• Title/Summary/Keyword: Quinoline N-oxides

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Synthesis of Fullerene Oxide by Fullerene ($C_{70}$) and Various Amino N-Oxides under Ultrasonic Irradiation (초음파 조건에서 여러가지 아민 N-옥시드와 풀러렌($C_{70}$)를 이용한 풀러렌 산화물의 합성)

  • Ko, Weon-Bae;Han, Ji-Yeon;Lim, Young-A;Shin, Won-Jic;Yu, Gu-Yong
    • Elastomers and Composites
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    • v.39 no.2
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    • pp.153-160
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    • 2004
  • Fullerene oxides were synthesized by fullerene ($C_{70}$) and several amine N-oxides such as 3-picoline N-oxide, pyridine N-oxide hydrate, quinoline N-oxide, and isoquinoline N-oxide under ultrasonic condition at $25{\sim}43^{\circ}C$. The reactivity of fullerene ($C_{70}$) with various amine N-oxides undo, ultrasonic irradiation showed the same in all of the proceeding experiments; 3-picoline N-oxide : pyridine N-oxide hydrate : quinoline N-oxide : isoquinoline N-oxide. The MALDI-TOF MS, UV-vis spectrophotometer and HPLC analysis confirmed that the products of fullerene oxidation are [$C_{70}(O)n$] (n=1).