• Journal of Environmental Science International
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• v.24 no.11
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• pp.1493-1500
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• 2015

Observation data (1981-2014) and climate change scenario data (historical: 1981-2005; RCP 2.6 and 8.5: 2006-2100) were used to analyze occurrence and future outlook of the extreme heat days and tropical nights in Daegu and Jeju. Then we compared the mortality and observations data (1993-2013). During 1981-2014, the average of extreme heat days (tropical nights) was 24.41 days (12.47 days) in Daegu, and 6.5 days (22.14 days) in Jeju. Extreme heat days and tropical nights have been similarly increased in Daegu, but tropical nights increased more than extreme heat days in Jeju. Extreme heat days and tropical nights in both, Daegu and Jeju showed high correlation with daily mortality, specifically Daegu's correlation was higher than that of jeju. The yearly increasing rate of extreme heat of the future (2076-2100) was 1.7-3.6 times and 7.8-37.7 times higher than the past (1981-2005) in Daegu and Jeju, respectively. The yearly increase rate of tropical nights of future was 2.6-5.0 times and 2.9-5.6 times higher in Daegu and Jeju, respectively. During 2006-2100 periods, the trend of extreme heat days was observed both in Daegu and Jeju. On the average, extreme heat days and tropical nights in Jeju increased more than that of Daegu. However, the trend of extreme heat days increase in Daegu was higher than that in Jeju, whereas, the trend of tropical nights in Jeju was higher than that in Daegu.

• Rapid Communication in Photoscience
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• v.4 no.2
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• pp.37-40
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• 2015

To examine the photosensitized biomolecules damaging activity, dimethoxyP(V)tetrakis(2-naphthyl)porphyrin (NP) and dimethoxyP(V)tetraphenylporphyrin (PP) were synthesized. The naphthyl moiety of NP hardly deactivated the photoexcited P(V)porphyrin ring in ethanol. In aqueous solution, the naphthyl moiety showed the quenching effect on the photoexcited porphyrin ring, possibly through electron transfer and self-quenching by a molecular association. Binding interaction between human serum albumin (HSA), a water soluble protein, and these porphyrins could be confirmed by the absorption spectral change. The apparent association constant of NP was larger than that of PP. It is explained by that more hydrophobic NP can easily bind into the hydrophobic pockets of HSA. The photoexcited PP effectively induced damage of the tryptophan residue of HSA, through electron transfer-mediated oxidation and singlet oxygen generation. NP also induced HSA damage during photo-irradiation and the contributions of the electron transfer and singlet oxygen mechanisms were speculated. The electron transfer-mediated mechanism to the photosensitized protein damage should be advantageous for photodynamic therapy in hypoxic condition. The quantum yield of the HSA photodamage by PP was significantly larger than that of NP. The quenching effect of the naphthyl moiety is considered to suppress the photosensitized protein damage. In conclusion, the naphthalene substitution to the P(V)porphyrins can enhance the binding interaction with hydrophobic biomacromolecules such as protein, however, this substitution may reduce the photodynamic effect of P(V)porphyrin ring in aqueous media.

• Rapid Communication in Photoscience
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• v.2 no.2
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• pp.42-45
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• 2013

Natural photosynthesis utilizes solar energy to convert carbon dioxide and water to energy-rich carbohydrates. Substantial use of sunlight to meet world energy demands requires energy storage in useful fuels via chemical bonds because sunlight is intermittent. Artificial photosynthesis research focuses the fundamental natural process to design solar energy conversion systems. Nicotinamide adenine dinucleotide ($NAD^+$) and $NADP^+$ are ubiquitous as electron transporters in biological systems. Enzymatic, chemical, and electrochemical methods have been reported for NADH regeneration. As photochemical systems, visible light-driven catalytic activity of NADH regeneration was carried out using platinum nanoparticles, molecular rhodium and cobalt complexes in the presence of triethanolamine as a sacrificial electron donor. Pt nanoparticles showed photochemical NADH regeneration activity without additional visible light collector molecules, demonstrating that both photoactivating and catalytic activities exist together in Pt nanoparticles. The NADH regeneration of the Pt nanoparticle system was not interfered with the reduction of $O_2$. Molecular cobalt complexes containing dimethylglyoxime ligands also transfer their hydrides to $NAD^+$ with photoactivation of eosin Y in the presence of TEOA. In this photocatalytic reaction, the $NAD^+$ reduction process competed with a proton reduction.

