• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제48권7호
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• pp.503-507
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• 1999

Quartz crystal in contact with viscoelastic medium was described directly in terms of the electrical equivalent circuit of the system. Stearic acid was used as viscoelastic medium and deposited on the surface of quartz crystal using the Langmuir-Blodgett(LB) method. Impedance properties of quartz crystal coated with LB films which were investigated by using admittance diagram and $Ζ-\theta$ plot a method of impedance analysis. When stearic acid LB film was deposited on the surface of quartz crystal, resonant frequency of quartz crystal was changed about 100 Hz/layer. This result illustrates the ability of the sensor system to detect small amounts of special gas in air.

• 한국항만학회지
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• 제12권2호
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• pp.323-328
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• 1998

A quartz crystal analyzer is utilized to monitor the corrosion process of an aluminum surface of a quartz crystal for marine sensor by sea water. A quartz crystal having 2000 $\AA$ of aluminum layer is installed in a specially designed cell and is in contact with sea water imitated electrolyte solution. While a constant potential is applied to the cell, the resonant frequency and resonant resistance are simultaneously measured using the quartz crystal analyzer. In addition, surface topographs are taken with an atomic force microscope(AFM) and the element analysis of the surface is conducted using an energy dispersive X-ray spectrometer(EDX). The simultaneous measurement of resonant frequency and resonant resistance during the corrosion process explains the change of surface structure caused by the corrosion. The variation of resonant frequency addresses the amount surface metal dissolution. As a conclusion, it is found that a simple measurement using the quartz crystal analyzer can replace the complex monitoring employing large equipments in the investigation of a corrosion process of sensor surface.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제48권7호
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• pp.508-513
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• 1999

The response properties of quartz crystal coated with stearic acid LB films to organic gases were investigated by measuring the shift of resonant frequency. Stearic acid was used as a sensing material and deposited on the surface of quartz crystal using the Langmuir-Blodgett(LB) method. The effect of temperature on the quartz crystal coated with stearic acid LB films was also investigated by Scanning Maxwell-stress Microscopy(SMM). As a result, the sensitivity of the quartz crystal coated with LB films to organic gases is dependent on temperature, thickness of LB film and molecular weight of organic gas.

• 한국항해항만학회:학술대회논문집
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• 한국항해항만학회 1998년도 추계학술대회논문집:21세기에 대비한 지능형 통합항만관리
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• pp.183-188
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• 1998

A quartz crystal analyzer is utilized to monitor the cmsion process of an aluminum surface of a quartz crystal by sea water. A quartz crystal having 2000${\AA}$ of aluminum layer is installed in a spedally designed cell and is in contact with an electrolyte solution. While a constant potential is applied to the cell, the resonant frequency and resonant resistance are simultaneously measured using the quartz crystal analyzer. In addition, surface topographs are taken with an atomic force microscope(AFM) and the element analysis of the surface is conducted using an energy dispersive X-ray spectrornetedEDX). The simultaneous measurement of resonant frequency and resonant resistance during the corrosion process explains the change of surface structure caused by the corrosion. The variation of resonant frequency addresses the amount surface metal dissolution. As a conclusion, it is found that a simple measurement using the quartz crystal analyzer can replace the complex monitoring employing large equipments in the investigation of a corrosion process of metal surface.

• 대한전자공학회논문지TE
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• 제42권1호
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• pp.7-12
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• 2005

유한요소해석 프로그램인 ANSYS를 이용하여 수정진동자의 진동 및 주파수특성을 해석하였다. 수정진동자의 직경을 고정하고 두께를 변화시키면서 주파수특성을 조사하였다. 전극박막을 금, 은, 알루미늄으로 적층하였을 경우, 금속의 종류에 따른 공진주파수를 구하였다. 그 결과 유한요소법을 이용하여 수정진동자의 최적조건을 예측할 수 있었다. 또 수정편 두께가 0.2mm 보다 작은 영역에서의 주공진주파수는 8.102 MHz이상의 고주파를 얻을 수 있는 것을 확인하였다. 전극박막으로 사용한 금속의 종류에 따른 수정진동자의 주공진주파수 변화를 조사한 결과, 금이나 은에 비해 알루미늄이 우수한 주파수특성을 나타내었다.

