
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    • 제10권1호
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    • pp.15-20
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    • 2003
  • Hybrid $A1_2O_3-TiC$ ceramic particle reinforced 6061 and 5083 Al composite powders were prepared by the combination of twin rolling and stone mill crushing process, followed by consolidating processes of cold compaction, degassing and hot extrusion. The composite bar consists of lamellar structure of ceramic particle rich area and matrix area, in which the hybrid was decomposed into each TiC of about $3-4\mutextrm{m}$ and $AI_2O_3$ particles of about $1-2\mutextrm{m}$ in diameter. It also found that fine $Mg_2Si$ precipitates of about 30 nm were embedded in the matrix, which have grains of about 3 $\mutextrm{m}$. Higher UTS was measured at the 5083 composite bar compared to the conventionally fabricated composite, due to again refinement effect by the rapid solidification. No particle was shown to form in the interface between the matrix and reinforcement, whereas carbon was diffused into the matrix.

Effect of Critical Cooling Rate on the Formation of Intermetallic Phase During Rapid Solidification of FeNbHfBPC Alloy

  • Kim, Song-Yi;Oh, Hye-Ryeong;Lee, A-Young;Jang, Haneul;Lee, Seok-Jae;Kim, Hwi-Jun;Lee, Min-Ha
    • 한국주조공학회지
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    • 제41권3호
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    • pp.235-240
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    • 2021
  • 진공 가스분사법으로 제조된 Fe75B13P5Nb2Hf1C4 합금의 응고중 액상의 크기와 이에 따른 냉각속도의 변화가 정출상의 형성에 미치는 영향에 대한 고찰을 하였다. 고온 액상에서 동일한 조건으로 응고된 서로 다른 크기의 액상이 구형의 분말형태로 응고될 때 크기에 따른 임계냉각속도의 차이를 계산하였으며, 액상의 평균 반지름이 3배정도 크기 차이가 날 경우 고상으로 변태할 때 임계냉각속도가 13.5배까지 차이가 나는 것을 알 수 있었다. 이러한 임계냉각 속도의 차이에 따른 정출상의 형성과 정출상의 형태와 크기에 따른 탄화물의 형성 거동을 조사하여 열역학 계산으로 예측된 결과와 비교 분석하였으며, 분말입자의 크기가 20~45 마이크론일 경우 Hf과 Nb이 포함된 MC타입의 탄화물이 초정으로 형성 되는 것을 알 수 있었으며 이때 Hf과 Nb의 비율은 합금의 조성 및 냉각속도에 따라 변화됨을 관찰 할 수 있었다.

급속응고기술에 의한 p-type 25% $Bi_{2}Te_{3}+75% Sb_{2}Te_{3}$ 열간압축제의 열전특성 (Thermoelectric Properties of p-type 25% $Bi_{2}Te_{3}+75%Sb_{2}Te_{3}$ Materials Prepared by Rapid Solidification Process and Hot Pressing)

  • 김익수
    • 한국분말재료학회지
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    • 제3권4호
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    • pp.246-252
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    • 1996
  • $Bi_{2}Te_{3}-Sb_{2}Te_{3}$, $Bi_{2}Te_{3}-Bi_{2}Se_{3}$ solid solutions are of great interest as materials for thermoelectric energy conversion. One of the key technologies to ensure the efficiency of thermoelectric device is to obtain chemically homogeneous solid solutions. In this work, the new process with rapid solidification followed by hot pressing was investigated to produce homogeneous thermoelectric materials. Characteristics of the materials were examined with XRD, SEM, EPMA-line scan and bending test. Property variations of the materials were investigated as a function of variables, such as excess Te quantity and hot pressing temperature. Quenched ribbons are very brittle and consisted of homogeneous $Bi_{2}Te_{3}$, $Sb_{2}Te_{3}$ solid solutions. When the process parameters were optimized, the maximum figure of merit was 3.073$\times$$10^{-3}K^{-4}$. The bending strength of the material, hot pressed at 45$0^{\circ}C$, was 5.87 kgf/${mm}^2$.

