• Korean Journal of Materials Research
• /
• v.9 no.1
• /
• pp.104-107
• /
• 1999

We investigated the effects of cooling condition on deep levels and iron precipitate formation in iron-contaminated p-type silicon by DLTS(Deep Level Transient Spectroscopy) and preferential etching technique. Dependency of cooling condition on Bulk Micro-Defect (BMD) and four different iron-related deep traps were observed. For normal cooling condition, T1, T2, T3, T4 traps that related to Fe\ulcorner or Fe-O complex were obtained. However, the trap with activation energy, 0.4 eV was observed for slow cooling condition. The trap caused by the $\textrm{Fe}^{+}\textrm{}^{-}$ pair (H4:0.56eV) were detected only at the case of $\textrm{LN}_{2}$ quenching condition.

• Journal of the Korean Society for Heat Treatment
• /
• v.9 no.2
• /
• pp.147-158
• /
• 1996

Generally, analytical consideration on the behaviour of metallic structures during quenching process, and analysis on the thermal stress and deformation after heat treatment are very important in presumption of crack and distorsion of quenched material. In this study a set of constitute equations relevant to the analysis of thermo elasto-viscoplastic materials with strain hysteresis during quenching process way presented on the basis of contimuum thermo-dynamics mechanics. The thermal stresses were numerically calculated by finite element technique of weighted residual method and the principle of virtual work. In the calculation process, the temperature depandency of physical and mechaniclal properties of the material in consideration. On the distribution of elasto-viscoplastic thermal stresses according to radial direction, axial and tangential stress are tensile stress(50MPa, 1.5GPa and 300MPa) in surface and compressive stress(-1.2GPa, -1.14GPa and -750MPa) in the inner part on the other hand, radial stress is tensile stress(900MPa) in area of analysis. According to axial direction, tangential stress gradients are average 60MPa/mm on the whole. The reversion of stress takes place at 11.5 to 16.8mm from the center in area of analysing.

• Journal of the Korean Society for Heat Treatment
• /
• v.25 no.4
• /
• pp.181-189
• /
• 2012

The demand on quantitative measurement of the heat flux is motivated in making higher-quality steel product through a water quenching process of plate mill. To improve a spatial degree of heat flux measurement, the multi-point heat flux measurement was carried out by a unique experimental technique that has a combination of the existing single-point heat flux gauge. The corresponding heat flux can be easily determined by Fourier's law in a conventional way. The multi-point heat flux gauge developed in this study can be applicable to measure the surface heat flux, the surface heat transfer coefficient during a water quenching applications of steelmaking process. The results exhibit different heat transfer regimes; such as single-phase forced convection, nucleate boiling, and film boiling, that are occurred in close proximity on the multi-point heat flux gauge quenched by water impinging jet.

• Bulletin of the Korean Chemical Society
• /
• v.15 no.8
• /
• pp.663-669
• /
• 1994

Decay kinetics of Ga(5s), Ga(5p) and Ga(4d) atoms in Ar were studied by laser induced fluorescence technique. Theground state gallium atoms in the gas phase were generated by pulsed dc discharge of trimethyl gallium and argon mixtures. Both pulsed discharge and YAG-DYE laser system were controlled by a dual channel pulse generator and the delay time between the end of discharge and laser pulses was set 3.0-6.0 ms. The Ga(5s) and Ga(4d) atoms were generated by single photon excitation from the ground state Ga atoms and radiative lifetimes as well as the total quenching rate constants in Ar were obtained from the pressure dependence of the fluorescence decay rates. The Ga(5p) atoms were populated by a two-photon excitation method and the cascade fluorescence from Ga(5s) atoms were analyzed to extract quenching rate constant of Ga(5p) atoms by Ar in addition to radiative lifetimes of Ga(5p) state. The magnitudes of the quenching rate constants by Ar for the low-lying excited states of Ga atoms are 1.6-3$ {\times}10^{-11}cm^3$ molecul$e^{-1}s^{-1}$, which are much larger than those for alkali, alkaline earth and Group 12 metals. Based on the measured rate constants, kinetic simulations were done to assign state-to-state rate constants.

