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Cycloplatinated Complexes of Thiosemicarbazones. Synthesis and Crystal Structure of [$Ph_2PC_6H_4CHNNC(S)NHCH_3PtCl$]

  • 유동원;강상욱;고재정;최문근
    • Bulletin of the Korean Chemical Society
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    • v.18 no.3
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    • pp.305-310
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    • 1997
  • The synthesis and characterization of the platinum heterocyclic carboxaldehyde thiosemicarbazone complexes [NC5H4CRNNC(S)NHR'PtCl] (R=H, R'=CH3(1); R=CH3, R'=CH3(2); R=CH3, R=H(3)) and diphenylphosphinophenyl carboxaldehyde thiosemicarbazone complexes [Ph2PC6H4CHNNC(S)NHRPtCl] (R=CH3(5); R=iC3H7(6); R=Ph(7)) are described. Compounds 1-3 were prepared by reaction of Pt(SEt2)2Cl2 with 2-acetylpyridine-4-alkylthiosemicarbazone in the presence of NEt3. Compounds 5-7 were prepared using Pt(SEt2)2Cl2 in toluene with diphenylphosphinophenyl carboxaldehyde alkylthiosemicarbazone. The compounds have been characterized by microanalysis, NMR (1H, 13C, 31P) spectroscopy, and single-crystal X-ray diffraction. X-ray single crystal diffraction analysis reveals that compound 5 is a mononuclear platinum compound with P,N,S-coordination mode.

Design of 250-Mb/s Low-Power Fiber Optic Transmitter and Receiver ICs for POF Applications

  • Park, Kang-Yeob;Oh, Won-Seok;Choi, Jong-Chan;Choi, Woo-Young
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.11 no.3
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    • pp.221-228
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    • 2011
  • This paper describes 250-Mb/s fiber optic transmitter and receiver ICs for plastic optical fiber applications using a$ 0.18-{\mu}m$ CMOS technology. Simple signal and light detection schemes are introduced for power reduction in sleep mode. The transmitter converts non-return-to-zero digital data into 650-nm visible-red light signal and the receiver recovers the digital data from the incident light signal through up to 50-m plastic optical fiber. The transmitter and receiver ICs occupy only 0.62 $mm^2$ of area including electrostatic discharge protection diodes and bonding pads. The transmitter IC consumes 23 mA with 20 mA of LED driving currents, and the receiver IC consumes 16 mA with 4 mA of output driving currents at 250 Mb/s of data rate from a 3.3-V supply in active mode. In sleep mode, the transmitter and receiver ICs consume only 25 ${\mu}A$ and 40 ${\mu}A$, respectively.

Analysis of the Propagation Characteristics of Ultrasonic Guided Waves Excited by Single Frequency and Broadband Sources

  • Kang, To;Song, Sung-Jin;Kim, Hak-Joon;Cho, Young-Do;Lee, Dong-Hoon;Cho, Hyun-Joon
    • Journal of the Korean Society for Nondestructive Testing
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    • v.29 no.6
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    • pp.570-578
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    • 2009
  • Excitation and propagation of guided waves are very complex problems in pipes due to their dispersive nature. Pipes are commonly used in the oil, chemical or nuclear industry and hence must be inspected regularly to ensure continued safe operation. The normal mode expansion(NME) method is given for the amplitude with which any propagating waveguide mode is generated in the pipes by applied surface tractions. Numerical results are calculated based on the NME method using different sources, i.e., non-axisymmetric partial loading and quasi-axisymmetric loading sources. The sum of amplitude coefficients for 0~nineth order of the harmonic modes are calculated based on the NME method and the dispersion curves in pipes. The superimposed total field which is namely the angular profile, varies with propagating distance and circumferential angle. This angular profile of guided waves provides information for setting the transducer position to find defects in pipes.

Viewing angle controllable liquid crystal display using fringe-field switching mode with high aperture ratio characteristic (고투과율 특성을 갖는 FFS 모드의 시야각 스위칭)

  • Kim, Jin-Ho;Her, Jung-Hwa;Chin, Mi-Hyung;Lim, Young-Jin;Jin, Hyun-Suk;Kim, Byeong-Koo;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.32-33
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    • 2009
  • We propose viewing angle switchable liquid crystal display(LCD) associated with fringe-field switching (FFS) mode with high aperture ratio characteristic. This device is composed of R(red), G(green), B(blue), pixel and W(white) pixel in which R,G,B pixel shows image and white pixel for both viewing angle control and image. Conventional viewing angle controllable liquid crystal display has not transmittance because the liquid crystal only tilts up without rotates in viewing angle control region. In this paper, we suggested that the device has high transmittance characteristic because the LC directors are rotated in which viewing angle control region are generated fringe electric field.

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A Study on the Surface Treatment of Prepreg with $Ar^+$ Ion to Increase Mode I Fracture Characteristics of Fiber-Reinforced Composites (섬유강화 적층복합재의 열림모드 파괴특성 향상을 위해 $Ar^+$ 이온도움반응법을 적용한 프리프레그의 표면처리 연구)

  • Lee, Gyeong-Yeop;Ji, Chang-Heon;Yang, Jun-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.11
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    • pp.2771-2776
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    • 2000
  • In this work, the effect of surface treatment of prepreg on the mode I fracture behavior was studied. Unidirectional (0-deg) double cantilever beam (DCB) specimens were used for fracture tests. Two groups of DCB specimens were made: the first group was made of prepregs surface-treated by Ar(sup)+ ion beam under oxygen environment and the second group was made of regular prepregs. For both groups, fracture resistance curve (R-curve) was determined and compared to each other, Results showed that resistance behavior of the first group is better than that of the second group. That is, mode I fracture toughness, G(sub)Ic of the first group is 24% larger than that of the second group. SEM examination shows that the improvement of G(sub)Ic is due to the increase of interfacial strength between plies.

