• Title/Summary/Keyword: R&D Phase

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Evaluation of the Properties of an Environment-Friendly De-icing Agent Based on Industrial By-Products (산업부산물을 활용한 친환경제설제의 특성평가)

  • Heo, Hyung-Seok;Lee, Byung-Jae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.132-139
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    • 2017
  • A huge amount of de-icing agent is sprayed during winter to promote traffic safety in cold regions, and the quantity of de-icing agent sprayed has increased each year. The main ingredients in commonly used de-icing agents are chlorides, such as calcium chloride($CaCl_2$) and sodium chloride(NaCl). While calcium chloride is mostly used in Korea and sodium chloride is usually used in the U.S. and Japan, all de-icing agents include chloride ions. The chlorides included in sprayed calcium chloride-based de-icing agents have severe adverse effects, including the corrosion of reinforcing steels through salt damage by infiltrating into road structures, reduced structural performance of pavement or damage to bridge structures, and surface scaling, in combination with freezing damage in winter, as well as water pollution. In addition, the deterioration of paved concrete road surface that occurs after the use of calcium chloride-based de-icing agent accelerates the development of visual problems with traffic structures. Therefore, the present study was performed to prepare an environment-friendly liquid de-icing agent through a reaction between waste organic acids and calcium-based by-products, which are industrial by-products, and to analyze the properties of the de-icing agent in order to evaluate its applicability to road facilities.

Die Notwendigkeit einer funktionalen Grammatik fur Deutsch als Fremdsprache (외국어로서 독일어 수업을 위한 기능문법의 필요성)

  • Park Hyun-Sun
    • Koreanishche Zeitschrift fur Deutsche Sprachwissenschaft
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    • v.7
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    • pp.237-256
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    • 2003
  • Das Deutsche als Fremdsprach hat sich als akademische Disziplin etabliert; es hat seine - von vielerlei Irrungen und Wirrungen begleitete - Startphase hinter sich und ist in eine Phase der Konsolidierung eingetreten. Bei aller Unterschiedlichkeit der $Ans\"{a}tze$, Forschungsmethoden und Lemziele gibt es doch eine Einheit in der Vielfalt, was angesichts der erst wenige ]ahrzehnte alten Disziplin erstaunt. Im Zentrum stehen nach allgemeiner Auffassung die Theorie und Praxis des Lehrens und Lernens/ Erwerbens des Deutschen als Fremdsprache; unterschidliche Auffassungen bestehen vor allem daruber, ob Deutsch als Fremdsprache ein germanistisches oder aber ein fremdsprachenphilologisches Fach sei. Unbestritten sind dagegen Fremdperspektive und $Interdisziplinarit\'{a}t$ der Disziplin rnit zahlreichen Beztigen zu Nachbarwissenschaften. Eine wesentliche Rolle in der Diskussion spielte stets die Rolle der Grammatik im fremdsprachlichen Deutschunterricht. Freilich hat die Diskussion ergeben, dass dieses in Wahrheit eine Scheinaltemative ist, die auf einer Reihe falscher Annahmen oder $Missverst\"{a}ndnissen$ beruht, vor allem jenen, im Unterricht komme es $ausschlie{\ss}lich$oder zurnindest vorrangig auf Fertigkeiten und Kommunikation an, nicht oder nur am Rande auf die Vermittlung sprachsystematischer Erkenntnisse. Durchgesetzt hat sich heute freilich die Erkenntnis, dass Grammatik, verstanden in diesem weiten Begriffssinn, aus dem Fremdsprachenunterricht nicht zu verbannen ist. Weiterhin $d\"{u}rfte$ Einvemehmen dariiber herrschen, dass Grammatik und Kommunikation keinen Gegensatz darstellen, vielmehr das Lernziel kommunikative Kompetenz die Beherrschung grammatischer Regeln einbezieht, wenn nicht voraussetzt. Der Funktionsbegriff ist umstritten. Der Oberbegriffe $f\"{u}r$ alle Funktionen $w\"{a}re$ Kommunikation. Fur unser Verstandnis einer funktionalen Grammatik fur Lemende des Deutschen als Fremsprache ist die entscheidende Frage, welche Funktion in der Kommunikation eine bestimmte Struktur spielt. Das Ziel oder der Zweck der kommunikativen Handlung steht im Mittelpunkt. Wir meinen, dass auch jenseits des deutschen Sprachraums Form und Funktion des sprachlichen Zeichens eine Einheit darstellen und im Unterricht nicht getrennt werden $k\"{o}nnen$. Zuerst lernen wir die Formen und Strukturen sprachlicher Mittel kennen, und danach werden wir sie praktisch an: Regelwissen, aber Versagen in der Kommunikation. Die Beispiele der sprachlichen $M\"{o}glichkeiten$ der Satzarten unter funktionalem Aspekt und des Ausdrucks der $Modalit\"{a}t$ im Deutschen machen die Notwendigkeit eines funktional-kommunikativen Ansatzes einer Grammatik fur Deutsch als Fremdsprache deutlich. Es belegt zugleich, dass - unter dem Primat des Didaktischen - die Grenze von Grammatik und Lexikon $\"{u}berwinden$ werden muss, um den Lemenden wirkliche $Erkl\"{a}rung$ und Lernhilfen zu bieten.