• Nuclear Engineering and Technology
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• v.44 no.7
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• pp.807-816
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• 2012

The Three Mile Island Unit 2 (TMI-2) accident has been studied extensively, as part of both post-accident technical assessment and follow-up computer code calculations. The models used in computer codes for severe accidents have improved significantly over the years due to better understanding. It was decided to reanalyze the severe accident scenario using current state of the art codes and methodologies. This reanalysis was adopted as a part of the joint standard problem exercise for the Atomic Energy Regulatory Board (AERB) - United States Regulatory Commission (USNRC) bilateral safety meet. The accident scenario was divided into four phases for analysis viz., Phase 1 covers from the accident initiation to the shutdown of the last Reactor Coolant Pumps (RCPs) (0 to 100 min), Phase 2 covers initial fuel heat up and core degradation (100 to 174 min), Phase 3 is the period of recovery of the core water level by operating the reactor coolant pump, and the core reheat that followed (174 to 200 min) and Phase 4 covers refilling of the core by high pressure injection (200 to 300 min). The base case analysis was carried out for all four phases. The majority of the predicted parameters are in good agreement with the observed data. However, some parameters have significant deviations compared to the observed data. These discrepancies have arisen from uncertainties in boundary conditions, such as makeup flow, flow during the RCP 2B transient (Phase 3), models used in the code, the adopted nodalisation schemes, etc. In view of this, uncertainty and sensitivity analyses are carried out using simulation based techniques. The paper deals with uncertainty and sensitivity analyses carried out for the first three phases of the accident scenario.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.18 no.1
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• pp.103-113
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• 2015

Korean pines(Pinus koraiensis) are one of the major plantation species in the Republic of Korea and their natural habitats range from Japan and China to Siberia. The seed of Korean pines, pine nuts, are well know for good food reserves. Due to the global changes which drive the Korean peninsula into the semi-tropical climate, current plantations and natural habitats of Korean pines are faced with the change in the environmental conditions to some extent. To anticipate suitable sites for Korean pines in the future, the location of Korean pines were extracted from the 'Map of suitable trees on a site' that provides the map of suitable trees on a site considering tree species for timber and special uses, and then MaxEnt modelling was used for generating a prediction map on the basis of statistical analysis. As a result, the order of predicted suitable sites were Kangwon-do, Kyungsangbuk-do and Chungcheongbuk-do provinces and sites with high elevation within those provinces were considered most suitable in common. The prediction map of suitable sites for Korean pines presented that suitable sites in the future decreased by 72.2% by 2050's and almost disappeared with a decrease of 92.1% by 2070's on a nationwide scale. In relation to the major production regions of pine nuts in South Korea - Gapyung gun and Yangpyung gun, Kyunggi province and Hongcheon gun, Kangwon province, suitable sites within their areas were predicted to increase by 2050's but become extinct in South Korea by 2070's. To establish a long-term countermeasures against the improvement on forest productivity quality in terms of managing national food security, the result from this study can be considered as a firm basis of predicting plantation suitability. Also, it can be used to predict the changes in supply of forest products and thereby market values in accordance with climate change scenarios.

• Journal of Soil and Groundwater Environment
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• v.23 no.1
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• pp.92-105
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• 2018

In this study, the projected land use area in 2030 for major crop production was estimated in Jeju Island using land cover map, and corresponding agricultural water demand for 40 sub-regions was quantitatively assessed using the future climate change scenario (RCP 4.5). Estimated basic unit of water demand in 2030 was the highest in the western region, and the lowest in the eastern region. Monthly maximum agricultural water demand analysis revealed that water demand in August of 2030 substantially increased, suggesting the climate of Jeju Island is changing to a subtropical climate in 2030. Agricultural water demand for sub-region in 2030 was calculated by multiplying the target area of the water supply excluding the area not in use in winter season by the basic unit of water demand, and the maximum and minimum values were estimated to be $306,626m^3/day$ at Seogwipo downtown region and $77,967m^3/day$ at Hallim region, respectively. Consequently, total agricultural water demand in Jeju Island in 2030 was estimated to be $1,848,010m^3/day$.

• Korean Journal of Materials Research
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• v.17 no.7
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• pp.366-370
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• 2007

Silicon nitride ($Si_3N_4$) ceramics have been considered for various components of nuclear power plants such as the mechanical seal of a reactor coolant pump (RCP), the guide roller for a control rod drive mechanism (CRDM), and a seal support, etc. Corrosion behavior of $Si_3N_4$ ceramics in a high-temperature and high-pressure water must be elucidated before they can be considered as components for nuclear power plants. In this study, the corrosion behaviors of $Si_3N_4$ ceramics containing MgO and $Al_2O_3$ as sintering aids were investigated at a hydrothermal condition ($300^{\circ}C$, 9.0 MPa) in pure water and 35 ppm LiOH solution. The corrosion reactions were controlled by a diffusion of the reactive species and/or products through the corroded layer. The grain-boundary phase was preferentially corroded in pure water whereas the $Si_3N_4$ grain seemed to be corroded at a similar rate to the grain-boundary phase in LiOH solution. Flexural strengths of the $Si_3N_4$ ceramics were significantly degraded due to the corrosion reaction. Results of this study imply that a variation of the sintering aids and/or a control (e.g., crystallization) of the grain-boundary phase are necessary to increase the corrosion resistance of $Si_3N_4$ ceramics in a high-temperature water.