• 한국결정성장학회지
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• 제4권3호
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• pp.315-324
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• 1994

고순도 규사 원료를 열처리하는 경우, 불순물로 포함되어 있는 미량성분이 quartz의 전이과정에 미치는 영향 및 전이 경로에 대하여 조사하였다. 미량성분의 영향을 조사한 결과, 규사 중의 미량성분 함량이 많아지면 cristobalite 생성량은 많아지며, quartz의 소멸온도 및 cristobalite의 생성온도는 낮아졌다. quartz의 전이경로를 조사한 결과 quartz $\rightarrow$ 천이비정질상 $\rightarrow$ melt (T) 및 quartz $\rightarrow$ 천이비정질상 $\rightarrow$ cristobalite $\rightarrow$ melt (C)의 경로가 항상 공존하며, 미량성분이 적은 경우는 T 경로가 우세하지만, 미량성분이 많은 경우는 C 경로가 우세한 것으로 규명되었다. 또한 XRD를 이용한 결정질 함량의 분석 결과로 부터 계산한 밀도와 pycnometer로 측정한 밀도를 비교한 결과 서로 일치하였다. 규사를 용융하여 석영유리를 제조하는 경우,특정온도에서 규사의 팽창 정도를 유추할 수 있을 것이다.

• KSBB Journal
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• 제18권2호
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• pp.79-89
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• 2003

This article contains an overview of acoustic wave devices, the theory and application of piezoelectric quartz crystal microbalances(PZ QCM), clinical analysis, gas phase detection, DNA biosensors, drug analysis, food microbial analysis and environmental analysis.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 추계학술대회 논문집
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• pp.171-174
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• 1998

Quartz crystal in contact with viscoelastic medium is described directly in terms of the electrical equivalent circuit of the system. Stearic acid is used as viscoelastic medium and deposited on the surface of quartz crystal using the Langmuir-Blodgett(LB) method. Impedance properties of quartz crystal coated with LB films which were investigated and the possibility of applying the technique to chemical sensing introduced.

• 한국항만학회지
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• 제14권4호
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• pp.475-479
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• 2000

A possibility of the implementation of a quartz crystal sensor to the determination of chemical oxygen demand is examined by checking the electrochemical behavior of the sensor in a glucose solution. Since the surface of a quartz crystal has to be oxidized, a relatively active metal is coated on the surface of a usual 9 MHz AT-cut crystal. The electrochemical behavior is investigated by measuring the changes of current, resonant frequency and resonant resistance while a constant potential is applied. The crystal is installed in a specially designed container, and a quartz crystal analyzer is utilized to measure the frequency and resistance simultaneously. The variations of the measurements are examined at different concentrations of glucose solution, and a proper relation between the concentrations of glucose solution, and a proper relation between the concentration and the measurements is analyzed. As a result, it is found that a linear relation between the concentration of less than 900 ppm and the peak current when a constant potential of -180 mV (SSCE) is applied. The relation can be utilized for the determination of glucose concentration in sea water, and considering a direct relation between gluose concentration and chemical oxygen demand tells a possibility of the measurement of chemical oxygen demand using quartz crystal oscillators.

• 터널과지하공간
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• 제10권1호
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• pp.70-79
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• 2000

입자수, 압력, 온도일정의 앙상블(NPT-ensemble) 분자동력학(MD) 시뮬레이션을 이용하여 300$^{\circ}$K에서 $\alpha$-quartz의 결정축에 따른 일축압축강도를 계산하고, 자연산 $\alpha$-quartz 단결정 코아를 제작하여 일축압축강도시험을 실시하였다. $\alpha$-quartz 단결정 코아에 대한 일축압축시험에서 측정된 결과에 의하면 재하 방향이 c축에 평행한 경우가 수직인 경우보다 높은 강도를 나타내지만, MD 시뮬레이션에서 계산된 완전무결함 $\alpha$-quartz의 경우 이와 반대의 결과를 보이고 있다. 두 경우 모두 재하방향에 따른 강도 이방성을 보이고 있으나, 그 이유는 서로 다르다. MD 시뮬레이션에 의해 계산된 무결함 $\alpha$-quartz의 강도 이방성은 결정구조의 차이에 기인하는 것으로 사료된다. 이에 반해 일축압축시험을 통해 측정된 $\alpha$-quartz의 강도 이방성은 결정성장과정에서 생기는 주상 미세결함에 의해 영향을 받는다.