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반복압출 공정을 이용한 금속분말의 미세조직 제어 (Microstructure Control of Mg Alloy Powder Using a Repeated Extrusion Process)

  • 김정곤;최한신;김택수
    • 한국분말재료학회지
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    • 제16권6호
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    • pp.438-441
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    • 2009
  • Mg-Cu composites were successively fabricated using a combination of rapid solidification and extrusion processes. In addition, the microstructural variation of the composite was investigated by performing the extrusion repeatedly. It resulted that the composite formed an uniform and dense structure by the extrusion, and the microstructure became fine as the extrusion conducted repeatedly. The microstructural variation was known to be dependent on the number of extrusion and the area reduction ratio. The tensile strength was also measured as a function of the microstructural variation.

강제교반법으로 제조된 Al-Pb계 베어링 합금의 마모특성 (Wear properties of Al-Pb alloys produced by a forced stirring method)

  • 임화영;허무영;임대순
    • Tribology and Lubricants
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    • 제8권1호
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    • pp.70-77
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    • 1992
  • Al-Pb-Si bearing alloys were produced by a forced stirring method and a rapid solidification process to study wear properties of bearing alloys. A homogeneous distribution of Pb particles in Al matrix could be obtained by means of the forced stirring and the rapid cooling during the casting. The wear properties of bearing alloys were tested by a pin-on-disc wear tester. The change in microstructure according to the alloy manufacturing variables was observed by the backscattered electron images. Al-Pb and Al-Si binary alloys showed a transition from mild to severe wear. The transition was not found in Al-Pb-Si ternary alloys. It could be concluded that the lubricatioin effect of Pb and the strengthening effect of Si in the ternary alloys enhanced the bearing properties. A Al-25%Pb-13%Si alloy showed the lowest coefficient of friction in this experiment. It indicated that the optimum concentration of alloy was 25% Pb and 13% Si when the forced stirring of melt and water-cooled-copper-mold solidification were adopted.

급속응고법으로 제조한 과공정 Al-Si합금분말 압출재의 마멸특성 (Wear Characteristics of the Extruded Bars of Hypereutectic Al-Si Alloy Powders produced by Rapid Solidification Process)

  • 안영남;조규섭;나형용
    • 한국주조공학회지
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    • 제14권5호
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    • pp.447-454
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    • 1994
  • Wear resistance and wear mechanism of hypereutectic Al-($15{\sim}40$)wt%Si alloys were investigated. Primary Si particles under $20{\mu}m$ size were formed in hypereutectic Al-Si alloy powders due to rapid solidification. But the Si particles of extruded bars were finely distributed in smaller size than that of atomized powders. The wear mechanism of hypereutectic Al-Si alloys was divided into three types of wear phenomena, which were abrasive wear, delamination wear and severe adhesive wear according to sliding speed and load. At low sliding speed and load, wear mechanism was abrasive wear, so Al-15wt%Si alloy showed the best wear resistance. At high sliding speed and load, wear mechanism was adhesive wear, and Al-40wt%Si alloy showed the best wear resistance.

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발포 폴리스티렌 폼을 이용한 가변 적층 쾌속 조형 공정 설계 및 개발 (Development and Design of Variable Lamination Manufacturing (VLM) Process by Using Expandable Polystyrene Foam)

  • 안동규;이상호;양동열;신보성;박승교;이용일
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2000년도 추계학술대회 논문집
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    • pp.759-762
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    • 2000
  • Rapid Prototyping (RP) techniques have their unique characteristics according to the working principles: stair-stepped surface of parts due to layer-by-layer stacking, low build speed caused by line-by-line solidification to build one layer, and additional post processing to improve surface roughness, so it is required very high cost to introduce and to maintain RP apparatus. The objective of this study is to develop and design a new RP process, Variable Lamination Manufacturing using expandable polystyrene foam sheet as part material (VLM-S), which can make up for the disadvantage of existing techniques, and to develop an apparatus to implement the process. In order to examine the possibility of practical utilization of the proposed VLM-S process for prototyping of a general three-dimensional shape, an auto-shift lever knob and a pyramid shape were fabricated.

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