Out-of-plane ductile failure of notch: Evaluation of Equivalent Material Concept

  • Torabi, A.R.;Saboori, Behnam;Kamjoo, M.R.
    • Structural Engineering and Mechanics
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    • v.75 no.5
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    • pp.559-569
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    • 2020
  • In the present study, the fracture toughness of U-shaped notches made of aluminum alloy Al7075-T6 under combined tension/out-of-plane shear loading conditions (mixed mode I/III) is studied by theoretical and experimental methods. In the experimental part, U-notched test samples are loaded using a previously developed fixture under mixed mode I/III loading and their load-carrying capacity (LCC) is measured. Then, due to the presence of considerable plasticity in the notch vicinity at crack initiation instance, using the Equivalent Material Concept (EMC) and with the help of the point stress (PS) and mean stress (MS) brittle failure criteria, the LCC of the tested samples is predicted theoretically. The EMC equates a ductile material with a virtual brittle material in order to avoid performing elastic-plastic analysis. Because of the very good match between the EMC-PS and EMC-MS combined criteria with the experimental results, the use of the combination of the criteria with EMC is recommended for designing U-notched aluminum plates in engineering structures. Meanwhile, because of nearly the same accuracy of the two criteria and the simplicity of the PS criterion relations, the use of EMC-PS failure model in design of notched Al7075-T6 components is superior to the EMC-MS criterion.

Beat Frequency Switchable Dual-mode External cavity laser (비트 주파수를 스위칭할 수 있는 듀얼 모드 외부 공진기 레이저)

  • Kim, Chul-Seop;Kim, Ryun-Kyung;Lee, Kyung-Shik;Song, Jeong-Hwan;Oh, Yun-Kyung
    • Korean Journal of Optics and Photonics
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    • v.17 no.6
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    • pp.489-492
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    • 2006
  • We demonstrate a beat frequency-Switchable dual-mode external cavity laser hybrid integrated on planar lightwave circuit with an FP-LD and a sampled grating as external reflector. The dual-mode external avity laser was able to switch its beat frequency from 132GHz to 406GHz by changing LD current from 50mA to 55mA.

Daily Heating Performance of a Ground Source Multi-heat Pump at Heating Mode (지열원 물대공기 멀티 히트펌프의 일일 난방 운전 특성에 관한 실증 연구)

  • Choi, Jong-Min;Lim, Hyo-Jae;Kang, Shin-Hyung;Moon, Je-Myung;Kim, Rock-Hee
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.9
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    • pp.527-535
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    • 2009
  • The aim of this study is to investigate the daily heating performance of ground source multi-heat pump system with vertical single U-tube type GLHXs, which were installed in a school building located in Cheonan. Daily average COP of heat pump unit on Jan. 12th, 2009 at heating mode was lower than it on Nov. 10th, 2008 and Dec. 15th, 2008, because of lower EWT of the outdoor heat exchanger and relatively smaller size of condenser and evaporator. But, the system COP on the former was higher than it on the latter because ground loop circulating pump was operated in rated speed. It is suggested that the new algorithms to control the flow rate of secondary fluid for GLHX according to load change have to be developed in order to enhance the performance of the system COP.

Motion Profile Generation Method for Absolute Angular Error Control Mode of Gun/Turret Driving System (포/포탑 구동 시스템의 절대 각 오차 제어 모드에 대한 모션 프로파일 생성 기법)

  • Eom, Myunghwan;Song, Sinwoo;Park, Ilwoo
    • Journal of the Korea Institute of Military Science and Technology
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    • v.22 no.5
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    • pp.674-686
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    • 2019
  • In this paper, we will discuss the absolute angular error control mode for the Gun/Turret driving system. The Gun/Turret driving controller receives absolute angular error calculated from the fire control system (FCS). Thus, the Gun/Turret driving controller is subjected to step command to cause residual vibration and system unstable. In order to reduce residual vibration and to ensure the system stability, we propose an error motion profile method with two types of trapezoidal and S-Curve. The validity of the proposed error motion profile method is confirmed via simulation by observing that the resulting position error, driving power, and power density satisfied the control performance.

State of the Art on Terrestrial Radionavigation System and Its Applications for Maritime PNT Service

  • Seo, Kiyeol;Fang, Tae Hyun;Park, Sang Hyun
    • Journal of Positioning, Navigation, and Timing
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    • v.11 no.4
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    • pp.229-238
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    • 2022
  • This paper addresses on the International technical trends, standards, and development status of terrestrial radionavigation system to provide more accurate and fail-safe Positioning, Navigation, and Timing (PNT) Information available in maritime navigation environment. We analyze the performance result of pilot service in enhanced Long range navigation (eLoran) testbed environment using Low Frequency (LF) signal, and describe the development status of Ranging-Mode (R-Mode) system using Medium Frequency (MF) and Very High Frequency (VHF) to meet the Harbor Entrances and Approaches (HEA) requirement of International Maritime Organization (IMO) within 10m position accuracy. Furthermore, we present an architecture for integrated service of satellite-terrestrial navigation system and future maritime applicable fields. As the core information infrastructure of future navigation for 4th industrial revolution, this paper will be contributed to determining the direction of present and future to provide fail-safe PNT service with Global Navigation Satellite System (GNSS) based on the technical enhancement of terrestrial integrated navigation system.