• Rapid Communication in Photoscience
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• v.3 no.1
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• pp.25-27
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• 2014

The relative importance of radiation dose, storage time, and temperature in radiation processing of spinach (Spinacia oleracea L.), was evaluated in terms of the postharvest quality through a model study using leaf disks. Physiological activity and chlorophyll and carotenoid contents were measured to represent the postharvest quality (in terms of external appearance) of spinach, a leafy green vegetable. At $22^{\circ}C$ and $30^{\circ}C$, the higher gamma-radiation dose caused a greater decrease in the physiological activity, depending on the storage time of 4 d. However, this decrease was not significant at $4^{\circ}C$ and $15^{\circ}C$. Total chlorophyll and carotenoid contents were substantially decreased by 3 kGy at $15^{\circ}C$, and dose-dependently by 0.5-3 kGy at $22^{\circ}C$. In contrast, the proportion of lutein in total carotenoid was significantly increased in the 2-3-kGy samples only at $22^{\circ}C$, while that of ${\beta}$-carotene was slightly decreased, indicating progression of leaf aging. These data suggest that the unfavorable effect of gamma irradiation on the postharvest quality of spinach could be avoided or controlled by the storage time or temperature rather than the radiation dose. The current study could be available to improve radiation processing of other leafy green vegetables.

• Rapid Communication in Photoscience
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• v.3 no.1
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• pp.16-19
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• 2014

Anodic self-organized titania nanotube (TNT) arrays have a great potential as efficient electron-transport materials for dye-sensitized solar cells (DSSC). Herewith we report the photovoltaic and kinetic investigations for a series of heteroleptic ruthenium complexes (RD16-RD18) sensitized on TNT films for DSSC applications. We found that the RD16 device had an enhanced short-circuit current density ($J_{SC}/mAcm^{-2}=15.0$) and an efficiency of power conversion (${\eta}=7.2%$) greater than that of a N719 device (${\eta}=7.1%$) due to the increasing light-harvesting and the broadened spectral features with thiophene-based ligands. However, the device made of RD17 (adding one more hexyl chain) showed smaller $J_{SC}(14.1mAcm^{-2})$ and poorer ${\eta}(6.8%)$ compare to those of RD16 due to smaller amount of dye-loading and less efficient electron injection for the RD17 device than for the RD16 device. For the RD18 dye (adding one more thiophene unit and one more hexyl chain), we found that the device showed even lower $J_{SC}(13.2mAcm^{-2}) $ that led to a poorest device performance (${\eta}=6.2%$) for the RD18 device. These results are against to those obtained from the same dyes sensitized on $TiO_2$ nanoparticle films and they can be rationalized according to the electron transport kinetics measured using the methods of charge extraction and transient photovoltage decays.

• Journal of Korean Society of Rural Planning
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• v.26 no.1
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• pp.1-12
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• 2020

다수의 국가에서 농촌이 쇠퇴하는 현상을 확인할 수 있으며, 특히 경작 포기지의 비율이 빠른 속도로 향상되고 있다. 일본에서 경작 포기지의 증가는 농작물의 국내 자급률 감소, 농지의 중요한 기능 중 하나인 자연재해 방지 기능의 상실, 그리고 농촌 지역사회가 계승해 오던 다양한 형태의 무형적 자산의 소실 등을 야기하였다. 농지와 농촌 지역사회 활동의 보존은 지속가능한 개발을 위해 필수적인 요소이다. 생태계 서비스는 농지가 보유한 기능 중 하나이며, 일본의 중산간 지역 직불제는 농지의 보전과 농촌 지역사회 활동을 지원하여 생태계 서비스 보존 및 유지에 일조하기에 생태계 서비스에 대한 지불(PES)이라 볼 수 있다. 본 연구의 목표는 중산간지역 직접지불제도의 혜택을 받는 지역과 RCP8.5 시나리오 하에서의 자연재해 피해액 간의 관계를 파악하여 직불제의 효율성을 간접적으로 검증하는 것이다. 본 연구의 대상지는 일본 홋카이도의 농지 전체이며, 2005년, 2010년, 2015년의 강우량 예측 패널 데이터와 농업 센서스 패널 데이터를 이용하여 한계효과를 구하여 분석하였다. 분석 결과, 중산간지역 직불제 해당지역이면서 농촌 지역사회 활동이 활발할수록 자연재해 피해액이 적었다. 따라서 특히 중산간지역 직불제 해당지역일수록 재해피해 감소를 위해 농촌 지역사회 활동이 필수적으로 요구된다. 본 연구의 의의는 중산간지역 직불제의 효율성을 자연재해 피해액을 통해 검증한 데 있으며, 향후 직불제의 효율성에 대한 논의에 기초자료로 활용될 수 있다.