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Efficient Second Harmonic Generation of a High-power Yb-doped Fiber MOPA Incorporating MgO:PPSLT (MgO:PPSLT를 이용한 고출력 Yb 광섬유 레이저 빔의 고효율 이차조화파 변환)

  • Song, Seungbeen;Park, Eunji;Park, Jong Sun;Oh, Yejin;Jeong, Hoon;Kim, Ji Won
    • Korean Journal of Optics and Photonics
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    • v.31 no.3
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    • pp.142-147
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    • 2020
  • In this paper, we report highly efficient second harmonic generation of continuous-wave Yb fiber lasers incorporating a periodically poled LiTaO3 device (MgO:PPSLT) as a frequency converter. The seed laser output from a Yb fiber master oscillator using a Fabry-Perot feedback cavity was amplified in a Yb fiber amplifier stage, yielding 28.5 W of linearly polarized output at 1064 nm in a beam with beam quality, M2, of ~1.07. Second harmonic generation was achieved by passing the laser beam through MgO:PPSLT. Under optimized conditions, we obtained 11.1 W of green laser output at 532 nm for an incident signal power of 25.0 W at 1064 nm, corresponding to a conversion efficiency of 44.4%. The detailed investigation to find the optimized operating conditions and prospects for further improvement are discussed.

APPLYING ENTERPRISE GIS TO DISASTER MANAGEMENT AT KANGWON PROVINCE

  • Yoon, Hoon-Joo;Ryu, Joong-Hi;Kim, Jung-Dai;Park, Hong-Gi
    • Journal of Korean Society for Geospatial Information Science
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    • v.9 no.2 s.18
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    • pp.29-36
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    • 2001
  • The purpose of this paper is to describe the Disaster Management System Development of Enterprise GIS at the Kangwon Province in Korea. This project is included into 'the Kangwon Enterprise GIS 21 plan'. The Division of Disaster Management is in the middle of the 2-year project of the Disaster Management System development, appropriate for business performed at the Departments of Forestry, Culture, Environment, Tourism, etc. At the 1st phase of CIS implementation, for more than half a year we focused on the necessity of management of disasters. In the planning process, we needed long-term information on the whole area of Kangwon. In the assessment and response processes, we needed real-time data from Korean Meteorological Administration and other agencies. All the above information was carefully studied and referred to. ESRI's new GIS technologies solve the natural hazard/disaster problems. For example, hazardous materials routing often needs to be found the least expensive path through a roadway network. In the circumstances given, we can choose the departure point and destination of the vehicle, which carries the materials. It's also possible to minimize overall risk and costs of disaster problems by making a plan of people and possessions evacuation from the disaster area in short time limits. We can meet all the above goals using the latest ESRI's technologies.

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Determination of 10${\alpha}$-Methoxy-9,10-dihydrolysergol (MDL), Main Metabolite of Nicergoline, in Human Plasma by HPLC-MS and Applicability to Oral Bioavailability in Korean Healthy Male Volunteers (HPLC-MS를 이용한 생체시료 중 니세르골린의 주대사체인 10${\alpha}$-Methoxy-9,10-dihydrolysergol(MDL)의 분석 및 이를 이용한 한국인 성인 남성에 대한 생체이용률 응용)