• Proceedings of the Korean Magnestics Society Conference
• /
• 1993.03a
• /
• pp.66-67
• /
• 1993

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.24 no.4 s.175
• /
• pp.858-865
• /
• 2000

It is well recently recognized that quench is one of the serious problems for the integrity of superconducting magnets, which is mainly attribute to the rapid temperature rising in the magnet due to some extrinsic factors such as conductor motion, crack initiation etc. In order to apply acoustic emission(AE)echnique effectively to monitor and diagnose superconducting magnets, it is essential to identify the sources of acoustic emission. In this paper, an acoustic emission technique has been used to monitor and diagnose quenching phenomenon in racetrack shaped superconducting magnets at cryogenic environment of 4.2K. For these purposes special attention was paid to detect AE signals associated with the quench of superconducting magnets. The characteristics of AE parameters have been analyzed by correlating with quench number, winding tension of superconducting coil and charge rate by transport current. In addition, the source location of quench in superconducting magnet was also discussed on the basis of correlation between magnet voltage and AE energy.

• The Korean Journal of Pharmacology
• /
• v.31 no.3
• /
• pp.271-278
• /
• 1995

The relative distribution ratio of barbiturates between hyarocarbon interior and surface region of outer monolayer of synaptosomal plasma membrane vesicles (RSPMV) isolated from rat whole brain was determined by employing the fluorescent probe technique. The two fluorescent probes N- octadecylnaphthyl-2-amine-6-sulfonic acid (ONS) and 12-(9-anthroyloxy) stearic acid (AS) were utilized as probes for hydrocarbon interior and surface of outer monolayer of RSPMV. respectively. The Stern-Volmer equation for fluorescent quenching was modified to calculate the relative distribution ratio. The analysis of preferential quenching of these probes by barbiturates indicates that pentobarbital, hexobarbital, amobarbital and phenobarbital are predominantly distributed on the surface region. whereas thiopental sodium has an accessibility to the hydrocarbon interior of the outer monolayer of the RSPMV. From these results, it is strongly suggested that the more effective penetration into the hydrocarbon interior of the outer monolayer of the membrane lipid bilayer could result in higher general anesthetic activity.

• Journal of the Korean Society for Heat Treatment
• /
• v.7 no.4
• /
• pp.233-243
• /
• 1994

Constitutive relation of thermoelasto-plastic material undergoing phase transformation during quenching process were developed on the basic of continuum thermodynamics. The metallic structure, temperature and residual stresses distributions were numerically calculated by the finite element technique. The metallic structure were defined by transformation from austenite to pearlite and characterized as a fuction of thermal history and mixture rule of phase. On the distribution of thermal stress along the radial direction, axial and tangential stresses are compressive in the surface, and tential in the inner part. Radial stress is tensile in the whole body. The reversion of residual stress takes plase at 11.5~15.5mm from the center.

• Journal of Photoscience
• /
• v.11 no.32
• /
• pp.65-69
• /
• 2004

The mechanism of interaction of four coumarin derivatives (CDS) with bovine serum albumin (BSA) was studied using spectrofluorometric technique. It was found that the coumarin ring common to all CDS makes major contribution to interaction. Binding affinities could be related to parachor values of CDS. Stem-Volmer plots indicated the presence of static component in the quenching mechanism. Results also showed that both tryptophan residues of protein are accessible to CDS. The high magnitude of rate constant of quenching indicated that the process of energy transfer occurs by intermolecular interaction forces and thus CDS binding site is in close proximity to tryptophan residues of BSA. Binding studies in the presence of the hydrophobic probe, 8-anilino-l-naphthalein-sulfonic acid showed that there is hydrophobic interaction between CDS and the probe and they do not share common sites in BSA. Thermodynamic parameters obtained from data at different temperatures showed that the binding of CDS to BSA involve hydrophobic bonds predominantly. The effects of various metal ions on the binding of CDS with BSA were also investigated.

• Journal of Ceramic Processing Research
• /
• v.20 no.3
• /
• pp.276-279
• /
• 2019

New green-emitting Sr4ScAl3O10:Eu2+ phosphor was prepared using a novel melt quenching synthesis method. The temperature of raw materials irradiated with the strong light of the Xe arc-lamp was rose up to about 2273 K, followed by a sharp drop in the temperature after turn off the lamp. This method is a useful tool for rapid screening of novel phosphor materials.