  • Lim, Hyon-Kyun;Yoo, Sun-Dong;Kim, Kyeong-Ho;Han, Sang-Beom;Youm, Jeong-Rok
    • YAKHAK HOEJI
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    • v.51 no.2
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    • pp.133-139
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    • 2007
  • A simple and sensitive HPLC-MS method for quantitation of 10${\alpha}$-methoxy-9,10-dihydrolysergol (MDL), the main metabolite of nicergoline, in human plasma was developed and the bioavailability parameters of MDL was assessed in Korean healthy male volunteers. Clomipramine was used as an internal standard. MDL and internal standard in plasma sample were extracted using ethyl acetate. A centrifuged upper layer was then evaporated and reconstituted with mobile phase of 10 mM ammonium acetate-acetonitrile (10 : 90, v/v). The reconstituted samples were injected into a Zorbax SB-C8 column (2.1${\times}$150 mm,5 ${\mu}$m) at a flow-rate of 0.3 ml/min. Using MS with selected ion monitoring (SIM) mode, MDL and clomipramine were detected without severe interference from human plasma matrix. MDL produced a protonated molecular ion ([M+H]$^+$) at m/z 287. Internal standard produced a protonated molecular ion ([M+H]$^+$) at m/z 315. A linear relationship for MDL was found in the range of 2.5${\sim}$100 ng/ml. The lower limit of quantitation (LLOQ) was 2.5 ng/ml with acceptable precision and accuracy. The intra- and inter-day validation for all coefficients of variation (R.S.D.%) were found less than 15%. Main pharmacokinetic parameters of 30 mg of nicergoline were revealed as follows: AUC$_t$ 321.1${\pm}$64.5 ng${\cdot}$hr/ml, C$_{max}$, 51.2${\pm}$25.3 ng/ml, T$_{max}$ 3.6${\pm}$1.5 hr, K$_{el}$ 0.12${\pm}$0.07 hr$^{-1}$ and t$_{1/2}$ 7.6${\pm}$3.4 hr. Inter subject variations and race differences were shown in comparison with the published data in the literature.

An Analysis of the Economy of Scale for Domestic On-site Hydrogen Fueling Stations (국내 분산형 수소충전소의 규모의 경제성 분석)

  • Gim, Bong-Jin;Kim, Jong-Wook
    • Journal of Energy Engineering
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    • v.16 no.4
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    • pp.170-180
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    • 2007
  • This paper deals with the economy of scale for domestic on-site hydrogen stations fueled with natural gas and naptha. We evaluate the economic feasibility of on-site hydrogen stations with hydrogen production capacities of $30Nm^3/hr,\;100Nm^3/hr\;and\;300Nm^3/hr$. We build a classical economic feasibility model and we make some sensitivity analyses by changing the values of input factors such as the hydrogen sale price and the discount rate. The estimated hydrogen prices of steam methane reforming stations with production capacities of $30\;Nm^3/hr,\;100\;Nm^3/hr\;and\;300\;Nm^3/hr$ are 18,472 won/kg, 10,689 won/kg and 7,758 won/kg, respectively. Also, the hydrogen prices are about the same if we use naptha as a raw material for hydrogen energy instead of natural gas. It turns out that small and medium size domestic on-site hydrogen stations will not be economical in the near future. This indicates that we need to construct large scale on-site hydrogen fueling stations even for the initial phase of the hydrogen economy.

Miscibility of Melt-mixed PLLA/PMMA Blends for Optical Film Application (광학 필름 적용을 위한 용융혼합된 PLLA/PMMA 블렌드의 상용성 연구)

  • Park, Eun Ju;Kim, In Seok;Park, Sang Seok;Lee, Ho Sang;Lee, Moo Sung
    • Polymer(Korea)
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    • v.37 no.6
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    • pp.744-752
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    • 2013
  • The miscibility between poly(L-lactide) (PLLA) and poly(methyl methacrylate) (PMMA) was investigated using thermal analyses for the purpose of developing birefringence-free material at oriented state. The effect of methyl acrylate (MA) units as comonomer of PMMA on the miscibility was also studied. All the blends prepared in this study show composition-dependent single $T_g$'s between those of blend components and high transparency over the visible region, indicating the miscibility at molecular level and no discernible effect of MA units on it. No phase separation was observed at elevated temperature of $280^{\circ}C$, higher than the degradation of PLLA and PMMA. The interaction energy density in PLLA/PMMA blends with 17 mol% of MA was measured to be $-0.74J/cm^3$ from the equilibrium melting temperature depression based on the Hoffman-Weeks method. The blends show zero-${\Delta}$n behavior at a specific mixing ratio and the drawing ratio of 3 due to compensation of intrinsic orientation birefringence. Birefringence dispersion of PLLA/PMMA5 blends was also measured to examine the possibility for quarter-wave plates or polarizer protective films.

Effects of Some Soil Conditioners on Soil Physical Properties and Lettuce Growth (토양구조개선제(土壤構造改善劑) 처리(處理)가 토양물리성(土壤物理性)과 상추생육(生育)에 미치는 영향(影響))

  • Ryu, In-Soo;Han, Jeung-Lim;Jo, In-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.28 no.3
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    • pp.249-255
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    • 1995
  • This study was conducted to investigate the effects of some soil conditioners, such as polyacrylamide(PAM), polyvinylalcohol(PVA) and Bitumen emulsion, on aggregate formation and stability, wetting angle, sorptivity and penetrability of the soil with different textures : sand, sandy loam, loam and clay loam. A pot experiment was carried out to find out the effect of treatment on the germination and growth of lettuce with three textures : sand, sandy loam and silt loam. Soil aggregates larger than 2mm in untreated soils at dry condition were naught in sand, 45% in sandy loam, 80% in loam and 90% in clay loam. Treatments of soil conditioners tended to increase the occurrence of soil aggregate larger than 2mm, which were 20~25% in sand, 55~75% sandy loam, but not affected greatly aggragate occurence in loam and clay loam. The aggregate instability was decreased by the soil conditioner treatment. The wetting angles of the soils were greatly changed by hydrophobic of Bitumen, but those were changed slightly by PVA and PAM application. The sorptivity and penetrability data indicated that the effects of different materials on these parameters differed depending upon soil texture. Application of PVA and PAM were no effect exceptive in sand. Application of Bitumen revealed that water movement was not showed in all soils. The germination rate, root weight and top plant weight of lettuce were increased in all soils by PAM treatment as compared to untreated soils. Particularly the greater effect was occurred in sand soil than in sandy loam and silt loam. PAM increased greatly the moisture content and air phase of soils.

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Development of Analytical Method for Sodium Alginate in Foods (식품 중 알긴산나트륨의 분석법 개발)

  • Kim, Hee-Yun;Hong, Ki-Hyoung;Choi, Jang-Duck;Park, Sung-Kwan;Jung, Si-Sub;Choi, Woo-Jeong;Ahn, Yeong-Sun;Hong, Yeong-Pyo;Song, Ok-Ja;Moon, Dong-Chul;Lee, Shin-Ho;Shin, Il-Shik
    • Korean Journal of Food Science and Technology
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    • v.38 no.1
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    • pp.1-4
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    • 2006
  • Method of analyzing sodium alginate in foods was developed using high performance liquid chromatography (HPLC). HPLC conditions for sodium alginate were: column, MCI GEL $(8\;mm\;i.d{\times}300\;mm)$; mobile phase, deionized water; detector, refractive index detection (sensitivity = 16). Separation of sodium alginate was achieved within 15 min. Sodium alginate showed good linear relationship at 0.1-2.0% range. Correlation coefficient of calibration curve for sodium alginate exceeded 0.999, and detection limit was 0.005%. Recovery rate of sodium alginate in wheat flour dough was 106.67%. This method was successfully applied to analyses of cereals, saccharides, and ice cream, etc. Sodium alginate was detected in chocolate, noodles, and kelp at 0-44.8% range.

Studies on the Morphology and Thermal Properties of the Polyurethane Synthesized from 4,4'-Diphenylmethane Diisocyanate (MDI) and Polyester Polyol (4,4'-Diphenylmethane Diisocyanate (MDI)와 폴리에스테르 폴리올로부터 합성된 폴리우레탄의 모폴로지와 열적 성질에 관한 연구)

  • Jung Hyun Chul;Kang Sung Joong;Kim Woo Nyon;Kim Sang Bum;Lee Yeong Beom;Hong Seong Ho
    • Journal of the Korean Institute of Gas
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    • v.2 no.1
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    • pp.59-65
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    • 1998
  • Morphology and thermal properties of polyurethane synthesized from 4,4'-diphenylmethane diisocyanate (MDI), polyester polyol, and 1,4-butane diol are investigated using fourier transform infrared spectroscopy (FT-IR), differential scanning calorimeter (DSC), and dynamic mechanical thermal analysis (DMTA). From the FT-IR study, it is found that the stretching peaks of hydrogen bonded N-H and C=O are shifted to the low frequencies with the increase of hard segment content of the polyurethanes. The shift of the stretching peaks of hydrogen bonded N-H and C=O indicates that the degree of hydrogen bonding is increased. From the DSC study, it appears that the glass transition temperature ($T_g$) of the polyurethanes is increased with the increase of the hard segment content. Also, it is found that the polyurethanes investigated in this study have the homogeneous network structure due to the high functionality of the MDI. From the DMTA study, transition of the soft segment was not found. Therefore it is concluded that the polyurethanes investigated in this study have the one-phase morphology which is consistent with the DSC results.

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